Changes of the Flavonoids in Onion Vinegar Fermented with Onion Juice and Ethanol

주정을 첨가한 양파식초 제조에서 Flavonoids의 함량변화

  • Cheun Kyung-Sun (Department of Food Engineering and Food Industrial Technology Research Center, Mokpo National University) ;
  • Kang Seong-Gook (Department of Food Engineering and Food Industrial Technology Research Center, Mokpo National University) ;
  • Kang Seong-Koo (Department of Food Science and Technology, Sunchon National University) ;
  • Jung Soon-Teck (Department of Food Engineering and Food Industrial Technology Research Center, Mokpo National University) ;
  • Park Yang-Kyun (Department of Food Engineering and Food Industrial Technology Research Center, Mokpo National University)
  • 천경선 (목포대학교 식품공학과 및 식품산업기술연구센터) ;
  • 강성국 (목포대학교 식품공학과 및 식품산업기술연구센터) ;
  • 강성구 (순천대학교 식품과학부) ;
  • 정순택 (목포대학교 식품공학과 및 식품산업기술연구센터) ;
  • 박양균 (목포대학교 식품공학과 및 식품산업기술연구센터)
  • Published : 2005.12.01

Abstract

To produce a flavonoid-enriched vinegar from onion, vinegar fermentations of onion juice, extraction of flavonoids from onion-dry scale, and change of the flavonoids in vinegar were investigated. Alcohol and vinegar fermentations from the onion juice were effectively improved by using the onion juice heated at $80^{\circ}C$ for 10 min. When various types of onion juices were used for onion vinegar production, the vinegar fermentation of heat-treated onion juice containing $4\%$ ethyl alcohol showed maximal acid production. Flavonoid compounds in onion vinegar made from fresh onion juice was larger than the other onion vinegar. To produce a flavonoid-enriched vinegar, when it was examined the $05\%$ onion-dry scale was added to $6\%$ acetic acid, optimum extraction time was 90 min. And by adding $0.5\%$ onion-dry scale to onion vinegar, quercerin monoglucoside and quercetin contents increased.

양파의 냄새를 줄이고 기능성을 살린 식초의 제조를 위한 기초 연구의 일부로서 양파즙에 보당하여 알콜 발효하는 대신에 알콜 발효 없이 양파즙에 에탄올을 첨가한 양파식초의 제조에서 flavonoid 물질의 함량변화, flavonoids를 강화한 양파식초의 제조방법 및 이들 물질의 초산에 대한 안정성을 조사하였다. 양파즙의 식초발효에서 $80^{\circ}C$, 10분 열처리하여 착즙한 양파액에 $4\%$ 에탄올을 첨가한 양파식초에서 초산생성량이 높았다. Flavonoids의 함량은 생양파즙을 사용한 식초에서 가장 많았다. 양파껍질의 flavonoid성분 추출을 위해 $6\%$ 초산액에서 $20^{\circ}C$, 140 rpm으로 교반추출시에 90분 처리가 적절하였고, 이것을 양파식초에 첨가한 결과 quercetin monoglucoside와 quercetin의 함량이 증가하였다. 양파식초에서 flavonoids의 안정성은 quercetin diglucoside가 quercetin monoglucoside에 비해 안정하였고 quercetin 배당체마다 산에 의한 영향이 차이가 있음을 알 수 있었다.

Keywords

References

  1. Yang, J., Meyers, K.J., van der Heide, J. and Lui, R.H. (2004) Varietal differences in phenolic content and antioxidant and antiproliferative activities of onions. J. Agric. Food Chem., 52, 6787-6793 https://doi.org/10.1021/jf0307144
  2. Lee, Y.K. and Lee, H.S. (1990) Effects of onion and ginger on the lipid peroxidation and fatty acid composition of mackerel during frozen storage. J. Korean Soc. Food Sci. Nutr., 19, 321-329
  3. Park, P.S., Lee, B.R. and Lee, M.Y. (1993) Effect on onion diet on carbon tetrachloride toxicity of rats. J. Korean Soc. Food Sci. Nutr., 20, 121-125
  4. Sheo, H.J., Lim, H.J. and Jung, D.L. (1993) Effects of onion juice on toxicity of lead in rat. J. Korean Soc. Food Nutr., 22, 138-143
  5. Kang, S.K., Kim, Y.D., Hyun, K.H., Kim, Y.W., Song, B.H., Shin, S.C. and Park, Y.K. (1998) Development of separating techniques on quercetin-related substances in onion (Allium cepa L.). 1. Contents and stability of quercetin-related substances in onion. J. Korean Soc. Food Sci. Nutr., 27, 682-686
  6. Kim, Y.D., Kang, S.H. and Kang, S.K. (1996) Studies on the acetic acid fermentation using Maesil juice. J. Korean Soc. Food Sci. Nutr., 25, 695-700
  7. Kim, S.K., Lee, G.D. and Chung, S.K. (2003) Monitoring on fermentation of persimmon vinegar from persimmon peel. Korean J. Food Sci. Technol., 35, 642-647
  8. Seo, J.H., Kim, Y.J. and Lee, K.S. (2003) Comparison of physicochemical characteristic of fruit vinegars produced from two-stage fermentation. Food Indust. Nutr., 8, 40-44
  9. Park, Y.K., Jung, S.T., Kang, S.G., Park, I.B., Cheun, K.S. and Kang, S.K. (1999) Production of a vinegar from onion. Korean J. Appl. Microbiol. Biotechnol., 27, 75-79
  10. Shin, J.S., Lee, O.S. and Jeong, Y.J. (2002) Changes in the components of onion vinegars by two stages fermentation. Korean J. Food Sci. Technol., 34, 1079-1084
  11. Masuda, T. (1994) Development and characteristics of onion vinegar. Food Sci. (Japan), 33, 93-96
  12. Horiuchi, J.I., Kanno, T. and Kobayashi, M. (2000) Effective onion vinegar production by a two-step fermentation system. J. Biosci. Bioeng., 90, 289-293 https://doi.org/10.1016/S1389-1723(00)80083-3
  13. Horiuchi, J.I., Kanno, T., Kobayashi, M. and Ebie, K. (2004) Biological approach for effective utilization of worthless onions-vinegar production and composting. Resources, Conservation, and Recycling, 40, 97-102 https://doi.org/10.1016/S0921-3449(03)00036-3
  14. Jeong, Y.J., Seo, J.H., Park, N.Y., Shin, S.R. and Kim, K.S. (1999) Changes in the components of persimmon vinegars by two stages fermentation (II). Korean. J. Postharvest Sci. Technol., 6, 233-238
  15. Kim, D.H. (1999) Studies on the production of vinegar from fig. J. Korean Soc. Food Sci. Nutr., 28, 53-60
  16. Lee, C.Y. and Park, Y.K. (1996) Identification of isorhamnetin-4-glucoside in onion. J. Agric. Food Chem., 44, 34-36 https://doi.org/10.1021/jf950310e
  17. Price, K.R., Bacon, J.R. and Rhodes, M.J.C. (1997) Effect of storage and domestic processing on the contents and composition of flavonoid glucosides in onion (Allium cepa). J. Agric. Food Chem., 45, 938-942 https://doi.org/10.1021/jf9605916
  18. Crozier, A., Lean, M.E.J., McDonald, M.S. and Black, C. (1997) Quantitative analysis of the flavonoid content of commercial tomatoes, onions, lettuce, and celery. J. Agric. Food Chem., 45, 590-594 https://doi.org/10.1021/jf960339y
  19. Erlund, I. (2004) Review of the flavonoids quercetin, hesperetin, and naringenin. Dietary sources, bioactivities, bioavailability, and epidemiology. Nutr. Res., 24, 851-874 https://doi.org/10.1016/j.nutres.2004.07.005
  20. Davis, W.L. and Matthew, S.B. (2000) Antioxidants and cancer III - Quercetin. Alternative Med. Rev., 5, 196-208
  21. Boyer, J., Brown, D. and Lui, R.H. (2004) Uptake of quercetin and quercetin 3-glucoside from whole onion and apple peel extracts by Caco-2 cell monolayers. J. Agric. Food Chem., 52, 7172-7179 https://doi.org/10.1021/jf030733d