DOI QR코드

DOI QR Code

저온 소결용 PMN-PT-BT 세라믹스의 물성에 미치는 승온 속도의 영향

Influence of Heating Rate on the Properties of Low-Temperature-Sinterable PMN-PT-BT Ceramics

  • 임경란 (한국과학기술연구원 재료연구부) ;
  • 김창삼 (한국과학기술연구원 재료연구부)
  • Han, Kyoung-Ran (Division of Materials Science and Technology, Korea Institute of Science and Technology) ;
  • Kim, Chang-Sam (Division of Materials Science and Technology, Korea Institute of Science and Technology)
  • 발행 : 2005.01.01

초록

저온 소결용 PMN-PT-BT분말을 $850^{circ}C/2h$ 소결할 때 승온 속도를 분당 5, 10, $20^{circ}C$로 변화하며 물성에 미치는 영향을 조사하였다. PbO(응점 $886^{circ}C$)의 휘발이 미미한 소결온도에서는 분당 $5^{circ}C$로 승은하여 소결한 것이 승온 속도 $10^{circ}C$$20^{circ}C$의 경우에 비하여 보다 균일한 미세구조를 나타내며, 소결밀도 $7.93g/cm^{3}$, 실온 유전을 15300, 유전손실 $0.92\%의 우수한 유전 특성을 나타내었다.

Effect of heating rate was studied on consolidation of the low-temperature-sinterable PMN-PT-BT powder by varying the heating rate from 5, 10, to $20^{circ}C/min$. Slow rate of $5^{circ}C/min$ showed more homogeneous microstructure than high rate of 10 or $20^{circ}C/min$ due to low PbO (m.p. $886^{circ}C$) evaporation at 850^{circ}C$. It showed sintered density of $7.93 g/cm^{3}$, room temperature dielectric constant of 15300, and dissipation factor of $0.92\%$.

키워드

참고문헌

  1. S. L. Swartz and T. R. Shrout, 'Fabrication of Perovskite Lead Magnesium Niobate,' Mater. Res. Bull., 17 1245-50 (1982) https://doi.org/10.1016/0025-5408(82)90159-3
  2. S. Nomura and K. Uchino, 'Recent Applications of PMN-Based Electrostrictors,' Ferroelectrics, 50 191-202 (1983) https://doi.org/10.1080/00150198308014449
  3. T. R. Shrout and A. Halliyal, 'Preparation of Lead-Based Ferroelectric Relaxors for Capacitors,' Am. Ceram. Soc. Bull., 66 [4] 704-11 (1987)
  4. C. E. Wheeler and B. G. Pazol, 'Multilayer Electrodisplacive Actuators,' Am. Ceram. Soc. Bull., 70 [1] 117-19 (1991)
  5. S. L. Swartz, T. R. Shrout, W. A. Schulze, and L. E. Cross, 'Dielectric Properties of Lead Magnesium Niobate Ceramics,' J. Am. Ceram. Soc., 67 [5] 311-15 (1984) https://doi.org/10.1111/j.1151-2916.1984.tb19528.x
  6. M. Lejeune and J. P. Boilet, 'Formation Mechanism and Ceramic Process of the Ferroelectric Perovskites : Pb($Mg_{1/3}Nb_{2/3}$)$O_3$ and Pb($Fe_{1/2}Nb_{1/2}$)$O_3$,' Ceram. Int., 8 99-103 (1982) https://doi.org/10.1016/0272-8842(82)90025-6
  7. K. H. Yoon and D. H. Kang, 'Influence of $BaTiO_3$ Content and Firing Temperature on the Dielectric Properties of Pb($Mg_{1/3}Nb_{2/3}$)$O_3$ Ceramics,' J. Kor. Ceram. Soc., 26 [2] 249-57 (1989)
  8. L. Wu and Y.-C. Lieu, 'Effect of Heating Rate on the Dielectric Properties of the PMN-PT Relaxor Ceramics,' J. Am. Ceram. Soc., 77 [12] 3255-58 (1994) https://doi.org/10.1111/j.1151-2916.1994.tb04579.x
  9. L. Wu and Y.-C. Lieu, 'The Effect of Heating Rate on the Properties of PMN Relaxor Ceramics,' Ceram. Int., 21 [5] 335-38 (1995) https://doi.org/10.1016/0272-8842(95)96205-4
  10. L. Wu and Y.-C. Lieu, 'Properties of PMN and 0.9PMN-0.1PT Ceramics Sintered with various Heating Rates,' Ferroelectrics, 168 [3-4] 251-59 (1995) https://doi.org/10.1080/00150199508217638
  11. Y.-C. Liou, 'Effect of Heating Rate on Properties of PMN Ceramics Produced by the Reaction-Sintering Process,' Mater. Lett., 58 944-47 (2004) https://doi.org/10.1016/j.matlet.2003.07.041
  12. Y.-C. Liou and J.-H. Chen, 'PMN Ceramics Produced by a Simplified Columbite Route,' Ceram. Int., 30 17-22 (2004) https://doi.org/10.1016/S0272-8842(03)00056-7