Effect of Wastewater Treatment with Tannins from Peel of Astringent Persimmon Fruits

떫은감 껍질로부터 분리한 탄닌을 이용한 폐수처리 효과

  • Cho Young-Je (Department of Food Engineering, Sangju National University) ;
  • Chun Sung-Sook (Department of Food Science & Technology, Yeungnam University)
  • 조영제 (상주대학교 식품공학과) ;
  • 천성숙 (영남대학교 식품가공학과)
  • Published : 2005.06.01

Abstract

The two major tannins were separated by Sephadex LH-20 and MCI-gel CHP-20 from peel of astringent persimmon fruits. Purified tannins were identified to (+)-catechin and (+)-gallocatechin by NMR, IR spectrum and FAB-mass spectrum. The removal rate of turbidity, T-N, T-P and CODcr in wastewater with lime and (+)-gallocatechin was higher than those of (+)-catechin because (+)-gallocatechin has more hydroxyl groups. As increasing concentration of tannins from peel of astringent persimmon fruits, the removal rate of turbidity, T-N, T-P and CODcr were increased. Synergistic activity by mixed tannins(catechin+gallocatechin) was also observed.

감 껍질 추출물을 Sephadex LH-20 및 MCI-gel CHP 20 column을 이용하여 2개의 주요 탄닌을 분리할 수 있었으며, NMR, IR, FAB-mass 등을 이용한 구조 동정 결과(+)-catechin, (+)-gallocatechin으로 확인되었다. 소석회와 보조응집제로 정제 탄닌을 처리할 때 얻어진 탁도, T-N, T-P 및 CODcr 제거율은 gallocatechin이 catechin보다 우수한 것으로 나타났으며, 이는 탄닌 분자의 -OH기가 타 물질과의 반응성이 높아 하수속의 물질과 결합을 하게 되는데 분자구조에 이러한 -OH기가 많을수록 응집 침전하는 능력이 더 우수한 것으로 판단되었다. 또한 단일 탄닌을 첨가하는 것보다 혼합 탄닌 실험군이 탁도, T-N, T-P 및 CODcr 제거율이 다소 높은 것으로 나타나, 물질 간 synergy 효과도 있는 것으로 확인되었다.

Keywords

References

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