Food Science and Preservation (한국식품저장유통학회지)

The Korean Society of Food Preservation (한국식품저장유통학회)
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Change of the Volatile Organic Compounds from Irradiated Dried-Red Pepper

방사선 조사된 건고추의 휘발성 유기화합물 변화

  • Published : 2005.08.01
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Abstract

Compare with volatile organic compounds from unirradiated and irradiated dried-red pepper that is representative spice of korea. Volatile compounds from unirradiated and irradiated dried-red pepper were extracted using simultaneous distillation-extraction(SDE) apparatus and analyzed by Gas chromatography/mass spectrometer (GC/MS). A total of 61 and 62 compounds were identified from unirradiated and irradiated dried red pepper at dose of 10 kGy. These compounds included alcohols, aldehydes, furans, hydrocarbons, ketones, N-containing compounds, terpenes and micellaneous compounds. Furfural, benzaldehyde, linalool, nerolidol, ${\alpha}$-curcumene, ${\alpha}$-zingibirene were detected as the major volatile compounds from dried-red pepper. Specially, 1,3-bis[1,1-dimethylethyl]-benzene was confirmed as a marker of irradiated dried-red pepper because is not detected in unirraiatied dried-red pepper.

본 연구에서는 우리 나라의 대표적인 향신료 중의 하나인 건고추의 휘발성 유기성분을 n-pentane과 diethylether 혼합용매를 추출용매로 사용하여 연속증류추출장치로 휘발성 유기화합물을 추출하고 이를 GC/MS로 사용하여 분석${\cdot}$확인하였다. 건고추와 조사된 건고추에서 확인된 성분은 각각 61종과 62종으로, 관능기별 상대 면적비는 대체적으로 terpene류, aldehyde류가 두드러지는 경향을 보여 건고추의 주요 휘발성 유기화합물에 크게 영향을 미치는 것으로 판단되었다. 건고추의 대표적인 휘발성 유기화합물로는 furfural, benzaldehyde, linalool, nerolidol, ${\alpha}$-curcumene 및 ${\alpha}$-zingibirene 등이었으며, benzaldehyde와 nerolidol, phenethyl alcohol은 방사선 조사한 후에 감소하였고, furfural과 linalool, ${\alpha}$-zingibirene, ${\alpha}$-curcumene은 방사선 조사한 후에 증가하였다. 특히 1,3-bis[1,1-dimethylethyl]-benzene은 대조군에서는 발견되지 않아 건고추의 방사선 조사여부를 확인하는데 중요한 성분으로 이용가능성이 높을 것으로 판단되었다. 따라서 1,3-bis[1,1-dimethylethyl]-benzene을 방사선 지시물질로 확실하게 판별하기 위해서는 다양한 실험방법을 통한 지속적인 연구가 필요할 것으로 사료된다.

Keywords

References

  1. Kim, B.K. and Kwon, J.H. (2004) Effects of irradiation and fumigation on physicochemical properties of red pepper during storage. Korean J. Food Culture., 19, 491-498
  2. Park, S H, Koo, H.J., Lim, H.S., Yoo, J.H., Hwang, S.Y., Shin, E.H., Park, Y.H., Lee, J.H. and Cho, J.S. (2003) The physicochemical changes during storage of red pepper powder dried in hot-air by various processing methods. Korean J. Nutr., 32, 876-881 https://doi.org/10.3746/jkfn.2003.32.6.876
  3. Seong, K.Y., Choi, G.I., Jeong, M.H., Heo, J.H., Kim, J.G. and Lee, G.S. (2004) Residues and half-lives of bitertanol and tebuconazole in greenhouse-grown peppers. J. Korean Soc. Appl Bio Chem., 47, 113-119
  4. Choi, S.M., Jeon, Y.S. and Park, K.Y. (2000) Comparison of quality of red pepper powders produced in korea. Korean J. Food Sci. Technol., 32, 16-22
  5. Kim, C.H., Kim, Y.Y., Park, S.B. and Eom, T.J. (2004) Chemical composition and alkaline pulping of a stem of red pepper(Capsicum annuum L.). Mokchae Konghak., 32, 26-32
  6. Kim, J.H., Ryu, S.H., Lee, M.J., Baek, J.W., Hwang, H.C. and Moon, G.S. (2004) Characteristics of red pepper (Capsicum Annuum L.) powder using $N_{2}$-circulated low temperature drying method. Korean J. Food Sci. Technol., 36, 25-31
  7. Vajdi M and Pereire RR. (1973) Comparative effects of ethylene oxide, $\gamma$-irradiation and microwave treatments on selected spices. J Food Sci., 38, 893-895 https://doi.org/10.1111/j.1365-2621.1973.tb02102.x
  8. UNEP. (1995) Montreal protocol on substances that deplete the ozone layer. Report of the methylbromide technical options committee. pp294
  9. Marcotte M. (1998) Irradiation as a disinfestation method update on methyl bromide phase out, regulatory action and emergeing opportunuties. Radiat. Phys. Chem., 52, 85-90 https://doi.org/10.1016/S0969-806X(98)00080-2
  10. Oh, K.N. and Lee, S.Y. (2004) Effects of gamma irradiation on the functional and structural characteristics of soy protein isolates. Korean J. Soc. Food Cookery Sci., 20, 256-264
  11. Kwon, J.H. (2003) Commercialization of food irradiation technology and the identification of irradiated foods. Food Sci. Indu., 36, 50-55
  12. Byun, M.W. and Lee, J.W. (2003) Application of irradiation technology for food safety and security. Food Sci. Indu., 36, 25-41
  13. Kim, B.K., Lee, J.E., Tusneem Kausar, Kim, D.H., Yang, J.G., Byun, M.W. and Kwon, J.H. (2004) Identification Characteristics of Irradiated Dried Red Pepper during Storage by the Analysis of Electron Spin Resonance and Hydrocarbons. J. Korean Soc. Food Sci. Nutr., 33, 1522-1528 https://doi.org/10.3746/jkfn.2004.33.9.1522
  14. IAEA. (2004) www. iaea org/icgfi
  15. Lee, W.M. and Cho, Y.S. (2004) Inheritance of mature fruit color and breeding of carotenoid-rich lines in capsicum pepper. The Korean Breeding Society., 36, 154-162
  16. Schultz, T.H., Flath, R.A., Mon, T.R., Enggling, S.B. and Teranishi, R. (1977) Isolation of volatile components from a model system J Agric. Food Chem, 25, 446-449 https://doi.org/10.1021/jf60211a038
  17. Nikerson, G.B. and Likens, S.T. (1966) Gas chromatography evidence for the Occurrence of Hop Oil components in Beer. J. Chromatography., 21, 1-5 https://doi.org/10.1016/S0021-9673(01)91252-X
  18. Robert, P.A. (1995) Identification of essential oil components by gas chromatography/mass spectroscopy. Allured Publishing Corporation, USA
  19. Stehagen, E., Abbrahamssom, S. and Malafferty, F.W. (1974) The wiley / NBS registry of mass spectral data, John Wiley and Sons, N.Y
  20. Davies, N.W. (1990) Gas chromatographic retention indices of monoterpenes and sesquiterpenes on methyl silicone and carbowax 20M phases. J. Chromatography., 503, 1-24 https://doi.org/10.1016/S0021-9673(01)81487-4
  21. Sadtler Research Laboratories. (1986) The sadtler standard gas chromatography retention Index Library. Sadtler, USA
  22. Chung, M.S. and Lee, M.S. (2003) Analysis of volatile compounds in elsholtzia splendens by solid phase microextraction. Korean J. Soc. Food Cookery Sci., 19, 79-82
  23. Kim, Y.S., Park, E.R. and Kim, K.S. (2003) Volatile components of chestnut flower. J Korean. Soc. Food Sci Nutr., 32, 801-805 https://doi.org/10.3746/jkfn.2003.32.6.801
  24. Javier Mateo, Mercedes Aguirrezabal, Concepcion Dominguez and Jose Maria Zumalacarregui. (1997) Volatile compounds in spanish paprika. J. Food Composition and Analysis., 10, 225-232 https://doi.org/10.1006/jfca.1997.0535
  25. Kim, Y.S. and Oh, H.I. (1993) Volatile flavor components of traditional and commercial kochujang. Korean J. Food Sci. Technol., 25, 494-501
  26. Jun, H.R. and Kim, Y,S (2002) Comparison of volatile compounds in red pepper( Capsicum annuum L.)powders from different origins. Food Sci. Biotechnol., 11, 293-302
  27. Pipen, E.L., Mecchi, E.P. and Nonaka, M. (1969) Origin and nature of aroma in fat of cooked poultry. J. Food Sci., 34, 436-442 https://doi.org/10.1111/j.1365-2621.1969.tb12799.x
  28. Park, J.Y., Kim, O.C and Kim, Y.H. (1986) Formation volatile compounds by the thermal degradation of $\beta$-carotene J Agric. Chem., 29, 260-265 https://doi.org/10.1021/jf00104a013
  29. Kim, H., Cho, W.J., Jung, Y.J., Lee, Y.M., Jeong, E.J., Yoo, Y.J., Byun, M.W. and Cha, Y.J. (2002) Irradiation-induced volatile compounds in irradiated chicken by P&T method. J. Korean Soc. Food Sci. Nutr., 31, 958-964 https://doi.org/10.3746/jkfn.2002.31.6.958