DOI QR코드

DOI QR Code

Effect of Heat-Treatment on the Optical Properties of Self-Assembled SiO2 Photonic Crystals

자기조립을 통해 형성된 실리카 광자결정의 광특성에 미치는 열처리 효과

  • O, Yong-Taeg (Department of Advanced Materials Engineering, Chosun University) ;
  • Kim, Myung-Soon (Department of Chemistry, Chosun University) ;
  • Shin, Dong-Chan (Department of Advanced Materials Engineering, Chosun University)
  • Published : 2005.02.01

Abstract

We examined the effect of low temperature heat-treatment on the optical properties of the photonic crystals self-assembled using a monodispersed spherical $SiO_2$ nanoparticle. When the heat treatment temperature increased, the reflectance peak, which is induced by the photonic band gap, moved to a shorter wavelength direction, and the peak intensity of Fabry-Perot fringes also increased. The highest reflectance peak intensity was obtained in the sample heat-treated at $250\~300^{\circ}C$. The heat-treatment reduced the average particle size and the quantity of defects, and increased the packing density of the photonic crystal.

열처리가 단분산 구형 $SiO_2$ 나노 분말의 자기조립을 통하여 형성된 광자결정 박막의 광특성에 미치는 영향에 대하여 조사하였다. 광밴드갭에 의해 나타나는 반사율 피크는 열처리 온도가 증가함에 따라 단파장 쪽으로 이동하였고, 빛의 회절에 의해 나타나는 Fabry-Perot fringes 피크의 강도도 증가하였다. 또한, 반사율의 절대값도 $250\~300^{\circ}C$ 사이에서 열처리한 시편에서 가장 높은 값을 나타내었다. 미세구조 분석에 따르면 저온열처리를 통하여 입자크기와 결함량이 줄어들고 결정의 치밀도는 증가하였다.

Keywords

References

  1. E. Yablonovitch, 'Inhibited Spontaneous Emission in Solid State Physics and Electronics,' Phys. Rev. Lett., 58 2059-62 (1987) https://doi.org/10.1103/PhysRevLett.58.2059
  2. C. Lopez, 'Materials Aspects of Photonic Crystals,' Adv. Mater., 15 1679-704 (2003) https://doi.org/10.1002/adma.200300386
  3. E. Yablonovitch and T. J. Gmitter, 'Photonic Band Structures : The Face-Centered Cubic Case,' Phys. Rev. Lett., 63 1950-54 (1989) https://doi.org/10.1103/PhysRevLett.63.1950
  4. T. F. Krauss and R. M. De La Rue, 'Photonic Crystals in the Optical Regime-Past, Present and Future,' Progress in Quantum Electronics, 23 51-96 (1999)
  5. S. H. Im, Y. T. Lim, D. J. Suh, and O. O. Park, 'Three-Dimensional Self-Assembly of Colloids at a Water-Air Interface : A Novel Technique for the Fabrication of Photonic Band Gap Crystals,' Adv. Mater., 14 1367-69 (2002) https://doi.org/10.1002/1521-4095(20021002)14:19<1367::AID-ADMA1367>3.0.CO;2-U
  6. E. Palacios-Lidon, A. Blanco, M. Ibisate, F. Meseguer, and C. Lopez, 'Optical Study of the Full Photonic Band Gap in Silicon Inverse Opals,' Appl. Phys. Lett., 81 4925-27 (2002) https://doi.org/10.1063/1.1530752
  7. Y. Xia, B.Gates, Y. Yin, and Y. Lu, 'Monodispersed Colloidal Spheres: Old Materials with New Applications,' Adv. Mater., 12 693-713 (2000) https://doi.org/10.1002/(SICI)1521-4095(200005)12:10<693::AID-ADMA693>3.0.CO;2-J
  8. P. Jiang, J. F. Bertone, K. S. Hwang, and V. L. Colvin, 'Single-Crystal Colloidal Multilayers of Controlled Thickness,' Chem. Mater., 11 2132-40 (1999) https://doi.org/10.1021/cm990080+
  9. Y.-H. Ye, F. LeBlanc, A. Hache, and V.-V. Truong, 'Self-Assembling Three-Dimensional Colloidal Photonic Crystal Structure with High Crystalline Quality,' Appl. Phys. Lett., 78 52-4 (2001) https://doi.org/10.1063/1.1337619
  10. W. Stober, A. Fink, and E. Bohn, 'Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range,' J. Colloid and Interface Sci., 26 62-9 (1968) https://doi.org/10.1016/0021-9797(68)90272-5
  11. K.-S. Kim and W.-S. Kim, 'Study on Nucleation and Growth Rates of $SiO_2$ Particles in the Supersaturation Solution Produced by TEOS,' Hwak Konghak, 37 56-63 (1999)
  12. H. Ko, H.-W. Lee, J.-S. Kim, and J. Moon, 'Process Development of Self-Assembled Monolayers (SAMs) of Colloidal Particles,' J. Kor. Ceram. Soc., 39 981-87 (2002) https://doi.org/10.4191/KCERS.2002.39.10.981
  13. M. S. Kim, S. J. Hong, Y. T. O, B. G. Lee, and D. C. Shin, 'Optical Properties of a $SiO_2$ Photonic Crystal Layer Fabricated by Seeded Growth of Spherical Nanoparticle,' The 21th Korea-Japan International Seminar on Ceramics, 387 (2004)
  14. Y.-H. Ye, S. Badilescu, and V.-V. Truong, 'Large-Scale Ordered Macroporous $SiO_2$ Thin Films by a Template-Directed Method,' Appl. Phys. Lett., 81 613-18 (2002) https://doi.org/10.1063/1.1495525
  15. K. P. Velikov, T. van Dillen, A. Ploman, and A. van Blaaderen, 'Photonic Crystals of Shape-Anisotropic Colloidal Particles,' Appl. Phys. Lett., 81 838-40 (2002) https://doi.org/10.1063/1.1497197
  16. H. Miguez, C. Lopez, F. Meseguer, A. Blanco, L. Vazquez, and R. Mayoral, 'Photonic Crystal Properties of Packed Submicrometric $SiO_2$ Spheres,' Appl. Phys. Lett., 71 1148-50 (1997) https://doi.org/10.1063/1.119849
  17. H. Miguez, C. Lopez, F. Meseguer, A. Blanco, L. Vazquez, and R. Mayoral, 'Photonic Crystal Properties of Packed Submicrometric $SiO_2$, Spheres,' Appl. Phys. Lett., 71 1148-50 (1997) https://doi.org/10.1063/1.119849