DOI QR코드

DOI QR Code

Electrical Properties of Sol-Gel Derived Ferroelectric Bi3.35Sm0.65Ti3O12 Thin Films

  • Kang, Dong-Kyun (Department of Materials Science and Engineering, Korea University) ;
  • Cho, Tae-Jin (Department of Materials Science and Engineering, Korea University) ;
  • Kim, Byong-Ho (Department of Materials Science and Engineering, Korea University)
  • Published : 2005.03.01

Abstract

Ferroelectric $Bi_{3.35}Sm_{0.65}Ti_{3}O_{12}(BSmT)$ thin films were synthesized by sol-gel process. In this experiments, $Bi(TMHD)_{3},\;Sm_{5}(O^{i}Pr)_{13},\;Ti(O^{i}Pr)_4$ were used as precursors, which were dissolved in 2-methoxyethanol. The BSmT thin films were deposited on the Pt/TiO/SiO/Si substrates by spin-coating. Thereafter, the thin films with the thickness of 240 nm were annealed from 600 to $720^{\circ}C$ in oxygen atmosphere for 1 h, and post-annealed in oxygen atmosphere for 1 h after deposition of Pt electrode to enhance the electrical properties. To investigate the effects of Sm-substitution in the BTO thin films, the BTO and BSmT thin films were prepared, respectively. The remanent polarization and coercive voltage of the BSmT thin films annealed at $720^{\circ}C$ were $19.48{\mu}C/cm^2$ and 3.40 V, respectively.

Keywords

References

  1. C. A-Paz de Arujo, J. D. Cuchiaro, L. D. McMillan, M. C. Scott, and J. F. Scott, 'Fatigue-Free Ferroelectric Capacitors with Platinum Electrode,' Nature, 374 627-29 (1995) https://doi.org/10.1038/374627a0
  2. B. H. Park, B. S. Kang, S. B. Bu, T. W. Noh, J. Lee, and W. Jo, 'Lanthanum-Substituted Bismuth Titanate for Use in Non-Volatile Memories,' Nature, 401 [14] 682-84 (1999) https://doi.org/10.1038/44352
  3. T. Watanabe, T. Sakai, K. Sakai, K. Saito, and H. Funakubo, 'Film Thickness Dependence of Ferroelectric Properties of c-Axis-Oriented Epitaxial $Bi_4Ti_3O_12$ Thin Films Prepared by Metalorganic Chemical Vapor Deposition,' J. of Appl. Phys., 89 [7] 3934-38 (2001) https://doi.org/10.1063/1.1352566
  4. D. Wu, A. Li, T. Zhu, Z. Li, Z. Liu, and N. Ming, 'Processing and Composition-Dependent Characteristics of Chemical Solution Deposited $Bi_{4-x}La_xTi_3O_12$ Thin Films,' J. of Mater. Res., 16 1325-32 (2001) https://doi.org/10.1557/JMR.2001.0185
  5. Y. Ding, J. S. Liu, H. X. Qin, J. S. Zhu, and T. N. Wang, 'Why Lanthanum-Substituted Bismuth Titanate Becomes Fatigue Free in a Ferroelectric Capacitor with Platinum Electrodes,' Appl. Phys. Lett., 78 [26] 4175-77 (2001) https://doi.org/10.1063/1.1381038
  6. U. Chon and J. S. Shim, 'Ferroelectric Properties and Crystal Structure of Praseodymium-Modified Bismuth Titanate,' J. of Appl. Phys., 93 [8] 4769-75 (2003) https://doi.org/10.1063/1.1561585
  7. H. Uchida, I. Okada, H. Matsuda, T. Iijima, T. Watanabe, and H. Funakubo, 'Fabrication of Ion-Cosubstituted Bismuth Titanate Thin Films by Chemical Solution Deposition Method,' Integrated Ferroelectrics, 52 41-54 (2003) https://doi.org/10.1080/10584580390254105
  8. U. Chon, K. B. Kim, H. M. Jung, and G. C. Yi, 'FatigueFree Samarium-Modified Bismuth Titanate $Bi_{4-x}Sm_xTi_3O_12$ Film Capacitors having Large Spontaneous Polarizations,' Appl. Phys. Lett., 79 [19] 3137-39 (2001) https://doi.org/10.1063/1.1415353
  9. T. Watanabe, H. Funakubo, K. Saito, R. Suzuki, M. Fujimoto, M. Osada, Y. Noguchi, and M. Miyayama, 'Preparation and Characterization of a-and b-Axis-Oriented Epitaxially Grown $Bi_4Ti_3O_12$-Based Thin Films with Long-Range Lattice Matching,' Appl. Phys. Lett., 81 [9] 1660-62 (2002) https://doi.org/10.1063/1.1503850
  10. Y. W. So, B. S. Kang, S. A. Seo, D. J. Kim, T. W. Noh, and J. G. Yoon, 'Effects of Lanthanide Dopants on the Ferroelectric Property of $Bi_4Ti_3O_12$ Thin Films,' Ferroelectrics, 271 347-52 (2002) https://doi.org/10.1080/713716167