Discrimination of the Heated Coconut Oil using the Electronic Nose

전자코를 사용한 가열처리 야자유의 판별

  • Han, Kee-Young (Department of Culinary Art, Seoul Health College) ;
  • Oh, Se-Yeon (KOSMO Scientific Co.,Department of Chemistry, Seoul Women's University) ;
  • Kim, Jung-Hoan (Department of Culinary Art, Seoul Health College) ;
  • Youn, Aye-Ree (Division of Food Science, Seoul Women's University) ;
  • Noh, Bong-Soo (Division of Food Science, Seoul Women's University)
  • 한기영 (서울보건대학 조리예술학과) ;
  • 오세연 (코스모과학,서울여자대학교 화학과) ;
  • 김정환 (서울보건대학 조리예술학과) ;
  • 윤예리 (서울여자대학교 식품과학부) ;
  • 노봉수 (서울여자대학교 식품과학부)
  • Published : 2006.02.01

Abstract

Effect of heat (160, 190, and $220^{\circ}C$ for 24 hr) on coconut oil was examined by principal component analysis using electronic nose consisting of six metal oxide sensors. Increase in heating temperature decreased ratio of resistance and first principal component score (from +0.952 to -0.325), indicating rancidity of coconut oil increased at high heating temperature. Result of electronic nose based on GC with surface acoustic wave sensor showed significant changes in volatile profiles of coconut oil. High resolution olfactory imaging $(VaporPrint^{TM})$ was particularly useful for evaluating oil quality. Peak numbers and areas increased with increasing heating time and temperature (160, $220^{\circ}C$). Electronic nose analysis can provide simple, fast, and straightforward results and is best suited for quality control and process monitoring in flavor field of food industry.

본 연구는 야자유를 190, $220^{\circ}C$에서 24시간 가열한 후 6개의 MOS로 구성된 전자코로 산패정도를 판별하였다. 주성분분석 결과 제1주성분 값이 열처리 시간에 따라 +0.952에서 0.325로 감소하였다. 가열 온도를 높임에 따라 야자유의 산패정도도 증가하였다. 또 다른 방법에 하나로 GC를 바탕으로 한 SAW센서가 부착된 전자코를 사용한 결과 후각이미지가 뚜렷하게 차이가 나는 것을 보여주었다. 160, $220^{\circ}C$에서 가열한 야자유로부터 휘발 성분에 대한 GC peak의 수와 넓이가 가열온도와 가열 처리 시간에 따라 증가함을 보여주었다. 이러한 방법은 신속하면서도 곧바로 알기 쉽게 데이터를 이미지화함으로써 가열 처리된 야자유의 휘발성분을 전자코로 신속하고 간편하게 분석하여 가열 처리 정도가 예측 가능하였다.

Keywords

References

  1. Megremis CJ. Medium chain triglycerides: A nonconventional fat. Food Technol. 45(2): 108-114 (1991)
  2. Kennedy JP. Structured lipids: Fats of the future. Food Technol. 45(11): 76-83 (1991)
  3. Kwon YA, Yoon SH. Concentration of medium chain fatty acids from coconut oil by supercritical $CO_2$ extraction. Food Biotechnol. 5: 229-233 (1996)
  4. Nomani MZA, Forbes BA, Mossaahebi P, Salita CG, Loth-Haglin MJ, Harvey JL, Brooks JL. Supplementation of energy-restricted diets with coconut oil improves nitrogen balance without elevation of blood cholesterol levels. J. Food Sci. 65: 1066-1069 (2000) https://doi.org/10.1111/j.1365-2621.2000.tb09419.x
  5. Hyun YH. The study on the thermal oxidation of mixed rapeseed oil with coconut and palm oil. J. Korean. Soc. Food Sci. Nutr. 15: 342-349 (2002)
  6. Lee BR. Comparison of stability of soybean, corn and palm oils added to soybean milk against accerelated oxidation. Korean J. Oil Chem. Soc. 2: 39-46 (1985)
  7. Chun HN, Kim ZU. Evaluation of soybean oil rancidity by pentanal and hexanal determination. Korean J. Soc. Appl. Biol. Chem. 34: 149-153 (1991)
  8. Chun HN, Kim ZU. Headspace gas chromatographic analysis as an objective method for measuring rancidity in soybean oil. Korean J. Soc. Appl. Biol. Chem. 34: 154-161 (1991)
  9. Choi HD. Use and development of sensation sensor. Bulletin Food Technol. 8: 122-131 (1995)
  10. Biswas S, Heidselmen K. Wohltjin H, Staff C. Differentiation of vegetable oils and detemination of sunflower oil oxidation using a surface acoustic wave sensing device. Food Control. 15: 19-26 (2004) https://doi.org/10.1016/S0956-7135(02)00163-9
  11. Neotronics Scientific Ltd. An Introduction to Electronic Nose Technology. Essex. UK (1996)
  12. Taurino A, Capone S, Distante C, Epifani M, Rella R, Siciliano P. Recognition of olive oils by means of an integrated sol-gel $SnO_2$, electronic nose. Thin Solid Films 418: 59-65 (2002) https://doi.org/10.1016/S0040-6090(02)00596-5
  13. Shen N, Moizuddin S, Wilson L, Duvick S, White P, Pollak L. Relationship of electronic nose analyses sensory evaluation of vegetable oils during storage. J. Am. Oil Chem. Soc. 78: 937-940 (2001) https://doi.org/10.1007/s11746-001-0367-z
  14. Tan TT, Loubet F, Bazzo S. Application of the electronic nose for quality control of edible oils. p. 324. In: The 1998 Pittsburgh Conference. Mar. 11-16, New Orleans. Conference on Analytical Chemistry and Applied Spectroscopy, Inc., Pitsburgh, PA, USA (1998)
  15. Innawong B, Mallikarjunan P, Marcy JE. The determination of frying oil quality using a chemosensory system. Leben.-Wiss.-Technol. 37: 35-41 (2004) https://doi.org/10.1016/S0023-6438(03)00122-1
  16. Muhl M, Demisch HU, Becker F, Kohl CD. Electronic nose for deterioration of frying fat-comparative studies for a new quick test. Eur. J. Lipid Sci. Technol. 102(8/9): 581-585 (2001) https://doi.org/10.1002/1438-9312(200009)102:8/9<581::AID-EJLT581>3.0.CO;2-N
  17. Han KY, Chung JS, Choi EO, Oh SY, Noh BS. Analysis of volatile compounds for sesame oil containing soybean oil using electronic nose. (abstract no P1-8) In: Abstracts: 67th Korean Food Science and Technology Annual Meeting. Oct. 18-20, Jeju National University, Jeju, Korea (2001)
  18. Stella R, Barisci JN, Serra G. Wallace GG. Rossi DD. Characterization of olive oil by an electronic nose based on conducting polymer sensors. Sensors and Actuators B. 63: 1-9 (2000) https://doi.org/10.1016/S0925-4005(99)00510-9
  19. Yang YM, Han KY, Noh BS. Analysis of lipid oxidation of soybean oil using the portable electronic nose. Food Sci. Biotechnol. 9: 146-150 (1998)
  20. Youn AR, Han KY, Kim JH, Oh SY, Noh BS. Discrimination of rancidity for the heated soybean oil using the electronic nose. J. Nat. Sci. Inst., Seoul Women's Univ. 17: 117-130 (2005)
  21. Staples EJ. Dioxin/Furan detection and analysis using a SAW based electronic nose. Available from: http://www.znose.com/tech_papers/papers. Accessed Aug. 12,2005
  22. AOAC. Official Methods of Analysis, 15th ed.. Association of Official Analytical Chemists, Washington D.C., USA (1990)
  23. Youn AR, Han KY, Oh SY, Noh BS. Prediction of rancidity for the heated rapeseed oil using the electronic nose. Food Eng. Progress 9: 309-319 (2005)
  24. Staples EJ. Real time characterization of food and beverages using an electronic nose with 500 orthogonal sensors and Vapor-$Pring^{TM}$ imaging. Available from: http://www.znose.com/tech_papers/ papers/GeneralAnalysis/SenExpo2000C.pdf. Accessed Aug. 12, 2005
  25. Kim MA. Influence of interesterification on the properties of fat and oil in cookery science. PhD thesis, Nara Women's University, Nara, Japan (1988)
  26. Noh BS, Oh SY. Application of electronic nose based on GC with SAW sensor. Food Sci. Ind. 35(3): 50-57 (2002)
  27. Gan HL, Tan CP, Che Man YB, NorAini I, Nazimah SAH. Monitoring the storage stability of RBD palm olein using the electronic nose. J. Agric. Food Chem. 90: 271-282 (2005) https://doi.org/10.1016/j.foodchem.2003.07.038
  28. Guadarrama A, Rodriguez-Mendez ML, Sanz C, Rios JL, de Saja JA. Electronic nose based on conducting polymers for the quality control of the olive oil aroma: Discrimination of quality, variety of olive and geographic origin. Anal. Chem. Acta. 432: 283-293 (2001) https://doi.org/10.1016/S0003-2670(00)01383-0
  29. Che Man YB, Gan HL, NorAini I, Nazimah SAH, Tan CP. Detection of lard adulteration in RBD palm olein using the electronic nose. J. Agric. Food Chem. 90: 829-835 (2005) https://doi.org/10.1016/j.foodchem.2004.05.062
  30. Gan HL, Che Man YB, Tan CP, NorAini I, Nazimah SAH. Characterization of vegetable oil by surface acoustic wave sensing electronic nose. J. Agric. Food Chem. 89: 507-518 (2005) https://doi.org/10.1016/j.foodchem.2004.03.005