DOI QR코드

DOI QR Code

Magnetic Susceptibility of the Single Crystal MnF2(1.5% EuF3)

단결정 MnF2(1.5% EuF3)의 자기 감수율

  • Lee, Jun-Young (Department of Physics, College of Liberal Arts and Sciences, Yonsei University) ;
  • Nahm, Kyun (Department of Physics, College of Liberal Arts and Sciences, Yonsei University) ;
  • Kim, Chul-Koo (Institute of Physics and Applied Physics, Yonsei University)
  • 이준영 (연세대학교 물리학과) ;
  • 남균 (연세대학교 물리학과) ;
  • 김철구 (연세대학교 물리 및 응용물리 사업단)
  • Published : 2006.10.31

Abstract

In order to investigate the magnetic properties of Eu ions in the single crystal $MnF_2$, the temperature dependent magnetic susceptibilities of the antiferromagnetic $MnF_2$ and the single crystal $MnF_2$(1.5% $EuF_3$) with the rutile structures were measured in the temperature range from 4K to 300K. The detailed analysis of the measured susceptibilities showed that the magnetic susceptibility by the doping of the small amount $EuF_3$ in the antiferromagnetic single crystal $MnF_2$ follows the antiferromagnetic Curie-Weiss law with the negative paramagnetic Curie temperature similarly as in $MnF_2$. It was also found that Eu ion has +3 valence. This solves the long standing discrepancy on this problem.

Rutile 구조를 가진 반강자성체 $MnF_2$내에서 Eu의 자기적 성질을 알아내기 위해 단결정 $MnF_2$(1.5% $EuF_3$)의 자기 감수율을 $4{\sim}300K$사이의 온도 구간에서 측정했다. 측정된 자기 감수율의 분석을 통해서 $EuF_3$의 첨가로 추가되는 자기 감수율 역시 $MnF_2$와 마찬가지로 상자성 큐리 온도가 -값을 가지는 반강자성 Curie-Weiss 법칙을 만족하는 것을 확인했다. 또한 Eu의 경우 +3가를 띄고 있는 것을 확인하여 기존의 일치되지 않는 연구들의 문제점을 해결했다.

Keywords

References

  1. Iberio de P. R. Moreira, R. Dovesi, C. Roetti, Victor R. Saunders, and R. Orlando, Phys. Rev. B, 62, 7816 (2000) https://doi.org/10.1103/PhysRevB.62.7816
  2. B. A. Wilson and W. M. Yen, Phys. Rev. B, 19, 4238 (1979) https://doi.org/10.1103/PhysRevB.19.4238
  3. J.-S. Kang, K. Nahm, C. K. Kim, C. G. Olson, J. Pelzl, J. H. Shim, and B. I. Min, Phys. Rev. B, 66, 075108 (2002)
  4. R. W. Alexander, Jr. A. E. Hughes, and A. J. Sievers, Phys. Rev. B, 1, 1563 (1970) https://doi.org/10.1103/PhysRevB.1.1563
  5. R. L. Melcher, Phys. Rev B, 2, 733 (1970) https://doi.org/10.1103/PhysRevB.2.733
  6. C. Kittel, Introduction to Solid State Physics p. 467 Seventh Edition, Wiley (1996)
  7. P. Dufek, K. Schwarz, and P. Blaha, Phys. Rev B, 48, 12672 (1993) https://doi.org/10.1103/PhysRevB.48.12672
  8. K. Nahm, J. S. Kim, K. B. Lee, B. Y. Cha, and C. K. Kim, J. of Materials Science Letters, 8, 1003 (1989) https://doi.org/10.1007/BF01730468
  9. R. Job, M. Rosenberg, K. Nahm, and C. K. Kim, Supercond. Sci. Technol., 4, 77(1991) https://doi.org/10.1088/0953-2048/4/2/008
  10. 김철구, 남균, 자성의 이론과 응용, 청문각 page 67 (2004)
  11. F. W.Oliver, D. Seifu, E. Hoffman, C. Williams, and E. Kannan, 43rd Annual Cnference on Magnetism and Magnetic Materials in Miami, Florida. November 9-12 (1998)