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분석방법에 따른 시판 게향료의 휘발성 향기성분 비교

Comparison of Volatile Flavor Compounds in Commercial Crab-like Flavorants by Analyzing Methods

  • 차용준 (창원대학교 식품영양학과) ;
  • 조우진 (창원대학교 식품영양학과) ;
  • 정은정 (창원대학교 식품영양학과)
  • Cha, Yong-Jun (Dept. of Food and Nutrition, Changwon National University) ;
  • Cho, Woo-Jin (Dept. of Food and Nutrition, Changwon National University) ;
  • Jeong, Eun-Jeong (Dept. of Food and Nutrition, Changwon National University)
  • 발행 : 2006.12.01

초록

시판 수입 게향료 4종의 휘발성 향기성분을 SPME법과 LLCE법으로 비교 분석하였다. 동정된 86개의 휘발성 화합물 중 71개가 positive하게 동정되었으며, 이들은 함황화합물류 (13종), 알데히드류(3종), 케톤류(2종), 에스테르류(26종), 알콜류(5종), 방향족화합물류(3종), 테르펜류(8종), 산류(2종) 및 기타화합물류(9종)로 구성되었다. 인조 게향의 분석 및 동정에 있어서는 SPME법이 LLCE법에 비해 검출 감도가 매우 우수함을 알 수 있었고, 산류를 포함한 휘발성이 낮은 화합물들은 LLCE법에서만 검출되었다 제품 A-D의 특성에 따라 화합물의 조성에 차이가 있었으나 대체로 인조 게향에서는 함황 및 함질소화합물류 (dimethyl sulfide, dimethyl disulfide, depropyl disulfide, e(methylthio)propyl acetate, 3-(methylthio)propanal, 3-(methylthio)propanol, 2-methyl-3-(methylthio)pyrazine, 2-methyl-5-(methylthio)pyrazine)와 에스테르류 (styrallyl acetate, ethyl acetate, isoamyl acetate, benzyl acetate, ethyl pentanoate, butyl pentanoate, isoamyl pentanoate, furfuryl acetate) 등이 대표적인 물질로 추정되었다.

Volatile flavor compounds in commercial crab-like flavorants were compared by mean of solid phase microextraction(SPME) and liquid continuous extraction (LLCE)/GC/MSD methods. A total of 86 volatile flavor compounds were detected. Of these, 71 were positively identified consisting mainly of sulfur-containing compounds (13), aldehydes (3), ketones (2), esters (26), alcohols (5), aromatic compounds (3), terpenes (8), acids (2) and miscellaneous compounds (9). SPME method was more effective than LLCE method in detection of volatile components in commercial crab-like flavorants. Eight S-, N-containing compounds such as dimethyl sulfide, dimethyl disulfide, dipropyl disulfide, 3-(methylthio)propyl acetate, 3-(methylthio) propanal, 3-(methylthio) propanol, 2-methyl-3-(methylthio) pyrazine and 2-methyl-5-(methylthio) pyrazine, 8 esters such as styrallyl acetate, ethyl acetate, isoamyl acetate, benzyl acetate, ethyl pentanoate, butyl pentanoate, isoamyl pentanoate and furfuryl acetate were considered as major components in crab-like flavorants.

키워드

참고문헌

  1. Arctander, S. 1969. Perfume and Flavor Chemicals (aroma chemicals) I, II. Montclair, N.J. USA
  2. Cha, Y. J. and H. H. Baek. 1995. Quantitative analysis of alkylpyrazines in snow crab cooker effluents. J. Korean Soc. Food Nutr. 24, 454-458
  3. Cha, Y. J., H. H. Baek and T. C.-Y. Hsieh. 1992. Volatile components in flavour concentrates from crayfish processing waste. J. Sci. Food Agric. 58, 239-248 https://doi.org/10.1002/jsfa.2740580212
  4. Cha, Y. J. and K. R. Cadwallader. 1995. Volatile components in salt-fermented fish and shrimp pastes. J. Food Sci. 60, 19-24 https://doi.org/10.1111/j.1365-2621.1995.tb05597.x
  5. Cha, Y. J., K. R. Cadwallader and H. H. Baek. 1993. Volatile flavor components in snow crab cooker effluent and effluent concentrate. J. Food Sci. 58, 525-530 https://doi.org/10.1111/j.1365-2621.1993.tb04316.x
  6. Cha, Y. J., H. Kim, S. M. Jang and J. Y. Park. 1999. Identification of aroma-active compounds in Korean salt-fermented fishes by aroma extract dilution analysis. 2. Aroma-active components in salt-fermented shrimp on the market. J. Korean Soc. Food Sci. Nutr. 28, 319-325
  7. Cha, Y. J., H. Kim, S. M. Jang and J. Y. Park. 1999. Identification of aroma-active compounds in Korean salt-fermented fishes by aroma extract dilution analysis. 1. Aroma-active components in salt-fermented anchovy on the market. J. Korean Soc. Food Sci. Nutr. 28, 312-318
  8. Cha, Y. J., G. H. Lee and K. R. Cadwallader. 1997. Aroma-active compounds in salt-fermented anchovy, pp. 131-147, In Shahidi, F. and K. R. Cadwallader (eds.), Flavor and Lipid Chemistry of Seafoods, ACS symposium series No. 674, Washington, DC
  9. Cha, Y. J., H. Kim, S. M. Jang and Y. J. You. 1998. Identification of aroma-active compounds in salt-fermented big-eyed herring on the market. J. Korean Soc. Food Sci. Nutr. 28, 1053-1058
  10. Cha, Y. J., H. Kim, S. Y. Park, S. J. Kim and Y. J. Yoo. 2000. Identification of irradiation-induced volatile flavor compounds in beef. J. Korean Soc. Food Sci. Nutr. 29, 1042-1049
  11. Choi, S. H., Y. M. Kim and S. K. Hyun. 2001. Volatile flavor components in boiled snow crab (Chionoecetes japonicus) and its concentrated cooker effluent. J. Food Sci. Nutr. 6, 87-90
  12. Chung, H. Y. and K. R. Cadwallader. 1993. Volatile components in blue crab (Callinectes sapidus) meat and processing by-product. J. Food Sci. 58, 1203-1211 https://doi.org/10.1111/j.1365-2621.1993.tb06148.x
  13. Chung, H. Y. and K. R. Cadwallader. 1994. Aroma extract dilution analysis of blue crab claw meat volitiles. J. Agric. Food Chem. 42, 2867-2870 https://doi.org/10.1021/jf00048a040
  14. Editor. 2001. Flavor industry. The Monthly Food World 2, 62-65
  15. Hayashi T., H. Ishii and A. Shinohara. 1990. Novel model experiment of cooking flavor research on crab leg meat. Food Reviews International, 6, 521-536 https://doi.org/10.1080/87559129009540890
  16. Heath, H. B. and C. Reineccius. 1986. Off-flavors in foods, pp.112-141, In Heath, H. B. and G. Reineccius (eds.), Flavor Chemistry and Technology, Macmillan Pub. England
  17. Hites, R. A. and K. Biemann. 1970. Computer evaluation of continuously scanned mass spectra of gas chromatographic effluents. Anal. Chem. 42, 855-860 https://doi.org/10.1021/ac60290a009
  18. Josephson D. B. and R. C. Lindsay. 1986. Enzymic generation of volatile aroma compounds from fresh fish, pp.201-219, In Parliment T. H. and R. Croteau (eds.) Biogeneration of Aroma, ACS symposium series, No. 317, Washington, DC
  19. Karahadian, C. and R. C. Lindsay. 1989. Role of oxidation in the formation an stability of fish flavors, pp.60-75, In Teranishi, R., R. G. Buttery and F. Shahidi (eds.), Flavor Chemistry: Trends and Developments, ACS symposium series No.388, Washington, DC
  20. Kim, H., J. S. Ahn, Y. M. Sin, Y. J. Lee, K. H. Lee, M. W. Byun and Y. J. Cha. 2005. Identification of irradiation-induced volatile marker compounds in irradiated red pepper powder. J. Korean Soc. Food Sci. Nutr. 34, 236-242 https://doi.org/10.3746/jkfn.2005.34.2.236
  21. KSFSN. 2000. Handbook of Experiments in Food Science and Nutrition. Food Science Part. The Korean Society of Food Science and Nutrition ed., pp.263-276. Hyoil Press Seoul
  22. Matiella J. E. and T. C.-Y. Hsieh. 1990. Analysis of crab meat volatile compounds. J. Food Sci. 55, 962-966 https://doi.org/10.1111/j.1365-2621.1990.tb01575.x
  23. Nonato, E. A., F. Carazza, F. C. Silva, C. R. Carvalho and Z. de L. Cardeal. 2001. A headspace solid-phase micro-extraction method for the determination of some secondary compounds of brazilian sugar cane spirits by gas chromatography. J. Agric. Food Chem. 49, 3533-3539 https://doi.org/10.1021/jf000896r
  24. Vercellotti, J. R., J. W. Kuan, A. M. Spanier and St. A. J. Angelo. 1989. Theramal generation of sulfur-containing flavor compounds in beef, pp.452-459, In Parliment T. H., R. J. McGorrin and C. T. Ho (eds.), Thermal Generation of Aromas, ACS symposium series, No. 409, Washington, DC

피인용 문헌

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