DOI QR코드

DOI QR Code

Electrical and Optical Characteristics of ZnO:Al Films Prepared by rf Magnetron Sputtering for Thin Film Solar Cells Application

rf 마그네트론 스파터법에 의해 제조된 태양전지용 ZnO:Al 박막의 전기 광학적 특성

  • Jeon, Sang-Won (Solar Cells Research Center, Korea Institute of Energy Research (KIER)) ;
  • Lee, Jeong-Chul (Solar Cells Research Center, Korea Institute of Energy Research (KIER)) ;
  • Park, Byung-Ok (Dep. of Inorganic Materials Engineering, Kyungpook National University) ;
  • Song, Jin-Soo (Solar Cells Research Center, Korea Institute of Energy Research (KIER)) ;
  • Yoon, Kyung-Hoon (Solar Cells Research Center, Korea Institute of Energy Research (KIER))
  • 전상원 (한국에너지기술연구원 태양전지연구센터) ;
  • 이정철 (한국에너지기술연구원 태양전지연구센터) ;
  • 박병옥 (경북대학교 무기재료공학과) ;
  • 송진수 (한국에너지기술연구원 태양전지연구센터) ;
  • 윤경훈 (한국에너지기술연구원 태양전지연구센터)
  • Published : 2006.01.27

Abstract

ZnO:Al(AZO) films prepared by rf magnetron sputtering on glass substrate and textured by post-deposition chemical etching were applied as front contact and back reflectors for ${\mu}c$-Si:H thin film solar cells. For the front transparent electrode contact, AZO films were prepared at various working pressures and substrate temperature and then were chemically etched in diluted HCl(1%). The front AZO films deposited at low working pressure(1 mTorr) and low temperature ($240^{\circ}C$) exhibited uniform and high transmittance ($\geq$80%) and excellent electrical properties. The solar cells were optimized in terms of optical and electrical properties to demonstrate a high short-circuit current.

Keywords

References

  1. K. L. Chopra, S. Major and D. K. Pandya, Thin Solid Films, 102, 1 (1983) https://doi.org/10.1016/0040-6090(83)90256-0
  2. C. M. Lampert, Energy research 7, 359 (1983) https://doi.org/10.1002/er.4440070407
  3. J. C. Manifacier, L. Szepessy, J. F. Bresse, M. Perotin and R. Stuck, Mater. Res. Bull., 14, 109 (1979) https://doi.org/10.1016/0025-5408(79)90238-1
  4. A. Yamada, Wilson W. Wenas and M. Yoshino, Jpn. J. Appl. Phys., 30, L1152 (1991) https://doi.org/10.1143/JJAP.30.L1152
  5. K. T. R. Reddy, H. Gopalaswamy, P. J. Reddy and R. W. Miles, J. Cryst. Growth, 210, 516 (2000) https://doi.org/10.1016/S0022-0248(99)00868-4
  6. Y. R. Ryu, S. Zhu, D. C. Look, J. M. Wrobel, H. M. Jeong and H. W. White, J. Cryst. Growth, 216, 330 (2000) https://doi.org/10.1016/S0022-0248(00)00437-1
  7. M. Chem, Z. L. Pei, C. Sun, J. Gong, R. F. Hung and L. S. Wen, Mater. Sci. Eng., B, Solid state mater. Adv. Technol., 85, 212 (2001) https://doi.org/10.1016/S0921-5107(01)00584-0
  8. I. Stambolova. K. Konstantinov, S. Vassilev and P. Peshev, Ts. Tsacheva, Mater. Chem. Phus., 63, 104 (2000) https://doi.org/10.1016/S0254-0584(99)00193-5
  9. M. A. Martimez, J. Herero and M. T. Gutierez, Sol. Energy Mater. Sol. cells, 45, 75 (1997). https://doi.org/10.1016/S0927-0248(96)00066-9
  10. J. S. Song, I. J. Park and K. H. Yoon, W. Y. Cho, J. Korean Phys. Soc, 29, 219 (1996)
  11. M. Yoshino, Wilson W. Wenas, A. Yamada, M. Konagai and K. Takahasi, Jpn. J. Appl. Phys, 32, 726 (1993) https://doi.org/10.1143/JJAP.32.726
  12. L. J. Meng and M. P. Dos santos, Thin Solid films, 250, 26 (1994) https://doi.org/10.1016/0040-6090(94)90159-7
  13. D. E. Brodie, R. Singh, J. Morgan, J. D. Leslie, C. J. More, and E. E. Dixon, Proc. 12th IEEE Photovoltaic Specialists Conf., 1980, New York, p. 468 https://doi.org/10.1109/PVSC.1990.111667
  14. O.kluth, B. Rech, L. Houben, S. Wieder, G. Schope, C. beneking, H. Wagner, A. Lffl and H. W. Shock, Thin Solid Films, 351, 247 (1999) https://doi.org/10.1016/S0040-6090(99)00085-1
  15. J. Mller, O. Kluth, S. Wieder, H. Siekmann, G. Schpe, W. Reetz, O.Vetterl, D. Lundszien, A. Lambertz, F. Finger, B. Rech and H. Wagner, Sol. Energy Mater. Sol. Cell, 66, 275 (2001) https://doi.org/10.1016/S0927-0248(00)00184-7
  16. J. A. Anna, Selven, K. Keppner and A. Shan, Mater. Res. Soc. Smp. Proc., 426, 497 (1997)
  17. A. Loffl, S. Wieder, B. Rech, O. kluth, C. Beneking and H. Wagner, Proc. 14th Eur. PV Sol. Energy Conf., Barcelona, 2089, (1997)
  18. K. Ellmer, R. Cebulla and R. Wendt, Thin Soild Films, 317, 413 (1998) https://doi.org/10.1016/S0040-6090(97)00633-0
  19. O. kluth, G. Schope, J. Hupkes, C. Agashe, J. Muller and B. Rech, Thin Solid Films, 442, 80 (2003) https://doi.org/10.1016/S0040-6090(03)00949-0
  20. B.S. Yu, E.S. Kim, S.W. Yoo and J.H. Lee, J. Kor. Ceram. Soc., 32, 799 (1996)
  21. B. Cullity. 'Elements of X-ray Diffracion', Addison-Wesley, London, 99 (1959)
  22. Choi, J, H and Cho, N, H, Korean J. Cryst., 10(2), 136 (1999)