Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Effect of High-Temperature Spinning and PVP Additive on the Properties of PVDF Hollow Fiber Membranes for Microfiltration

  • Cha, Bong-Jun (Division of Environmental Engineering and Biotechnology, Myongji University) ;
  • Yang, Jung-Mok (Division of Environmental Engineering and Biotechnology, Myongji University)
  • Published : 2006.12.31
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Abstract

The effect of high-temperature spinning and poly(vinyl pyrrolidone) (PVP) additive on poly(vinylidene fluoride) (PVDF) hollow fiber membranes was investigated using differential scanning calorimetry, X-ray diffraction measurement, and scanning electron microscopy, together with the corresponding microfiltration performances such as water flux, rejection rate, and elongational strength. Using high-temperature spinning, porous hollow fiber membranes with particulate morphology were prepared through PVDF crystallization. The particulate structure of the membranes was further modified by the addition of miscible PVP with PVDF. Due to these effects, the rejection rate and strength of the fibers were increased at the expense of reduced water flux and mean pore size, which indicates that high-temperature spinning and PVP addition are vary effective to control the morphology of PVDF hollow fiber membranes for microfiltration.

Keywords

References

  1. P. Witte, P. J. Dijkstra, J. W. A. Berg, and J. Feijen, J. Membrane Sci., 117, 1 (1996) https://doi.org/10.1016/0376-7388(96)00088-9
  2. D. -J. Lin, K. Beltsios, T. -H. Young, Y. -S. Jeng, and L. -P. Cheng, J. Membrane Sci., 274, 64 (2006) https://doi.org/10.1016/j.memsci.2005.07.043
  3. L. -P. Cheng, T. -H. Young, L. Fang, and J. -J. Gau, Polymer, 40, 2394 (1999)
  4. X. Tan, S. P. Tan, W. K. Teo, and K. Li, J. Membrane Sci., 271, 153 (1998)
  5. M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic, Dordrecht, The Netherlands, 1992
  6. L. Y. Lafreniere, F. D. F. Talbot, T. Matsuura, and S. Sourirajan, Ind. Eng. Chem. Res., 26, 2385 (1987) https://doi.org/10.1021/ie00071a035
  7. M.-C. Yang and T. -Y. Liu, J. Membrane Sci., 226, 119 (2003) https://doi.org/10.1016/j.memsci.2003.08.013
  8. C. Hying and E. Staude, J. Membrane Sci., 144, 251 (1998) https://doi.org/10.1016/S0376-7388(98)00059-3
  9. J. -J. Qin, F. -S. Wong, Y. Li, and Y. -T. Liu, J. Membrane Sci., 211, 139 (2003) https://doi.org/10.1016/S0376-7388(02)00415-5
  10. J. H. Kim, J. E. You, and C. K. Kim, Macromol. Res., 10, 209 (2002) https://doi.org/10.1007/BF03218307
  11. D. Wang, K. Li, and W. K. Teo, J. Membrane Sci., 163, 211 (1999) https://doi.org/10.1016/S0376-7388(99)00181-7
  12. B. J. Cha, K. Char, J. -J. Kim, S. S. Kim, and C. K. Kim, J. Membrane Sci., 108, 219 (1995) https://doi.org/10.1016/0376-7388(95)00171-9
  13. H. Matsuyama, H. Okafuji, T. Maki, M. Teramoto, and N. Kubota, J. Membrane Sci., 223, 119 (2003) https://doi.org/10.1016/S0376-7388(03)00314-4
  14. B. T. Kim, K. Song, and S. S. Kim, Macromol. Res., 10, 127 (2002) https://doi.org/10.1007/BF03218302
  15. K. Tan and S. K. Obendorf, J. Membrane Sci., 274, 150 (2006) https://doi.org/10.1016/j.memsci.2005.08.004
  16. J. W. Cho, H. Y. Song, and S. Y. Kim, Polymer, 34, 1024 (1993) https://doi.org/10.1016/0032-3861(93)90224-X
  17. B. S. Kim, S. T. Baek, K. W. Song, I. H. Park, J. O. Lee, and N. Nemoto, J. Macromol. Sci., B43, 741 (2004)
  18. M. Tazaki, R. Wada, M. Okabe, and T. Homma, J. Appl. Polym. Sci., 65, 1517 (1997) https://doi.org/10.1002/(SICI)1097-4628(19970822)65:8<1517::AID-APP9>3.0.CO;2-J
  19. B. J. Cha, J. M. Yang, Y. J. Choi, and H. Kim, J. Membrane Sci., submitted
  20. L.-P. Cheng, Macromolecules, 32, 6668 (1999) https://doi.org/10.1021/ma990418l
  21. Z. H. Liu, Ph. Marechal, and R. Jerome, Polymer, 37, 5317 (1996) https://doi.org/10.1016/0032-3861(96)00423-5
  22. S. Hietala, S. Holmberg, M. Karjalainen, J. Nsman, M. Paronen, P. Serima, F. Sundhole, and S. Vahvaselk, J. Mater. Chem., 7, 721 (1997) https://doi.org/10.1039/a607675k
  23. B.-E. E. Mohajir and N. Heymans, Polymer, 42, 5661 (2001) https://doi.org/10.1016/S0032-3861(01)00064-7
  24. F. A. Landis and R. B. Moore, Macromolecules, 33, 6031 (2000) https://doi.org/10.1021/ma000636a
  25. N. Chen and L. Hong, Polymer, 43, 1429 (2002) https://doi.org/10.1016/S0032-3861(01)00671-1
  26. M. A. Sabino, S. Gonzalez, L. Maequez, and J. L. Feijoo, Polym. Degrad. Stabil., 69, 209 (2000) https://doi.org/10.1016/S0141-3910(00)00062-8