대한환경공학회지 (Journal of Korean Society of Environmental Engineers)

  • 제28권2호
  • /
  • Pages.173-177
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  • 2006
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  • 1225-5025(pISSN)
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  • 2383-7810(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
권호 표지

중성 pH조건에서 철($Fe^0$)을 이용한 Atrazine의 탈염소화

Dechlorination of Atrazine using Zero Valent Iron($Fe^0$) under Neutral pH Condition

  • 김건하 (한남대학교 공과대학 토목환경공학과) ;
  • 정우혁 (한남대학교 공과대학 토목환경공학과) ;
  • 최승희 (고려대학교 환경정책연구소)
  • Kim, Geon-Ha (Department of Civil and Environmental Engineering, Hannam University) ;
  • Jeong, Woo-Hyeok (Department of Civil and Environmental Engineering, Hannam University) ;
  • Choe, Seung-Hee (Research Institute for Environmental Technology and Sustainable Development, Korea University)
  • 발행 : 2006.02.28
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초록

비점오염원에서 배출되는 농악은 부유물질과 흡착하여 퇴적되며 수체로 유출되어 공공 보건에 위해를 미친다. 본 연구에서는 0가 철이 퇴적물에 포함된 농약의 일종인 아트라진을 분해하는 속도를 구하고자 하였으며 이때 퇴적물의 완충능력을 모사하기 위하여 완충액을 첨가하여 pH를 중성으로 하였다. 아트라진의 초기농도를 10, 30, 50 mg/L로 할 때 아트라진의 감소는 가1차 반응을 따랐으며 반응속도상수 $K_{obs}$는 평균 $3.21{\times}10^{-2}/d$를 나타내었다.

Pesticides from diffuse pollution sources adsorbed in suspended particles flow into surface water and threats to the public health. In this research, dechlorination constants of Atrazine by zero valent iron were measured with addition of buffer solution for simulating buffer capacity of sediment. When initial concentration of Atrazine was 10, 30, and 50 mg/L, their dechlorination was explained using the pseudo-first order reaction. Dechlorination constants $K_{obs}$ were $3.21{\times}10^{-2}/d$ in average.

키워드

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