대한환경공학회지 (Journal of Korean Society of Environmental Engineers)

  • 제28권4호
  • /
  • Pages.402-406
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  • 2006
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  • 1225-5025(pISSN)
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  • 2383-7810(eISSN)
대한환경공학회 (Korean Society of Environmental Engineers)
권호 표지

N-Nitrosodimethylamine(NDMA) 생성에 관한 예측과 비교 연구

Prediction and Comparison for the N-Nitrosodimethylamine(NDMA) Formation

  • 김종오 (목포대학교 환경교육과) ;
  • 김동수 (광주광역시 보건환경연구원)
  • Kim, Jong-O (Department of Environmental Education, Mokpo National University) ;
  • Kim, Dong-Soo (Gwangju City Health and Environment Research Institute)
  • 발행 : 2006.04.30
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초록

본 연구에서는 pH가 7과 8인 조건에서 디메칠아민 농도를 0.05 mM로 고정시키고 클로라민 농도 변화에 따른 NDMA 생성농도를 측정하여 회귀식을 개발하였다. 클로라민/디메칠아민 비율이 1보다 클 때와 작을 때에 NDMA 생성에 큰 차이를 보여 통계분석에서 구분하여 회귀식을 제시하였다. NDMA 생성 농도는 클로라민/디메칠아민 비율에 높은 상관성을 보여 주었다. 개발한 회귀식을 근거로 하여 NDMA 생성 농도를 기존 연구에 적용한 결과 상대오차는 $-79{\sim}163%$로 조사되었다. 상수 처리장에서 원수의 디메칠아민 농도를 알 경우 이 식을 적용 하면 NDMA 발생 범위를 제시하여 주입할 클로라민 농도나 전처리 필요성을 결정하는데 도움을 줄 것으로 생각된다.

N-Nitrosodimethylamine(NDMA) formation was studied as a function of chloramine concentration at a fixed dimethylamine (DMA) concentration of 0.05 mM at pH 7 and 8. Regression equations were developed by molar ratio of chloramine to DMA. The NDMA formation was dependent on molar ratio(chloramine/DMA) and was different when the ratio is less or greater than 1. The formation of NDMA increased with increasing chloramine concentration and a linear correlation was examined between NDMA concentration and the ratio on a log scale. The developed regression was applied to previously reported data and relative errors ranged from -79 to 163%. Regression equations could provide a potential tool to predict NDMA formation for a simple and quick estimation in water supply systems.

키워드

참고문헌

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