Identification Characteristics of Irradiated Dried-Spicy Vegetables by Analyzing Photostimulated Luminescence (PSL), Thermoluminescence (TL) and Electron Spin Resonance (ESR)

방사선조사 건조향신채소의 PSL, TL 및 ESR 검지 특성

  • Kwon Joong-Ho (Depaprtment of Food Science and Technology, Kyungpook National University) ;
  • Kim Mi-Yeung (Depaprtment of Food Science and Technology, Kyungpook National University) ;
  • Kim Byeong-Keun (Depaprtment of Food Science and Technology, Kyungpook National University) ;
  • Lee Jeong-Eun (Depaprtment of Food Science and Technology, Kyungpook National University) ;
  • Kim Dong-Ho (Korea Atomic Energy Research Institute) ;
  • Lee Ju-Woon (Korea Atomic Energy Research Institute) ;
  • Byun Myung-Woo (Korea Atomic Energy Research Institute) ;
  • Lee Chang-Bok (Taekyung Nongsan, Co. Ltd.)
  • Published : 2006.02.01

Abstract

The identification characteristics of inadiated dried onion and garlic at 1, 4 and 7 kGy were investigated by analyzing their photostimulated luminescence (PSL), thermoluminescence (TL) and electron spin resonance (ESR). The PSL results showed that the photon counts of non-irradiated dried onion were less than 700 (negative) and those of irradiated samples at 1kGy or more were over 5000 (positive), making it possible to discriminate non-irradiated onions from irradiated ones. However, the intermediate counts (700-5000) were observed in irradiated garlic at 1 and 4 kGy, even though positive counts were measured in 7 kGy group. Radiation-induced TL glow curves $(TL_1)$ were measured at $150^{\circ}C$ range in both irradiated onion and garlic samples at 1 kGy or more, which could identify irradiated groups. Furthermore, determination of TL ratios $(TL_1/TL_2)$ for both samples could verify the above results. It was found, however, that ESR spectroscopy was not suitable for the detection of irradiated dried onion and garlic.

건조 채소류 중 건조 양파 및 마늘에 대하여 감마선 조사(1,4,7kGy)에 따른 검지특성을 photostimulated luminescence(PSL), thermoluminescence(TL) 및 electron spin resonance (ESR)분석에 의해 확인하였다. PSL분석 결과, 건조 양파 시료는 설정된 negative$(\leq1700)$ 및 Positive$(\geq5000)$ 기준에 맞게 비조사군과 조사군의 차이를 쉽게 확인할 수 있었다. 그러나 건조 마늘의 경우 1 및 4 kGy 조사군은 $700\~5000$ 범위의 photon counts (intermediate)를 보였으나 7kGy 조사군에서는 positive한 결과를 나타내었다. 반면, TL 분석 결과에서는 1kGy 이상으로 조사된 두 시료 모두 $150^{\circ}C$ 전후에서 TL glow curve $(TL_1)$를 나타내어 조사 여부의 확인이 가능하였다. 또한 TL ratio $(TL_1/TL_2)$의 측정은 TL 검지결과의 신뢰성을 높여주었다. ESR 분석에서는 두 시료 모두 비 특이적인 signal이 관찰되어 적용이 불가능한 것으로 나타났다.

Keywords

References

  1. Shin, K.S., Ma, J.S. and Cho, C.H. (1989) Effects of gamma irradiation and ethylene oxide fumigation for the quality preservation of spices and dry vegetables. Kor. J. Food Hygiene, 4, 119-132
  2. UNEP. (1995) Montreal protocol on substances that deplete the ozone layer. Report of the methyl bromide technical options committee, p.294
  3. Kwon, J.H., Chung, H.W. and Kwon, Y.J. (2000) Infrastructure of quarantine procedures for promoting the trade of irradiated foods. Paper presented at Symposium of The Korean Society of Postharvest Science and Technology of Agricultural Products on Irradiation Technology for the Safety of Food and Public Health Industries and Quality Assurance, Daejeon, 13 October, p.209-254
  4. WHO. (1981) Wholesomeness of Irradiated Food, Report of a Joint FAO/IAEA/WHO Expert Committee. Technical Report Series 659, p.7-34
  5. Codex Alimentarius Commission. (1984) Codex General Standard for Irradiated Foods and Recommended International Code of Practice for the Operation of Radiation Facilities Used for the Treatment of Foods, CAC/ VOL, XV, FAO, Rome
  6. IAEA homepage (2002) www.iaea.org/icgfi
  7. KFDA. (2004) Regulation of Food Irradiation. Food Standard Code, The Korea Food and Drug Administration., Seoul. p.126
  8. Oduko, J.M. and Spyrou, N.M. (1990) Thermoluminescence of irradiated foodstuffs. Radiat. Phys. Chem., 36, 603-607
  9. Khan, H. and Delincee, H. (1995) Detection of Radiation Treatment of spices and herbs of asian origin using thermoluminescence of mineral contaminants. Appl. Radiat. Isol., 46, 1071-1075 https://doi.org/10.1016/0969-8043(95)00193-H
  10. Mamoon, A., Zaheer, A. and Abu-Abdullah, S. (1996) Variation in thermoluminescence of irradiated brands of foodstuffs: A test for hygienic quality. Radiat. Phys. Chem., 48, 683-687 https://doi.org/10.1016/0969-806X(95)00049-4
  11. Sanderson, D.C.W., Carmichael, L.A., Riain, S.N., Naylor, J. and Spencer, J.Q. (1994) Luminescence studies to identify irradiated food. Food Science and Technology Today, p.93
  12. Schreiber, G.A. (1996) Thermoluminescence and photostimulated luminescence techniques to indentify irradiated foods. In: Detection Methods for Irradiated Foods, McMurray, C.H., Stewart, E.M., Gray, R. and Pearce, J. (ed), The Royal Society of Chemistry, Cambridge, UK, p.121-123
  13. Raffi, J.J. and Benzaria, S.M. (1993) Identification of irradiated foods by electron spin resonance techniques. J. Radiat. Steril,. 1, 281-304
  14. Raffi, J. and Stocker, P. (1996) Electron paramagnetic resonance detection of irradiated foodstuffs. Appl. Magn. Reson., 10, 357-373 https://doi.org/10.1007/BF03163119
  15. European Committee for Standard. (2002) Detection of irradiated food using photosimulated luminescence. English version of DIN EN 13751
  16. Sanderson, D.. C.W., Carmichael, L.A. and Fisk, S. (1998) Establishing luminescence methods to detect irradiated foods. Food Science and Technology Today, 12, 97-102
  17. Schreiber, G.A. (1996) Thermoluminescence and photostimulated luminescence techniques to identify irradiated foods. In: Detection Methods for Irradiated Foods, McMurray, C.H., Stewart, E.M., Gray, R. and Pearce, J. (eds.), The Royal Society of Chemistry, Cambridge, UK, p.121-123
  18. European Committee for Standard (2001) Detection of irradiated food from which silicate minerals can be isolated. Method by thermoluminescence. English version of DIN EN 1788
  19. Kwon, J.H., Jeong, J.Y., Lee, E.Y., Jo, D.J., Noh, J.E. and Lee, J.E (2002) Multiple detection to identify irradiated brown rice of different origins. Food Sci. Biotechnol., 11, 215-219
  20. Choi, I.D., Byun, M.W., Kwon, J.H. and Kim, D.H. (2004) An application of photo-stimulated luminescence (PSL) and electron spin resonance (ESR) analysis for the irradiated spicy vegetables. Food Sci. Biotechnol., 13, 645-650
  21. Jeong, J.Y., Lee, E.Y. and Kwon, J.H. (2001) The detection of irradiated agricultural commodities by origins with photostimulated luminescence (PSL) analysis. Korean J. Postharvest Sci. Technol., 8, 291-295
  22. Kwon, J.H., Jeong, J.Y. and Chung, H.W. (2002) Thermoluminescence characteristics of minerals from irradiated potatoes of different origins of production. Radiat. Phys. Chem., 63, 415-418 https://doi.org/10.1016/S0969-806X(01)00590-4
  23. Nam, H.S. and Yang, J.S. (2001) Detection of gamma-irradiated spices by ESR spectroscopy. J. Korean Soc. Food Sci. Nutr., 30, 239-242