Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Electrical Transport Properties of Gd0.33Sr0.67FeO3 Ceramics

Gd0.33Sr0.67FeO3 세라믹스의 전기전도 특성

  • Published : 2006.02.01
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Abstract

In this study, the dielectric, magnetic and transport properties of $Gd_{0.33}Sr_{0.67}FeO_3$ have been analyzed. The dielectric loss anomaly was found to be around 170 K. The activation energy corresponding to relaxation process of this dielectric anomaly was 0.17 eV. From the temperature dependence of the characteristic frequency, we concluded that the elementary process of the dielectric relaxation peak observed is correlated with polaron hopping between $Fe^{3+}\;and\;Fe^{4+}$ ions. The electrical resistivity displayed thermally activated temperature dependence above 200 K with an activation energy of 0.16 eV. In addition, the temperature dependence of thermoelectric power and resistivity suggests that the charge carrier responsible for conduction is strongly localized.

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References

  1. G. J. Snyder, C. H. Booth, F. Bridges, R. Hiskes, S. DiCarolis, M. R. Beasley, and T. H. Geballe, 'Local Structure, Transport, and Rare-Earth Magnetism in the Ferrimagnetic Perovskite $Gd_{0.67}Ca_{0.33}MnO_3$,' Phys. Rev. B, 55 6453-59 (1998) and references therein https://doi.org/10.1103/PhysRevB.55.6453
  2. J. W. Park, M. S. Kim, J. G. Park, I. P. Swainson, H. C. Ri, H. J. Lee, K. H. Kim, T. W. Noh, S. W. Cheong, and C. H. Lee, 'Study of Low-Temperature Magnetic Properties of $Nd_{0.7}Sr_{0.3}MnO_3$,' J. Kor. Phys. Soc., 36 412-16 (2000)
  3. J. G. Park, M. S. Kim, H. C. Ri, K. H. Kim, T. W. Noh, and S. W. Cheong, 'Magnetic Properties of $Pr_{0.63}Sr_{0.37}MnO_3$ and $Nd_{0.7}Sr_{0.3}MnO_3$ Single Crystal,' Phys. Rev. B, 60 14804-08 (1999)
  4. G. Chern, W. K. Hsieh, M. F. Tai, and K. S. Hsung, 'High Dielectric Permittivity and Hole-Doping Effect in $La_{1-x}Sr_xFeO_3$,' Phys. Rev. B, 58 1252-56 (1998) and references therein https://doi.org/10.1103/PhysRevB.58.1252
  5. K. S. Roh, K. H. Ryu, and C. H. Yo, 'Nonstoichiometry and Physical Properties of $SrSn_{1-x}Fe_xO_{3-y}$ System,' J. Solid State Chem., 142 288-93 (1999) https://doi.org/10.1006/jssc.1998.8033
  6. J. Matsuno, T. Mizokawa, A. Fujimori, K. Mamiya, Y. Takeda, S. Kawasaki, and M. Takano, 'Photoemission and Hartree-Fock Studies of Oxygen-Hole Odering in Charge- Disproportionated $La_{1-x}Sr_xFeO_3$,' Phys. Rev. B, 60 4605-08 (1999) https://doi.org/10.1103/PhysRevB.60.4605
  7. W. H. Jung, J. H. Sohn, J. H. Lee, J. H. Sohn, M. S. Park, and S. H. Cho, 'Alternating-Current Electrical Properties of $CaMnO_3$ below Néel Temperature,' J. Am. Ceram. Soc., 83 797-801 (2000) and references therein https://doi.org/10.1111/j.1151-2916.2000.tb01277.x
  8. A. I. Mills, 'Cooperative Jahn-Teller Effect and Electron- Phonon Coupling in Stoichiometry and Electronic Properties of $La_{1-x}A_xMnO_3$,' Phys. Rev. B, 53 8434-41 (1996) https://doi.org/10.1103/PhysRevB.53.8434
  9. A. I. Mills, 'Orbital Ordering and Superexchange in Manganites Oxides,' Phys. Rev. B, 55 6405-08 (1997) https://doi.org/10.1103/PhysRevB.55.6405
  10. S. K. Park, T. Ishikawa, Y. Tokura, J. Q. Li, and Y. Matsui, 'Variation of Charge-Ordering Transitions in $R_{1/3}Sr_{2/3}FeO_3$ (R = La, Pr, Nd, Sm, and Gd),' Phys. Rev. B, 60 10788-95 (1999) and references therein https://doi.org/10.1103/PhysRevB.60.10788
  11. T. Ishikawa, S. K. Park, T. Katsufuji, T. Arima, and Y. Tokura, 'Optical Spectroscopy of Charge-Ordering Transition in $La_{1/3}Sr_{2/3}FeO_3$,' Phys. Rev. B, 58, R13326-29 (2000) https://doi.org/10.1103/PhysRevB.58.R13326
  12. C. H. Kim, Y. R. Uhm, and J. C. Sur, 'Mossbauer Studies of Perovskite $Gd_{0.5}Sr_{0.5}FeO_{3-y}$,' J. Kor. Phys. Soc., 37 [4] 447-50 (2000)
  13. Y. P. Lee, V. G. Prokhorov, J. Y. Rhee, K. W. Kim, G. G. Kaminsky, and V. S. Flis, 'The Controlled Charge Ordering and Evidence of the Metallic State in $Pr_{0.65}Ca_{0.35}MnO_3$ Films,' J. Phys.: Condens. Mater., 12 L133-38 (2000) https://doi.org/10.1088/0953-8984/12/6/112
  14. N. Nakamura and E. Iguchi, 'Nonadiabatic Hopping Conduction in $Sr_{1+x}La_{1-x}FeO_4 (0 {\leq} x {\leq} 0.20)$ below 300 K,' J. Solid State Chem., 145 58-64 (1999) https://doi.org/10.1006/jssc.1999.8219
  15. N. Ikeda, K. Kohn, H. Kito, J. Akimitsu, and K. Sirator, 'Dielectric Relaxation and Hopping of Electrons in $ErFe_2O_4$,'; J. Phys. Soc. Jpn., 63 [12] 4556-64 (1994) https://doi.org/10.1143/JPSJ.63.4556
  16. A. Seeger, P. Lunkenheimer, J. Hemberger, A. A. Mukhin, V. Y. Ivanov, A. M. Balbasov, and A. Loid, 'Charge Carrier Localization in $La_{1-x}Sr_xMnO_4$ Investigated by AC Conductivity Measurements,' J. Phys.: Condens. Mater., 11 3273-90 (1999) https://doi.org/10.1088/0953-8984/11/16/009
  17. H. Jhnas, D. Kim, R. J. Rasmussen, and J. M. Honig, 'AC-Conductivity Measurements on $La_2NiO_{4+\delta}$,' Phys. Rev. B, 54 11224-29 (1996)
  18. W. H. Jung and E. Iguchi, 'Electrical Conduction Behaviour in $K_2NiF_4$-Type $Ca_2MnO_{3.98}$ below Room Temperature,' J. Phys. D: Appl. Phys., 31 794-99 (1998) https://doi.org/10.1088/0022-3727/31/7/007
  19. W. H. Jung, 'valuation of Mott's Parameters for Hopping Conduction in $La_{0.67}Ca_{0.33}MnO_3$ above TC,' J. Mater. Sci. Lett., 17 1317-19 (1998) https://doi.org/10.1023/A:1006665200481
  20. S. Wang, K. Li, Z. Chen, and Y. Zhang, 'Small-Polaron Transport in the Zn-Doped Colossal Magnetoresistance Materials $Fe_{1-x}Zn_xCr_2S_4$,' Phys. Rev. B, 61 575-79 (2000) https://doi.org/10.1103/PhysRevB.61.575
  21. T. T. M. Palsta, A. P. Ramirez, S. W. Cheong, B. R. Zegarski, P. Schiffer, and J. Zaanen, 'Transport Mechanisms in Doped $LaMnO_3$ : Evidence for Polaron Formation,' Phys. Rev. B, 56 5140-07 (1997) https://doi.org/10.1103/PhysRevB.56.5140
  22. V. H. Crespi, L. Lu, Y. X. Jia, K. Khazeni, A. Zettle, and M. L. Cohen, 'Thermopower of Single-Crystal $Nd_{1-x}(Sr, Pb)_xMnO_{3-\delta}$,' Phys. Rev. B, 53 14303-08 (1996)