DOI QR코드

DOI QR Code

Characterization of Glass Melts Containing Simulated Low and Intermediate Level Radioactive Waste

  • Jung, Hyun-Su (Department Materials Science and Engineering, Kunsan National University) ;
  • Kim, Ki-Dong (Department Materials Science and Engineering, Kunsan National University) ;
  • Lee, Seung-Heon (Department Materials Science and Engineering, Kunsan National University) ;
  • Kwon, Sung-Ku (Department Materials Science and Engineering, Kunsan National University) ;
  • Kim, Cheon-Woo (Nuclear Environment Technology Institute, Korea Hydro and Nuclear Power Co. Ltd.) ;
  • Park, Jong-Kil (Nuclear Environment Technology Institute, Korea Hydro and Nuclear Power Co. Ltd.) ;
  • Hwang, Tae-Won (Nuclear Environment Technology Institute, Korea Hydro and Nuclear Power Co. Ltd.) ;
  • Ahn, Zou-Sam (Center for High-Rate Nanomanufacturing)
  • Published : 2006.03.01

Abstract

In order to examine the process parameters for the vitrification of Low and Intermediate Level radioactive Waste (LILW) generated from nuclear power plants, measurements of several melt properties was performed for four selected glasses containing simulated waste. Electrical conductivity and viscosity were determined at temperatures ranging from 1123 to $1673^{\circ}C$. The temperature dependences of both properties in the molten state showed a similar behavior in which their values decrease as the temperature increases. The values of the electrical conductivity and viscosity at a temperature of 1423K adopted in an induction cold crucible melter process were $0.27{\sim}0.42$ S/cm and $9.8{\sim}42$ dPas, respectively.

Keywords

References

  1. J. K. Park and M. J. Song, 'Feasibility Study on Vitrification of Low-And Intermediate-Level Waste from Pressurized Water Reactors,' Waste Management, 18 157-67 (1998) https://doi.org/10.1016/S0956-053X(98)00017-8
  2. C. W. Kim and M. J. Song, 'Vitrification of Combustible Dry Active Waste Generated from Korean Nuclear Power Plants,' Jpn. J. Health Phys., 39 [3] 250-56 (2004) https://doi.org/10.5453/jhps.39.250
  3. C. W. Kim, J. Y. Kim, J. R. Choi, P. K. Ji, J. K. Park, S. W. Shin, J. H. Ha, and M. J. Song, 'Characteristics of Vitrification Process and Vitrified Form for Radioactive Waste,' J. Kor. Radioact. Waste Soc., 2 [3] 175-80 (2004)
  4. C. W. Kim, J. R. Choi, P. K. Ji, J. K. Park, S. W. Shin, J. H. Ha, and M. J. Song, 'Development of Vitrification Process for LILW Generated from Nuclear Power Plants,' ICAPP 2005, Korea (2005)
  5. F. G. K. Bauke and W. A. Frank, 'Conductivity Cell for Molten Glasses and Salts,' Glastech. Ber., 49 [7] 157-61 (1976)
  6. J. Hlavae, 'The Technology of Glass and Ceramics: An Introduction,' Elsevier Scientific Publishing Company, pp. 63-70 (1983)
  7. K. D. Kim, 'Resistivity Measurement of Molten Glass and Mixed Alkali Effect in Sodium and Potassium Silicate Glass Melts,' Glass Technol., 36 [1] 27-31 (1995)
  8. G. W. Morey, 'The Properties of Glass,' Reinhold, New York, 1954
  9. W. A. Weyl and E. C. Marboe, 'The Constitution of Glasses, A Dynamic Interpretation,' Vol. II, Wiley Interscience, pp. 1411-15 (1964)
  10. F. Tooley, 'The Handbook of Glass Manufacture,' Vol. II BFI. NY, pp. 937-40 (1974)
  11. J. Hlavae, 'The Technology of Glass and Ceramics: An Introduction,' Elsevier Scientific Publishing Company, pp. 91-3 (1983)
  12. J. T. Littleton, 'Critical Temperature in Silicate Glasses,' Industrial and Engineering Chemistry, 25 [7] 748-55 (1933) https://doi.org/10.1021/ie50283a010
  13. C. L. Babcock, 'Viscosity and Electrical Conductivity of Molten Glasses,' J. Am. Ceram. Soc., 17 329-42 (1934) https://doi.org/10.1111/j.1151-2916.1934.tb19333.x
  14. C. L. Babcock, 'Silicate Glass Technology Methods,' John Wiley & Sons, pp. 179-82 (1977)
  15. R. H. Doremus, 'Glass Science,' John Wiley & Sons, pp. 154-56 (1973)