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Fabrication of Solid Oxide Fuel Cells via Physical Vapor Deposition with Electron Beam: II. Unit Cell Performance

전자빔 물리증착을 이용한 고체 산화물 연료전지의 제조: II. 단전지 성능

  • Kim, Hyoung-Chul (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Park, Jong-Ku (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Jung, Hwa-Young (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Son, Ji-Won (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Kim, Joo-Sun (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Lee, Hae-Weon (Nano-Materials Research Center, Korea Institute of Science and Technology) ;
  • Lee, Jong-Ho (Nano-Materials Research Center, Korea Institute of Science and Technology)
  • 김형철 (한국과학기술연구원 나노재료연구센터) ;
  • 박종구 (한국과학기술연구원 나노재료연구센터) ;
  • 정화영 (한국과학기술연구원 나노재료연구센터) ;
  • 손지원 (한국과학기술연구원 나노재료연구센터) ;
  • 김주선 (한국과학기술연구원 나노재료연구센터) ;
  • 이해원 (한국과학기술연구원 나노재료연구센터) ;
  • 이종호 (한국과학기술연구원 나노재료연구센터)
  • Published : 2006.05.01

Abstract

In this paper, anode supported SOFC with columnar structured YSZ electrolyte was fabricated via Electron Beam Physical Vapor Deposition (EBPVD) method. Liquid condensation process was employed for the preparation of NiO-YSZ substrate and the high power electron beam deposition method was used for the deposition of YSZ electrolyte film. Double layered cathode with LSM-YSZ and LSM was printed on electrolyte via screen-printing method and fired at $1150^{\circ}C$ in air atmosphere for 3 h. The electrochemical performance and the long-term stability of $5{\times}5cm^2$ single cell were investigated with DC current-voltage characteristics and AC-impedance spectroscopy. According to the investigation, $5{\times}5cm^2$ sized unit cell showed the maximum power density of around $0.76W/cm^2$ at $800^{\circ}C$ and maintained the stable performance over 400 h.

Keywords

References

  1. S. C. Singhal and K. Kendall, 'High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications,' Elsevier Ltd. (2003)
  2. N. Q. Minh and T. Takahashi, 'Science and Technology of Ceramic Fuel Cells,' Elsevier Ltd., Amsterdam, The Netherlands (1995)
  3. N. Q. Minh, 'Ceramic Fuel Cells,' J. Am. Ceram. Soc., 76 [3] 563-88 (1993) https://doi.org/10.1111/j.1151-2916.1993.tb03645.x
  4. J. Larminie and A. Dicks, 'Fuel Cells Explained 2nd Edition,' John Wiley & Sons Inc. (2003)
  5. H. Y. Jung, T. W. Roh, J. Kim, H.-W. Lee, H. Ko, K. C. Lee, and J.-H. Lee, 'Power Generating Chracteristics of Anode- Supported SOFC Fabricated by Uni-Axial Pressing and Screen Printing(in Korean),' J. Kor. Ceram. Soc., 41 [6] 456-63 (2004) https://doi.org/10.4191/KCERS.2004.41.6.456
  6. H. Y. Jung, W. S. Kim, S. H. Choi, J. Kim, H.-W. Lee, H. Ko, K. C. Lee, and J.-H. Lee, 'Fabrication of Small SOFC Stack Based on Anode-Supported Unit Cells and Its Power Generating Characteristics(in Korean),' J. Kor. Ceram. Soc., 41 [10] 777-82 (2004) https://doi.org/10.4191/KCERS.2004.41.10.777
  7. H.-W. Lee, H.-Y. Jung, T.-W. Roh, H. Kim, S. H. Choi, W. S. Kim, J. Kim, and J.-H. Lee, 'Recent R&D Activity at KIST to Develop SOFC Stack Using $10{\times}10\;cm^2$ Anode- Supported Cells'; pp. 54-59 in Proceedings of 6th European Solid Oxide Fuel Cell Forum (Lucerne, Switzerland, 2004). Ed. by M. Mogensen, European Fuel Cell Forum, Oberrohrdorf, Switzerland, (2004)
  8. H. Y. Jung, W. S. Kim, S. H. Choi, J. Kim, H.-W. Lee, H. Song, and J.-H. Lee, 'Analysis of Structure-Property Correlation of SOFC Electrodes'; pp. 1380-1386 in Proceedings of 6th European Solid Oxide Fuel Cell Forum (Lucerne, Switzerland, 2004). Ed. by M. Mogensen, European Fuel Cell Forum, Oberrohrdorf, Switzerland, (2004)
  9. H. Kim, M.-S. Koo, J.-K. Park, H. Y. Jung, J. Kim, H.-W. Lee, and J.-H. Lee, 'Fabrication of Solid Oxide Fuel Cells with Electron Beam Physical Vapor Deposition: I. Preparation of Thin Electrolyte Film of YSZ(in Korean),' J. Kor. Ceram. Soc., 43 [2] 85-91 (2006) https://doi.org/10.4191/KCERS.2006.43.2.085