Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Nonlinear, Optical and Luminescent Properties of xK2O-(33.3-x)BaO-16.7TiO2-50SiO2(mole%) Glasses

xK2O-(33.3-x)BaO-16.7TiO2-50SiO2(mole%) 유리의 비선형 광학 및 형광 특성

  • Lee, Hoi-Kwan (Department of Materials Science and Engineering, Dankook University) ;
  • Yoo, Eun-Sung (Department of Materials Science and Engineering, Dankook University) ;
  • Chae, Su-Jin (Department of Materials Science and Engineering, Dankook University) ;
  • Kang, Won-Ho (Department of Materials Science and Engineering, Dankook University)
  • 이회관 (단국대학교 신소재공학과) ;
  • 유은성 (단국대학교 신소재공학과) ;
  • 채수진 (단국대학교 신소재공학과) ;
  • 강원호 (단국대학교 신소재공학과)
  • Published : 2006.09.01
Download PDF
⟨ Previous Next ⟩

Abstract

Transparent glass-ceramics containing fresnoite crystals have been prepared by controlled heat treatment in $K_2O-BaO-TiO_2-SiO_2$ and their nonlinear optical and luminescent properties were investigated using Maker fringe method and Spectrofluorometer. The second harmonic generation was observed in all samples and the values decreased with increasing $K_2O$ content. The luminescence of blue light at ${\sim}482nm$ could be observed and it was shown that the luminescent property was controlled by the $K_2O$ content.

Keywords

References

  1. Y. Tkakhashi, K. Saito, Y. Benino, T. Fujiwara, and T. Komatsu, 'Stoichiometric Crystallized Glasses with Large Second-Order Optical Nonlinearities,' J. Ceram. Soc. Jpn., 122 [5] S1168-72 (2004)
  2. J. Gopalakrishnan, K. Ramesha, K. K. Rangan, and S. Pandey, 'In Search of Inorganic Nonlinear Optical Materials for Second Harmonic Generation,' J. Solid State Chem., 148 75-80 (1999) https://doi.org/10.1006/jssc.1999.8353
  3. T. Takahsashi, Y. Benino, T. Fujiwara, and T. Komatsu, 'Second-Order Optical Nonlinearity of $LaBGeO_5,\;LiBGeO_4$, and $Ba_2TiGe_2O_8$ Crystals in Corresponding Crystallized Glasses,' Jpn. J. Appl. Phys., 41 L1455-58 (2002) https://doi.org/10.1143/JJAP.41.1455
  4. Y. Takahashi, K. Saito, T. Fujiwara, and T. Komatsu, 'Optical Second Order Nonlinearity of Transparent $Ba_2TiGe_2O_8$ Crystallized Glasses,' Appl. Phys. Lett., 82 [2] 223-25 (2002)
  5. A. Halliyal, A. S. Bhalla, R. E. Newnham, and L. E. Cross, $Ba_2TiGe_2O_8\;and\;Ba_2TiSi_2O_8$ Pyroelectric Glass-Ceramics,' J. Mat. Sci., 16 1023-28 (1981) https://doi.org/10.1007/BF00542748
  6. A. Halliyal, A. S. Bhalla, R. E. Newnham, L. E. Gross, and T. R. Gururaja, 'Study of the Piezoelectric Properties of $Ba_2Ge_2TiO_8$ Glass-Ceramics and Single Crystals,' J. Mat. Sci., 17 295-300 (1982) https://doi.org/10.1007/BF00809065
  7. H. K. Lee, Y. S. Lee, A. S. Bhalla, and W. H. Kang, 'Preparation and Properties of Transparent Glass-Ceramics in $xK_2O-(33.3-x)BaO-16.7TiO_2-50SiO_2$ Glasses,' Ferroelectrics, 330 9-18 (2006) https://doi.org/10.1080/00150190600605361
  8. H. K. Lee, Y. S. Lee, A. S. Bhalla, and W. H. Kang, 'The Effect of $K_2O$ in the Glass-Ceramics Based on the $BaOTiO_2-SiO_2$ Glasses,' Mater. Lett., 60 2457-60 (2006) https://doi.org/10.1016/j.matlet.2006.01.018
  9. H. K. Lee, E. S. Yoo, S. J. Chae, and W. H. Kang, 'Surface Crystallization of $BaO-TiO_2-SiO_2$ Glass by a Nd:YAG Laser Irradiation,' J. New Mater. Tech., 12 [1] 97-104 (2005)
  10. H. K. Lee, S. J. Chae, and W. H. Kang, 'Preparation and Crystallization Kinetics of Glass with Ferroelectric Fresnoite Crystal,' J. Microelectron. Packag., 12 [2] 161-66 (2005)
  11. J. Jerphagnon and S. K. Kurtz, 'Maker Fringes: A Detailed Comparison of Theory and Experiment for Isotropic and Uniaxial Crystals,' J. Appl. Phys., 41 [4] 1667-81 (1970) https://doi.org/10.1063/1.1659090
  12. T. Cardinal, E. Fargin, V. Nazabal, G. L. Flem, S. L. Boiteux, and L. Ducasse, 'Glass Local Structure and Optical Nonlinearities of Oxide Glasses,' J. Non-Cryst. Solids, 239 131-38 (1998) https://doi.org/10.1016/S0022-3093(98)00729-7
  13. G. Blasse, 'Fluorescence of Compounds with Fresnoite $(Ba_2TiSi_2O_8)$ Structure,' J. Inorg. Nucl. Chem., 30 2283-84 (1967) https://doi.org/10.1016/0022-1902(68)80233-7
  14. M. Gaft, L. Nagli, G. Waychunas, and D. Weiss, 'The Nature of Blue Luminescence from Natural Benitoite $BaTiSi_3O_9$,' Phys. Chem. Minerals, 31 365-73 (2004)
  15. A. K. Sahu, D. Kumar, O. Parkash, O. P. Thakur, and C. Prakash, 'Effect of $K_2O/BaO$ Ration on Crystallization, Microstructure and Dielectric Properties of Strontium Titanate Borosilicate Glass Ceramics,' Ceramics International, 30 477-83 (2004) https://doi.org/10.1016/S0272-8842(03)00134-2