Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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Adsorption of Amine and Sulfur Compounds by Iron Phthalocyanine Derivatives

철 프탈로시아닌 유도체에 의한 아민 및 황 화합물의 흡착

  • Lee, Jeong-Se (School of Chemical Engineering and Bioengineering, University of Ulsan) ;
  • Park, Jin-Do (Department of Environmental & Life Chemistry, Ulsan College) ;
  • Lee, Hak-Sung (School of Chemical Engineering and Bioengineering, University of Ulsan)
  • 이정세 (울산대학교 생명화학공학부) ;
  • 박진도 (울산과학대학 환경생활화학과) ;
  • 이학성 (울산대학교 생명화학공학부)
  • Published : 2007.10.31
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Abstract

The adsorption capability of iron phthalocyanine derivatives were investigated by means of X-ray diffractometor (XRD), IR (infrared) spectroscopy, scanning electron microscopy (SEM) and temperature programmed desorption (TPD). According to TPD results, iron phthalocyanine derivatives showed two desorption peaks at low temperature ($100{\sim}150^{\circ}C$) and high temperature ($350{\sim}400^{\circ}C$) indicating that there were two kinds of acidities. Tetracarboxylic iron phthalocyanine (Fe-TCPC) have a stronger desorption peak (chemical adsorption) at the high temperature and a weaker desorption peak (physical adsorption) at the low temperature than iron phthalocyanine (Fe-PC). The specific surface areas of Fe-TCPC and Fe-PC were $26.46\;m^2/g\;and\;11.77\;m^2/g$, respectively. The pore volumes of Fe-TCPC and Fe-PC were $0.14\;cm^3/g\;and\;0.06\;cm^3/g$, respectively. The adsorption capability of triethyl amine calculated by breakthrough curve at 220 ppm of equilibrium concentration was 29.2 mmoL/g for Fe-TCPC and 0.8 mmoL/g for Fe-PC. The removal efficiency of dimethyl sulfide of Fe-TCPC and Fe-PC in batch experiment of 225 ppm of initial concentration were 44.9% and 28.9%, respectively. The removal efficiency of trimethyl amine of Fe-TCPC and Fe-PC in batch experiment of 118 ppm of initial concentration were approximately 100.0% and 33.9%, respectively.

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