Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Synthesis of Fe2O3−CoO−Cr2O3−MnO2 Pigments and Coloring in Glazes

Fe2O3−CoO−Cr2O3−MnO2계 안료의 합성 및 유약에서의 발색

  • Shin, Kyung-Hyun (Department of Materials Science & Engineering, Myongji University) ;
  • Lee, Byung-Ha (Department of Materials Science & Engineering, Myongji University)
  • 신경현 (명지대학교 공과대학 신소재공학과) ;
  • 이병하 (명지대학교 공과대학 신소재공학과)
  • Published : 2007.10.31
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Abstract

Synthesis and characterization of pigments by using $Fe_2O_3,\;CoO,\;Cr_2O_3\;and\;MnO_2$ were undertaken. The resulting pigments were characterized by using XRD, SEM, FT-IR and UV-Vis spectrophotometer. The color of glazed tiles containing 6 wt% pigment changed from dark green to black depending on the compositions of used materials. Pigments were calcined with mixed materials at $1350^{\circ}C$, and the dark green and dark brown color were obtained. Pigments were used to determine possible interactions between a pigment and a glaze.

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References

  1. Yoichi Shiraki, 'Glaze and Pigment,' pp. 711 (1968)
  2. Aladar Burgyan and Richard A. Eppler, 'Classification of Mixed-Metal-Oxide Inorganic Pigments,' Am. Ceram. Bull., 62 [9] 1001-03 (1983)
  3. Emel Ozel and Servet Turan, 'Production and Characterisation of Iron-chromium Pigments and Their Interactions with Transparent Glazes,' J. Eur. Ceram. Soc., 23 2097-104 (2003) https://doi.org/10.1016/S0955-2219(03)00036-0
  4. M. F. Gazulla, M. P. Gomez, A. Barba, and S. Mestre, 'Characterization of Chromium-containing Ceramic Pigments by XRF and XRD,' X-ray spectrom. 33 431-38 (2004) https://doi.org/10.1002/xrs.745
  5. A. Escardino, S. Mestre, A. Barba, M. Monzo, A. Blasco, and V. Beltran, 'Colorimetric Study of $Black(Fe,Cr)_2O_3$ Pigment Synthesis Reaction :Relation between ChromaticCoordinates and Synthesis Conditions,' British Ceramic Transactions, 102 [6] 247-50 (2003) https://doi.org/10.1179/096797803225009292
  6. R. K. Data and Rustum Roy, 'Equilibrium Order-Disorder in Spinels,' J. Am. Ceram. Soc., 50 [11] 578-83 (1967) https://doi.org/10.1111/j.1151-2916.1967.tb15002.x
  7. Atsushi Ohtsuka, 'Studies on the Pigments of Titanium-Tin and Aluminium-chrome Spinel,' J. Ceram. Assoc. Japan, 70 [4] 110-13 (1962)
  8. Atsushi Ohtsuka, 'Studies on the Formation and the Color Development of Magnesium-Zinc Titanium Spinels containing $Co^{2+}$ and $Ni^{2+}$ ions,' J. Ceram. Assoc. Japan, 73 [8] 170-80 (1965) https://doi.org/10.2109/jcersj1950.73.840_170
  9. Atsushi Ohtsuka, 'Research on the Titanium-Aluminum Spinels containing $Co^{2+}$ and $Ni^{2+}$ ions,' J. Ceram. Assoc. Japan, 74 [3] 68-83 (1966) https://doi.org/10.2109/jcersj1950.74.847_68
  10. Atsushi Ohtsuka, 'Formation and Color of the Spinel Solid Solutions in CoO-ZnO-$Al_2O_3-Cr_2O_3-Fe_2O_3$ System,' J. Ceram. Assoc. Japan, 81 [2] 49-63 (1973) https://doi.org/10.2109/jcersj1950.81.930_49
  11. Atsushi Ohtsuka and Yuhichiroh Fujihashi, 'Formation and Color of the Spinel Solid Solutions in CoO-MgO-$Cr_2O_3-TiO_2-SnO_2$ System,' J. Ceram. Assoc. Japan, 82 [2] 114-25 (1974) https://doi.org/10.2109/jcersj1950.82.942_114
  12. Atsushi Ohtsuka and Kazuo Kitamura, 'Formation and color of the Spinel Solid Solutions in CoO-ZnO-$Cr_2O_3-TiO_2-SnO_2$ System,' J. Ceram. Assoc. Japan, 83 [7] 347-61 (1975) https://doi.org/10.2109/jcersj1950.83.959_347
  13. Atsushi Ohtsuka and Kiyomitsu Kazama, 'Formation and color of the Spinel Solid Solutions in CoO-ZnO-$Al_2O_3-Cr_2O_3-TiO_2$ System,' J. Ceram. Assoc. Japan, 84 [10] 457-69 (1976) https://doi.org/10.2109/jcersj1950.84.974_457
  14. Atsushi Ohtsuka, Osamu Kosugi, and Takamasa Ishigaki, 'Formation and color of the Spinel Solid Solutions in CoOZnO- $Cr_2O_3-Fe_2O_3-TiO_2$ System,' J. Ceram. Assoc. Japan, 88 [2] 57-70 (1980) https://doi.org/10.2109/jcersj1950.88.1014_57

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