DOI QR코드

DOI QR Code

Synthesis and Photoactivity of SnO2-Doped TiO2 Thin Films

SnO2가 도핑된 TiO2 박막의 합성 및 광촉매 효과

  • Jung, Mie-Won (Department of Chemistry, Sungshin Women's University) ;
  • Kwak, Yun-Jung (Department of Chemistry, Sungshin Women's University)
  • Published : 2007.11.30

Abstract

[ $SnO_2$ ]-doped $TiO_2$ thin films were prepared from tin (IV) bis (acetylacetonate) dichloride and titanium diisopropoxide bis (acetylacetonate) with pluronic P123 or degussa P25 as a structural-directing agent. These hydrolyzed sol were spin coated onto Si(100) wafer substrate. The microstructure, morphology and bonding states of thin films were studied by field-emission scanning electron microscopy (FE-SEM), X-ray diffractometry (XRD), and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity of these films was investigated by using indigo carmine solution.

Keywords

References

  1. J. C. Yu, L. Zhang, and W. Ho, 'Enhancing Effects of Water Content and Ultrasonic Irradiation on the Photocatalytic Activity of Nano-sized $TiO_2$ Powders,' J. Photochem. Photobio., A148 263-71 (2002) https://doi.org/10.1016/S1010-6030(02)00052-7
  2. L. Zhang, Y. Zhu, Y. He, and W. Li, 'Preparation and Performances of Mesoporous $TiO_2$ Film Photocatalyst supported on Stainless Steel,' Appl. Catalysis B, 40 287-92 (2003) https://doi.org/10.1016/S0926-3373(02)00154-6
  3. Y. Takahashi and Y. Matsuoka, 'Dip-coating of $TiO_2$ Films using a Sol derived from $Ti(O-i-Pr)_4-diethanolamine-H_2O-i-PrOH$ System,' J. Mater. Sci., 23 2259-66 (1988) https://doi.org/10.1007/BF01115798
  4. G. A. Battiston, R. Gerbasi, and G. A. Rizzi, 'PECVD of Amorphous $TiO_2$ thin Film: Effect of Growth Temperature and Plasma Gas Composition,' Thin Solid Films, 371 126-31 (2000) https://doi.org/10.1016/S0040-6090(00)00998-6
  5. Y. K. Ree and J. C. Cha, 'Glass Transition Temperature of Poly (tert-butyl methacrylate) Langmuir-Blodgett Film and Spin-Coated Film by X-ray Reflectivity and Ellipsometry,' Langmuir, 16 [5] 2351-55 (2000) https://doi.org/10.1021/la991074v
  6. D. Zao, J. Feng, Q. Huo, N. Melsh, and G. D. Stucky, 'Triblock Copolymer Syntheses of Mesoporus Silica with Periodic 50 to 300 Angstrom Pores,' Science, 279 548-52 (1998) https://doi.org/10.1126/science.279.5350.548
  7. R. A. Eppler, 'Effect of Antimony Oxide on the Anatase-Rutile Transformation in Titanium Dioxide,' J. Am. Ceram. Soc., 70 [4] C64-6 (1987) https://doi.org/10.1111/j.1151-2916.1987.tb04985.x
  8. M. W. Jung and Y. J. Kwak, 'Synthesis and Photoactivity of $SnO_2$-doped Anatase Type $TiO_2$ Powder via Polymerization-Complex Route(in Korean),' J. Kor. Ind. Eng. Chem., 17 [5] 561-64 (2006)
  9. D. C. Hurum, A. G. Agrios, and K. A. Gray, 'Explaining the Enhanced Photocatalytic activity of Degussa P25 Mixed-Phase $TiO_2$ using EPR,' J. Phys. Chem. B, 107 4545-49 (2003) https://doi.org/10.1021/jp0273934
  10. G. Balasubramanian, D. D. Dionysiou, M. T. Suidan, J. M. Laine, and I. Baudin, 'Evaluating the Activities of Immobilized $TiO_2$ Powder Films for the Photocatalytic Degradation of Organic Contaminants in Water,' Appl. Catalysis B, 47 73-84 (2004) https://doi.org/10.1016/j.apcatb.2003.04.002
  11. N. G. Park, K. M. Kim, M. G. Kang, K. S. Ryu, S. H. Chang, and Y. J. Shin, 'Chemical Sintering of Nanoparticles: A Methodology for Low Temperature Fablication of Dye-Sensitized TiO2 Films,' Adv. Mater., 17 2349-53 (2005) https://doi.org/10.1002/adma.200500288