Korean Membrane Journal

The Membrane Society of Korea (한국막학회)
권호 표지

Oxygen Permeation Properties and Phase Stability of Co-Free $La_{0.6}Sr_{0.4}Ti_{0.2}Fe_{0.8}O_{3-{\delta}}$ Oxygen Membrane

  • Kim, Ki-Young (Energy Conversion Research Department, Korea Institute of Energy Research) ;
  • Park, Jung-Hoon (Energy Conversion Research Department, Korea Institute of Energy Research) ;
  • Kim, Jong-Pyo (Energy Conversion Research Department, Korea Institute of Energy Research) ;
  • Son, Sou-Hwan (Energy Conversion Research Department, Korea Institute of Energy Research) ;
  • Park, Sang-Do (Carbon Dioxide Reduction and Sequestration R&D Center, Korea Institute of Energy Research)
  • Published : 2007.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

A perovskite-type ($La_{0.6}Sr_{0.4}Ti_{0.2}Fe_{0.8}O_{3-{\delta}}$) dense ceramic membrane was prepared by polymerized complex method, using citric acid as a chelating agent and ethylene glycol as an organic stabilizer. Effect of Ti addition on lanthanum-strontium ferrite mixed conductor was investigated by evaluating the thermal expansion coefficient, the oxygen flux, the electrical conductivity, and the phase stability. The thermal expansion coefficient in air was $21.19\;{\times}\;10^{-6}/K$ at 473 to 1,223 K. At the oxygen partial pressure of 0.21 atm ($20%\;O_2$), the electrical conductivity increased with temperature and then decreased after 973 K. The decrement in electrical conductivity at high temperatures was explained by a loss of the lattice oxygen. The oxygen flux increased with temperature and was $0.17\;mL/cm^2{\cdot}min$ at 1,223 K. From the temperature-dependent oxygen flux data, the activation energy of oxygen ion conduction was calculated and was 80.5 kJ/mol at 1,073 to 1,223 K. Also, the Ti-added lanthanum-strontium ferrite mixed conductor was structurally and chemically stable after 450 hours long-term test at 1,173 K.

Keywords

References

  1. J. E. ten Elshof, H. J. M. Bouwmeester, and H. Verweij, 'Oxidative coupling of methane in a mixed-conducting perovskite membrane reactor', Appl. Catal. A., 130, 195 (1995)
  2. Y. Zeng, Y. S. Lin, and S. L. Swartz, 'Perovskitetype ceramic membrane: synthesis, oxygen permeation and membrane reactor performance for oxidative coupling of methane', J. Membr. Sci., 150, 87 (1998)
  3. C. H. Chen, H. Bouwmeester, R. H. E. V. Doors, H. Kruidhof, and A. J. Burggraaf, 'Oxygen permeation of $La_{0.3}Sr_{0.7}CoO_{3-\delta}$', Solid State Ionics, 98, 7 (1997)
  4. T. M. Gur, A. Belzner, and R. A. Huggins, 'A new class of oxygen selective chemically driven nonporous ceramic membranes. Part I. A-site doped perovskites', J. Membr. Sci., 75, 151 (1992)
  5. V. V. Kbarton, E. N. Naumovich, and A. V. Nikolaev, 'Materials of high-temperature electrochemical oxygen membranes', J. Membr. Sci., 111, 149 (1996)
  6. L. Qiu, T. H. Lee, L. M. Liu, Y. L. Yang, and A. J. Jacobson, 'Oxygen permeation studies of $SrCo_{0.8}Fe_{0.2}O_{3-\delta}$', Solid State Ionics, 76, 321 (1995)
  7. L. W. Tai, M. M. Nasrallah, H. U. Anderson, D. M. Sparlin, and S. R. Sehlin, 'Structure and electrical properties of $La_{1-x}Sr_xCo_{1-y}Fe_yO_3$. Part 1. The system $La_{0.8}Sr_{0.2}Co_{1-y}Fe_yO_3$', Solid State Ionics, 76, 259 (1995)
  8. J. H. Park and J. P. Kim, 'Properties according to Sr substitution into $La_{1-x}Sr_xCo_{0.2}Fe_{0.8}O_{3-\delta}$', Proc. 1st Symp. of the membrane society of Korean, Eds. N. W. Kim and J. H. Kim, pp. 180, Yong-In, Korea
  9. Y. Teraoka, H. M. Zhang, S. Furukawa, and N. Yamazoe, 'Oxygen permeation through perovskitetype oxides', Chem. Lett., 1743 (1985)
  10. R. Bredesen and J. Sogge, In A technical and economic assessment of membrane reactors for hydrogen and syngas production, In seminar on the Ecological Applications of Innovative Membrane technology in the chemical Industry, Cerato, Calabria, Italy, 1996
  11. J. E. ten Elshof, H. J. M. Bouwmeester, and H. Verweij, 'Oxygen transport through $La_{1-x}Sr_xFeO_{3-\delta}$ membranes. I. Permeation in air/He gradients', Solid State Ionics, 81, 97 (1995)
  12. J. W. Stevenson, T. R. Armstrong, R. D. Carmeim, L. R. Pederson, and L. R. Weber, 'Electrochemical Properties of Mixed conducting perovskite $La_{1-x}M_xCo_{1-y}Fe_yO_{3-\delta}$ (M = Sr, Ba, Ca)', J. Electrochem. Soc., 143, 2722 (1996)
  13. C. Y. Tsai, A. G. Dixon, Y. H. Ma, W. R. Moser, and M. R. Pascucci, 'Dense perovskite $La_{1-x}A_xFe_{1-y}Co_yO_{3-\delta}$ (A = Ba, Sr, Ca), Membrane synthesis, Application and characterization', J. Am. Ceram. Soc., 81, 1437 (1998)
  14. T. J. Mazanec, T. L. Cable, J. G. Frye, and W. R. Kliewer, US patent, 5,591,315 (1997)
  15. M. Schwartz, J. H. White, and A. F. Sammells, US patent, 6,214,757 (2001)
  16. V. V. Kharton, A. P. Viskup, E. N. Naumovich, and N. M. Lapchuk, 'Mixed electronic and ionic conductivity of LaCo(M)$O_3$ (M = Ga, Cr, Fe or Ni): I. Oxygen transport in perovskites $LaCoO_3-LaGaO_3$', Solid State Ionics, 104, 67 (1997)
  17. V. V. Kharton, A. P. Viskup, D. M. Bochkov, E. N. Naumovich, and O. P. Reut, 'Mixed electronic and ionic conductivity of LaCo(M)$O_3$ (M = Ga, Cr, Fe or Ni): III. Diffusion of oxygen through $LaCo_{1-x-y}Fe_xNi_yO_{3+/-\delta}$ ceramics', Solid State Ionics, 110, 61 (1998)
  18. S. J. Benson, D. Waller, and J. A. Kilner, 'Degradation of $La_{0.6}Sr_{0.4}Fe_{0.8}Co_{0.2}O_{3-\delta}$ in Carbon Dioxide and water Atmospheres', J. Electochem. Soc., 146, 1305 (1999)
  19. J. H. Park and S. D. Park, 'Oxygen Permeability and Structural Stability of $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_{3-\delta}$ Oxygen Membrane', Korean J. Chem. Eng., 24(5) (2007) https://doi.org/10.1007/s11814-007-0062-2
  20. A. Yaremchenko, V. V. Kharton, A. L. Shaula, M. V. Patrakeev, and F. M. B. Marques, 'Transport properties and thermal expansion of perovskite-like $La_{0.3}Sr_{0.7}Fe(Al,Cr)O_{3-\delta}$ ceramics', J. Eur. Ceram. Soc., 25, 2603 (2005)
  21. E. V. Tsipis, M. V. Patrakeevb, V. V. Kharton, A. A. Yaremchenko, G. C. Mather, A. L. Shaula, I. A. Leonidov, V. L. Kozhevnikov, and J. R. Fradea, 'Transport properties and thermal expansion of Ti-substituted $La_{1-x}Sr_xFeO_{3-\delta}$ (x = 0.5 - 0.7)', Solid State Sciences, 7, 355 (2005)
  22. R. D. Shannon, 'Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides', Acta Crystallogr., A32, 751 (1976)
  23. S. Kim, Y. L. Yang, R. Christoffersen, and A. J. Jacobson, 'Oxygen permeation, electrical conductivity and stability of the perovskite oxide $La_{0.2}Sr_{0.8}Cu_{0.4}Co_{0.6}O_3O_{3-\delta}$', Solid State Ionics, 104, 57 (1997)
  24. Y. Teraoka, H. Zhang, K. Okamoto, and N. Yamazoe, 'Mixed Ionic-electronic conductivity of $La_{1-x}Sr_xCo_{1-y}Fe_yO_{3-\delta}$ perovskite-type oxides', Mat. Res. Bull., 23, 51 (1988)