타이타늄 합금에 다양한 두께로 코팅된 TiN 피막의 기계적 성질

MECHANICAL PROPERTIES OF TIN COATED FILM WITH VARIOUS COATING THICKNESS ON TITANIUM ALLOY

  • 이재윤 (조선대학교 치과대학 치과보철학교실) ;
  • 오동준 (조선대학교 치과대학 치과보철학교실) ;
  • 김희중 (조선대학교 치과대학 치과보철학교실) ;
  • 정재헌 (조선대학교 치과대학 치과보철학교실)
  • Lee, Jae-Yun (Department of Prosthodontics, College of Dentistry, Chosun University) ;
  • Oh, Dong-Joon (Department of Prosthodontics, College of Dentistry, Chosun University) ;
  • Kim, Hee-Jung (Department of Prosthodontics, College of Dentistry, Chosun University) ;
  • Chung, Chae-Heon (Department of Prosthodontics, College of Dentistry, Chosun University)
  • 발행 : 2007.10.31

초록

Statement of problem: Titanium nitride(TiN) coatings are the most general and popular coating method and used to improve the properties of metallic surface for industrial purposes. When TiN coating applied to the abutment screw, frictional resistance would be reduced, as a results, the greater preload and prevention of the screw loosening could be expected. Purpose: The purpose of this study was to investigate mechanical properties of TiN coated film of various coating thickness on the titanium alloy surface and to evaluate proper coating thickness. Material and method: 95 Titanium alloy (Ti-6Al-4V) discs of 15 mm in diameter and 3 mm in thickness were prepared for TiN coating and divided into 7 groups in this study. Acceding to coating deposition time (CDT) with TiN by using Arc ion plating, were divided into 7 groups : Group A (CDT 30min), Group B (CDT 60min), Group C (CDT 90min), Group D (CDT 120min), Group E (CDT 150min), Group F(CDT 180min) and Group G (no CDT) as a control group. TiN coating surface was observed with Atomic Force Microscope(AFM), field emission scanning electron microscopy(FE-SEM) and examined with scratch tester, wear tester. Result: 1. Coating thickness fir each coated group was increased in proportion to coating deposition time. 2. Surface of all coated groups except Group A was homogeneous and smooth. However, surface of none coated Group G had scratch. 3. Adhesion strength for each coated group was increased in proportion to coating deposition time. 4. Wear resistance for each coated group was increased in proportion to coating deposition time. 5. Surface roughness in Group A, B, C was increased in proportion to coating deposition time. But, surface roughness in Group D, E, F was showed decreased tendency in proportion to coating deposition time. Conclusion: According to coating deposition time, mechanical properties of TiN coated film were changed. It was considered that 120 minutes coating deposition time ($1.32{\mu}m$ in coating thickness) is necessary.

키워드

참고문헌

  1. Goodacre CJ, Bernal G, Rungcharassaeng K, Kan JYK. Clinical complications with implants and implant prostheses. J Prosthet Dent 2003:90:121-132 https://doi.org/10.1016/S0022-3913(03)00212-9
  2. Taylor TD. Prosthodontic problems and limitations associated with osseointegration. J Prosthet Dent 1998:79:74-78 https://doi.org/10.1016/S0022-3913(98)70197-0
  3. Jemt T. Failures and complication s in 391 consecutively inserted fixed prostheses supported by Banemark implants in edentulous jaws: A study of treatment from the time of prosthesis placement to the first annual checkup. Int J Oral Maxillofac Implants 1991:6:270-276
  4. Jemt T, Pettersson P. A 3-year follow-up study on single implant treatment. J Dent 1993:21:203-208 https://doi.org/10.1016/0300-5712(93)90127-C
  5. Binon PP, Sutter F, Beaty K, Brunski J, Gulbransen H, Weiner R. The role of screw in implant systems. Int J Oral Maxillofac Implants (supplement) 1994:9:48-63
  6. Haack JE, Sakaguchi RL, Sun T, Coffey JP. Elongation and preload stress in dental implant abutment systems. Int J Oral Maxillofac Implants 1995:10:529-536
  7. Motosh N. Development of design charts for bolts preloaded up to the plastic range. J Eng Ind 1976:98:849-851 https://doi.org/10.1115/1.3439041
  8. Binon PP. Implants and components : Entering the new millenium. Int J Oral Maxillofac Implants 2000:15:76-94
  9. Choi JU. Jeong CM, Jeon YC, Lim JS, Jeong HC, Eom TG, Influence of Tungsten Carbide/Carbon coating on the preload of implant abutment screws. J Korean Acad Prosthodont 2006:44:229-242
  10. Martin WC, Woody RD, Miller BH. Miller AW. Implant abutment screw retations and preloads for four different screw materials and surfaces. J Prosthet Dent 2001:86:24-32 https://doi.org/10.1067/mpr.2001.116230
  11. Kim HJ, Choe HC, Kim SG, Chung CH. Effect of TiN coating of abutment screw on detorque force. Int J Oral Maxillofac Implants 2006 under review
  12. Mezger PR, Creugers NH. Titanium nitride coatings in clinical dentistry. J Dent 1992:20:342-344 https://doi.org/10.1016/0300-5712(92)90021-4
  13. Arias DF, Arango YC, Devia A. Characterization of bilayer coatings of TiN/ZrN grown using pulsed arc PAPVD. Appl. Sur. Sci 2005:252:1175-1181 https://doi.org/10.1016/j.apsusc.2005.02.047
  14. Takadoum J, Bennani HH. Influence of substrate roughness and coating thickness on adhesion, friction and wear of TiN films. Surf. & Coat. Tech. 1997:96:272-282 https://doi.org/10.1016/S0257-8972(97)00182-5
  15. Sundgren JE. Structure and properties of TiN coatings. Thin Solid Films 1985:128:21-44 https://doi.org/10.1016/0040-6090(85)90333-5
  16. Polonsky IA, Chang TP, Keer LM, Sproul WD. A study of rolling-contact fatigue of bearing steel coated with physical vapor deposition TiN films: Coating response to cyclic contact stress and physical mechanism underlying coating effect on the fatigue life. Wear 1998:215:191-204 https://doi.org/10.1016/S0043-1648(97)00256-1
  17. Oh DJ, Kim HJ, Chung CH. A study on mechanical properties of TiN, ZrN, WC coating in titanium alloy. J Korean Acad Prosthodont 2006:44:740-750
  18. Millic M, Milosavljevic M, Bibic N, Nenadovic T. Mechanical properties of sputtered TiN coatings. Thin Solid Films 1985:126:319-323 https://doi.org/10.1016/0040-6090(85)90327-X
  19. Winkler S, Ring K. Ring JD, Boberick KG. Implant screw mechanics and the settling effect : An overview. J Oral Implantol 2003:29:242-245 https://doi.org/10.1563/1548-1336(2003)029<0242:ISMATS>2.3.CO;2
  20. Jorneus L, Jemt T, Carlsson L. Loads and designs of screw joints for single crowns supported by osseointegrated implants. Int J Oral Maxillofac Implants 1992:7:353-359
  21. Sakaguchi RL, Borgersen SE. Nonlinear contact analysis of preload in dental implant screws. Int J Oral Maxillofac Implants 1995:10:295-302