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Corrosion of Refractory in Glass Melts for Plasma Display Panel Substrate

Plasma Display Panel용 기판 유리용융체의 내화물 침식

  • Kim, Ki-Dong (Department of Materials Science and Engineering, Kunsan National University) ;
  • Jung, Hyun-Su (Department of Materials Science and Engineering, Kunsan National University) ;
  • Kim, Hyo-Kwang (Department of Materials Science and Engineering, Kunsan National University)
  • 김기동 (군산대학교 신소재나노화학공학부 신소재공학) ;
  • 정현수 (군산대학교 신소재나노화학공학부 신소재공학) ;
  • 김효광 (군산대학교 신소재나노화학공학부 신소재공학)
  • Published : 2007.01.31

Abstract

For self-developed alkali-alkaline earth-silicate and commercial glass melts for plasma display panel substrate, the corrosion behavior of fused casting refractory consisting of $Al_2O_3-ZrO_2-SiO_2$ was examined at the temperature corresponding to $10^2\;dPa{\cdot}s$ of melt viscosity by static finger methode. The corroded refractory specimens showed a typical concave shape due to interfacial convection of melts at their flux line. However, the corrosion thickness by commercial glass melts was $6\sim10$ times comparing to that by the self?developed melts. From the view point of the glass composition and the role of alkaline earth in glass network, it was discussed the effect of alkali/alkaline earth diffusion and temperature on the refractory corrosion.

Keywords

References

  1. K. D. Kim, W. M. Jung, S. K. Kwon, and S. Y. Choi, 'Composition and Propeties of Substrate Glasses for Plasma Display Panel(in Korean),' J. Kor. Ceram. Soc., 43 [5] 293-98 (2006) https://doi.org/10.4191/KCERS.2006.43.5.293
  2. K. D. Kim, W. M. Jung, H. S. Jung, S. K. Kwon, and S. Y. Choi, 'Melt Properties of Plasma Display Panel Substrate Glasses Based on Float Process(in Korean),' J. Kor. Ceram. Soc., 43 [7] 433-438 (2006) https://doi.org/10.4191/KCERS.2006.43.7.433
  3. F. E. Woolley, 'Melting/Fining,' in Engineered Materials Handbook Vol. 4, pp. 386-393, Ceramics and Glasses, The Materials Information Society. ASM Internatinal, 1992
  4. H. Jebsen-Marwedel and R. Brueckner, 'Glastechnische Fabrikationsfehler,' Springer-Verlag, pp. 358-384 (1980)
  5. W. Trier, 'Glass Furnace,' Society of Glass Technology, pp. 169-174 (1987)
  6. M. Dunkl, 'Corrosion Tests-A very Important Investigation Method for the Selection of Refractories for Glass Tanks,' Glastech. Ber. Glass Science and Technology, 67 [12] 325- 334 (1994)
  7. G. Duvierre, Y. B. Roux, and M. Nelson, 'Fused Zirconia of Fused AZS: Which is the Best Choice?,' Glasteknisk Tidskrift, 54 [2] 56-62 (1999)
  8. D. E. Day, 'Mixed Alkali Glasses-Their Properties and Uses,' J. Non-Cry. Solid, 21 343-372 (1976) https://doi.org/10.1016/0022-3093(76)90026-0
  9. G. H. Frischat, 'Ionic Diffusion in Oxide Glasses,' Trans Tech Publication, pp. 59-64 (1975)
  10. H. Scholze, 'Glas: Natur, Struktur, Eigenschaften,' Springer- Verlag, pp. 126-128 (1988)
  11. V. V. Gorbachev, A. S. Bystrikov, S. K. Vasilev, and L. V. Bogomolova, 'An X-Ray Spectral Study of the State of Magnesium Ions in Sodium Magnesium and Sodium Calcium Magnesium Silicate Glasses,' Sov. J. Glass Phys. Chem., 9 [6] 447-452 (1983)
  12. M. Dunkl, A. Gupta, and J. Mackintosh, 'Considerations of the Corrosion of Refractories by Glass,' Glasteknisk Tidskrift, 57 [3] 41-44 (2002)