Abstract
This study centered on the quantitative analysis of about 27 trace elements including toxic ones using instrumental neutron activation analysis of fine ambient particulate matter in the third and fourth industrial complex area of Daejeon city, Korea. For analytical quality control, the certified reference material (NIST, the National Institute of Standards and Technology, U.S.A., SRM 2783, air particulate on filter media) was used. The errors relative to SRM values of Sb, Mn, V, Mg, Na, K, Ti, Co, Zn, and Sm fell below 5%, while those of Cr, Fe, Ba, Th, Ce, Al, and Cu were less than 10%. From the results of the quantitative analysis, the concentration of toxic metals such as As, Mn, Se, V, and Zn were $3.26{\pm}2.72$, $9.86{\pm}4.71$, $2.18{\pm}1.25$, $4.91{\pm}2.41$, $158{\pm}78ng/m^3$, respectively. And the results of factor analysis indicated that there are no more than six factors of sources of fine ambient particulate with statistical significance in the study area.
대전시 3, 4 공단지역의 대기 중 미세분진을 대상으로 기기 중성자방사화분석법을 이용하여 유해금속을 포함한 약 27종의 미량원소를 분석하였다. 원소분석에 대한 정확도를 평가하기 위해 NIST SRM 2783(air particulate on filter media)을 사용하여 동일한 조건에서 분석한 결과, Sb, Mn, V, Mg, Na, K, Ti, Co, Zn, Sm은 상대오차 5% 이내의 매우 정확한 분석결과를 보였고 Cr, Fe, Ba, Th, Ce, Al, Cu는 10% 이내로 나타났다. 유해금속인 As, Mn, Se, V, Zn의 농도는 각각 $3.26{\pm}2.72$, $9.86{\pm}4.71$, $2.18{\pm}1.25$, $4.91{\pm}2.41$, $158{\pm}78ng/m^3$로 나타났고 인자분석 결과 연구대상지역의 미세분진에 대한 오염원은 6개로 추정되었다.
