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Volatile Flavor Compounds of Freeze Dried Garlic and Garlic Roasted with Oils

건조마늘과 기름에 볶은 마늘의 향기성분

  • Seo, Hye-Min (Dept. of Food Science and Nutrition, Keimyung University) ;
  • Joo, Kwang-Jee (Dept. of Food Science and Nutrition, Keimyung University)
  • 서혜민 (계명대학교 식품영양학과) ;
  • 주광지 (계명대학교 식품영양학과)
  • Published : 2007.03.31

Abstract

The purpose of this study was to investigate the change of flavor compounds of freeze-dried garlic and garlic roasted with soybean oil and sesame oil. Freeze-dried garlic and ground raw garlic roasted with oils was prepared at $180^{\circ}C$ for 5 minutes. Volatile compounds of garlic samples were obtained by Likens-Nickerson distillation/solvent extraction and identified by GC and GC/MS. Sulfur compounds, methyl allyl sulfide, diallyl sulfide, methyl allyl disulfide, dimethyl trisulfide, diallyl disulfide, methyl allyl trisulfide and diallyl trisulfide were the major volatile in garlic flavor which was more than 98% of the total volatile compounds. The total amount of sulfur compounds in freeze-dried garlic roasted with soybean oil was decreased to 20% compare to that of garlic flavor; however, 10 pyrazines such as 2-methyl pyrazine, 2,6-dimethyl pyrazine, 2-ethyl-5-methyl pyrazin and 3-ethyl-2,5-dimethyl pyrazine which were not originated from both freeze-dried garlic and soybean oil were identified. They might be generated from thermal interactions of sugars and nonvolatile flavor precursors of garlic. In freeze-dried garlic roasted with sesame oil, the amount of diallyl sulfide, methyl allyl disulfide, dimethyl trisulfide increased whereas diallyl disulfide completely disappeared. The amount of two cyclic compounds 3,4-dihydro-3-vinyl-1,2-dithiin and 2-vinyl-4H-1,3-dithiin, which were artifacts from allicin, increased in roasted garlic with sesame oil.

마쇄한 생마늘과 생마늘을 동결건조한 분말의 함황화합물과 휘발성 향기성분의 변화를 관찰하기 위하여 마늘을 동결 건조시켜 분말로 제조하고, 마늘과 동결건조 마늘을 콩기름과 참기름에 $180^{\circ}C$에서 각각 5분간 볶은 6개의 시료를 제조하여 향기성분을 추출하였다. 마늘의 독특한 향기를 나타내는 sulfur compounds로서 methyl allyl sulfide, diallyl sulfide, methyl allyl disulfide, diallyl disulfide, methyl allyl trisulfide, diallyl trisulfide 등이 확인되었으며 diallyl disulfide와 diallyl trisulfide의 함량이 풍부하였다. 이 sulfur compounds 성분들은 마늘의 총 향기성분의 98%를 차지하여 마늘의 주요 구성분임을 다시 한 번 확인하였다. 건조마늘에서 확인된 향기성분은 마늘에서 검출되지 않았던 aldehyde, alcohol, furans, esters가 생성되어 개별 향기성분의 수는 마늘의 것보다 더 많았으나 sulfur compounds와 향기성분의 총 함량이 마늘의 것보다 감소하였다. 콩기름에 볶은 건조마늘의 sulfur compounds 함량은 크게 감소하여 건조마늘의 sulfur compounds 함량의 20%에 불과하여 그 함량이 크게 감소하였다. 마늘을 콩기름과 참기름으로 가열하였을 때 allicin의 분해 생성물인 많은 양의 3,4-dihydro-3-vinyl-1,2-dithiin과 2-vinyl-4H-1,3-dithiin이 확인되었다. 그리고 건조마늘을 콩기름과 참기름에 가열하였을 때 마늘의 아미노산과 당류의 반응에 의하여 생성된 2-methyl pyrazine, 2,6-dimethyl pyrazine, 2-ethyl-5-methyl pyrazine 등 17개의 pyrazine이 관찰되었다. 건조마늘을 참기름에 볶은 시료에서 확인된 개별 향기성분의 수는 모든 마늘시료 중에서 가장 많았고 향기성분의 총 함량도 마늘의 것과 거의 동일하여 차이가 없었으나 sulfur compounds의 함량은 마늘의 27%에 해당되었다. 건조마늘을 콩기름과 참기름으로 가열함으로써 그 함량이 마늘 자체의 것보다 오히려 증가한 것은 diallyl sulfide, methyl allyl disulfide, dimethyl trisulfide이었다. 마늘에서 그 함량이 가장 많았고 마늘의 독특한 향기성분을 내는 diallyl disulfide는 건조하여 참기름으로 가열함으로써 파괴되어 완전히 소멸되었다.

Keywords

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