Low temperature deposition of carbon nanofilaments using vacuum-sublimated $Fe(CO)_5$ catalyst with thermal chemical vapor deposition

  • Kim, Nam-Seok (Department of Electronic Materials Engineering, Silla University) ;
  • Kim, Kwang-Duk (Department of Electronic Materials Engineering, Silla University) ;
  • Kim, Sung-Hoon (Department of Electronic Materials Engineering, Silla University)
  • Published : 2007.02.28

Abstract

Carbon nanofilaments were deposited on silicon oxide substrate by thermal chemical vapor deposition method. We used $Fe(CO)_5$ as the catalyst for the carbon nanofilaments formation. Around $800^{\circ}C$ substrate temperature, the formation density of carbon nanofilaments could be enhanced by the vacuum sublimation technique of $Fe(CO)_5$, compared with the conventional spin coating technique. Finally, we could achieve the low temperature, as low as $350^{\circ}C$, formation of carbon nanofilaments using the sublimated Fe-complex nanograins with thermal chemical vapor deposition. Detailed morphologies and characteristics of the carbon nanofilaments were investigated. Based on these results, the role of the vacuum sublimation technique for the low temperature deposition of carbon nanofilaments was discussed.

Keywords

References

  1. SJ. Tans, M.H. Devoret, H. Dai, A. Thess, R.E. Smalley, LJ. Geerligs and C. Dekker, 'Individual single-wall carbon nanotubes as quantum wires', Nature 386 (1997) 474 https://doi.org/10.1038/386474a0
  2. S.D. Robertson, 'Graphite formation from low temperature pyrolysis of methane over some transition metal surfaces', Nature 221 (1969) 1044 https://doi.org/10.1038/2211044a0
  3. S. Iijima, 'Helical microtubules of graphitic carbon', Nature 354 (1991) 56 https://doi.org/10.1038/354056a0
  4. MJ. Ledoux, R. Vieira, C. Pham-Huu and N. Keller, 'New catalytic phenomena on nanostructured (fibers and tubes) catalysts', J. of Catalysis 216 (2003) 333 https://doi.org/10.1016/S0021-9517(02)00108-2
  5. L. Marty, V. Bouchiat, A.M. Bonnot, M. Chaumont, T. Foutnier and S. Decossas, 'Batch processing of nanometer- scale electrical circuitry based on in-situ grown single- walled carbon nanotubes', S. Roche, Microelectronic Engineering 61-62 (2002) 485
  6. M. Knupfer, 'Electronic properties of carbon nanostructures', Surface Science Reports 42 (2001) 1
  7. R. Ma, C.L. Xu, B.Q. Wei, J. Liang, D.H. Wu and D. Li, 'Electrical conductivity and field emission characteristics of hot-pressed sintered carbon nanotubes', Mater. Res. Bull. 34 (1999) 741 https://doi.org/10.1016/S0025-5408(99)00064-1
  8. XX Zhang, Z.Q. Li, G.H. Wen, KK Fung, J.L. Chen and YD. Li, 'Microstructure and growth of bambooshaped carbon nanotubes', Chem. Phys. Lett. 333 (2001) 509 https://doi.org/10.1016/S0009-2614(00)01431-7
  9. E.F. Kukovitsky, S.G Lvov, N.A. Sainov, V.A. Shustov and L.A. Chemozatonski, 'Correlation between metal catalyst particle size and carbon nanotube growth', Chem. Phys. Lett. 355 (2002) 497 https://doi.org/10.1016/S0009-2614(02)00283-X
  10. C.J. Lee, J. Park, Y Huh and J.Y Lee, 'Temperature effect on the growth of carbon nanotubes using thermal chemical vapor deposition', Chem. Phys. Lett. 343 (2001) 33 https://doi.org/10.1016/S0009-2614(01)00680-7
  11. S. Hofmann, B. Kleinsorge, C. Ducati, A.C. Ferrari and J. Robertson, 'Low-temperature plasma enhanced chemical vapour deposition of carbon nanotubes', Diamond Relat. Mater. 13 (2004) 1171 https://doi.org/10.1016/j.diamond.2003.11.046
  12. G Yu, J. Gong, D. Zhu, S. He and Z. Zhu, 'Synthesis of carbon nanotubes over rare earth zeolites at low temperature', Carbon 43 (2005) 3015 https://doi.org/10.1016/j.carbon.2005.06.036
  13. K Kamada, T. lkuno, S. Takahashi, T. Oyama, T. Yamamoto, M. Kamizono, O. Ohkura, S. Honda, M. Katayama, T. Hirao and K Oura, 'Surface morphology and field emission characteristics of carbon nanofiber films grown by chemical vapor deposition on alloy catalyst', Applied Surface Science 212 (2003) 383 https://doi.org/10.1016/S0169-4332(03)00119-3
  14. GJ. Yu, J.L. Gong, D.Z. Zhu, S.X. He, J.Q. Cao and Z.Y Zhu, 'Efficient synthesis of carbon nanotubes over rare earth zeolites by thermal chemical vapor deposition at low temperature', Diamond Relat. Mater. 15 (2006) 1261 https://doi.org/10.1016/j.diamond.2005.09.035