DOI QR코드

DOI QR Code

Synthesis and Characterization of One-Dimensional GaN Nanostructures Prepared via Halide Vapor-Phase Epitaxy

  • Published : 2007.03.31

Abstract

High-quality one-dimensional GaN nanorods and nanowires were synthesized on Ni-coated c-plan sapphire substrate using halide vapor-phase epitaxy (HVPE). Their structure and optical properties were investigated by X-ray diffraction, scanning and transmission electron microscopy, and photoluminescence techniques. Full substrate coverage of densely packed, uniform, straight and aligned one-dimensional GaN nanowires with a diameter of 80nm were grown at $700{\sim}900^{\circ}C$. The X-ray diffraction patterns, transmission electron microscopic image, and selective area electron diffraction patterns indicate that the one-dimensional GaN nanostructures are a pure single crystalline and preferentially oriented in the [001] direction. We observed high optical quality of GaN nanowires by photoluminescence analysis.

Keywords

References

  1. S. Iijima, 'Helical Microtubules of Graphitic Carbon,' Nature,354 [6348] 56-8 (1991) https://doi.org/10.1038/354056a0
  2. A. M. Morales and C. M. Lieber, 'A Laser Ablation Method for the Synthesis of Crystalline Semiconductor Nanowires,' Science, 2791 208-11 (1998) https://doi.org/10.1126/science.279.5348.208
  3. Y. Zhang, K. Suenaga, C. Colliex, and S. Iijima, 'Coaxial Nanocable: Silicon Carbide and Silicon Oxide Sheathed with Boron Nitride and Carbon,' Science, 281 973-75 (1998) https://doi.org/10.1126/science.281.5379.973
  4. G. S. Cheng, L. D. Zhang, Y. Zhu, G. T. Fei, L. Li, C. M. Mo, and Y. Q. Mao, 'Large-Scale Synthesis of Single Crystalline Gallium Nitride Nanowires,' Appl. Phys. Lett., 75 2455-57 (1999) https://doi.org/10.1063/1.125046
  5. C. M. Lieber, 'One-Dimensional Nanostructures: Chemistry, Physics, and Applications,' Solid State Communications, 107 [11] 607-16 (1998) https://doi.org/10.1016/S0038-1098(98)00209-9
  6. W. Han, S. Fan, Q. Li, and Y. Hu, 'Synthesis of Gallium Nitride Nanorods Through a Carbon Nanotube-Confined Reaction,' Science, 277 1287-89 (1997) https://doi.org/10.1126/science.277.5330.1287
  7. C.-C. Chen and C. C. Yeh, 'Large-Scale Catalytic Synthesis of Crystalline Gallium Nitride Nanowires,' Adv. Mater., 12 738-41 (2000) https://doi.org/10.1002/(SICI)1521-4095(200005)12:10<738::AID-ADMA738>3.0.CO;2-J
  8. J. Y. Li, X. L. Chen, Z. Y. Qiao, Y. G. Cao, and Y. C. Lan, 'Formation of GaN Nanorods by a Sublimation Method,' J. Crystal Growth, 213 [3-4] 408-10 (2000) https://doi.org/10.1016/S0022-0248(00)00390-0
  9. J. C. Johnson, H.-J. Choi, K. P. Knutsen1, R. D. Schaller, P. Yang, and R. J. Saykally, 'Single Gallium Nitride Nanowire Lasers,' Nature Mater., 1 106-10 (2002) https://doi.org/10.1038/nmat728
  10. M. S. Gudiksen, L. J. Lauhon, J. Wang, D. C. Smith, and C. M. Lieber, 'Growth of Nanowire Superlattice Structures for Nanoscale Photonics and Electronics,' Nature, 415 [6872] 617-20 (2002) https://doi.org/10.1038/415617a
  11. E. W. Wong, P. E. Sheehan, and C. M. Lieber, 'Nanobeam Mechanics: Elasticity, Strength, and Toughness of Nanorods and Nanotubes,' Science, 277 1971-75 (1997) https://doi.org/10.1126/science.277.5334.1971
  12. J. Chaudhuri, C. Ignatiev, S. Stepanov, D. Tsvetkov, A. Cherenkov, V. Dmitriev, and Z. Rek, 'High Quality GaN Layers Grown by Hydride Vapor Phase Epitaxy: A High Resolution X-Ray Diffractometry and Synchrotron X-Ray Topography Study,' Mater. Sci. and Eng. B, 78 [1] 22-7 (2000) https://doi.org/10.1016/S0921-5107(00)00507-9
  13. R. J. Molnar, W. Gotz, L. T. Romano, and N. M. Johnson, 'Growth of Gallium Nitride by Hydride Vapor-Phase Epitaxy,' J. Crystal Growth, 178 [1-2] 147-56 (1997) https://doi.org/10.1016/S0022-0248(97)00075-4
  14. A. Koukitu and Y. Kumagai, 'Thermodynamic Analysis of Group III Nitrides Grown by Metal-Organic Vapour-Phase Epitaxy (MOVPE), Hydride (or Halide) Vapour-Phase Epitaxy (HVPE) and Molecular Beam Epitaxy (MBE),' J. Phys.: Condensed. Matter., 13 6907-34 (2001) https://doi.org/10.1088/0953-8984/13/32/303
  15. W. Seifert, G. Fitzl, and E. Butter, 'Study on the Growth Rate in VPE of GaN,' J. Crystal Growth, 52 257-62 (1981) https://doi.org/10.1016/0022-0248(81)90201-3

Cited by

  1. A Detailed Investigation of the Growth Conditions of Gallium Nitride Nanorods by Hydride Vapor Phase Epitaxy vol.51, pp.1, 2012, https://doi.org/10.1143/JJAP.51.01AF05
  2. A Detailed Investigation of the Growth Conditions of Gallium Nitride Nanorods by Hydride Vapor Phase Epitaxy vol.51, pp.1S, 2013, https://doi.org/10.7567/JJAP.51.01AF05