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LED용Mg2+·Ba2+Co-Doped Sr2SiO4:Eu 노란색 형광체의 발광특성

Luminescence Characteristics of Mg2+·Ba2+ Co-Doped Sr2SiO4:Eu Yellow Phosphor for Light Emitting Diodes

  • 최경재 (한국화학연구소 화학소재연구부) ;
  • 지순덕 (한국교원대학교 기술교육과) ;
  • 김창해 (한국화학연구소 화학소재연구부) ;
  • 이상혁 (한국교원대학교 기술교육과) ;
  • 김호건 (한양대학교 응용화학과)
  • Choi, Kyoung-Jae (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Jee, Soon-Duk (Department of Technology Education, Korea National University of Education) ;
  • Kim, Chang-Hae (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Lee, Sang-Hyuk (Department of Technology Education, Korea National University of Education) ;
  • Kim, Ho-Kun (Department of Applied Chemistry, Hanyang University)
  • 발행 : 2007.03.31

초록

An improvement for the efficiency of the $Sr_{2}SiO_{4}:Eu$ yellow phosphor under the $450{\sim}470\;nm$ excitation range have been achieved by adding the co-doping element ($Mg^{2+}\;and\;Ba^{2+}$) in the host. White LEDs were fabricated through an integration of an blue (InGaN) chip (${\lambda}_{cm}=450\;nm$) and a blend of two phosphors ($Mg^{2+},\;Ba^{2+}\;co-doped\;Sr_{2}SiO_{4}:Eu$ yellow phosphor+CaS:Eu red phosphor) in a single package. The InGaN-based two phosphor blends ($Mg^{2+},\;Ba^{2+}\;co-doped\;Sr_{2}SiO_{4}:Eu$ yellow phosphor+CaS:Eu red phosphor) LEDs showed three bands at 450 nm, 550 nm and 640 nm, respectively. The 450 nm emission band was due to a radiative recombination from an InGaN active layer. This 450 nm emission was used as an optical transition of the $Mg^{2+},\;Ba^{2+}\;co-doped\;Sr_{2}SiO_{4}:Eu$ yellow phosphor+CaS:Eu red phosphor. As a consequence of a preparation of white LEDs using the $Mg^{2+},\;Ba^{2+}\;co-doped\;Sr_{2}SiO_{4}:Eu$ yellow phosphor+CaS:Eu red phosphor yellow phosphor and CaS:Eu red phosphor, the highest luminescence efficiency was obtained at the 0.03 mol $Ba^{2+}$ concentration. At this time, the white LEDs showed the CCT (5300 K), CRI (89.9) and luminous efficacy (17.34 lm/W).

키워드

참고문헌

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