Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Efficient Method for the Cleavage of Fullerene Oxides with Several Aromatic Amines under Ultrasonic Irradiation

초음파 조건에서 방향족 아민 화합물을 사용한 풀러렌 산화물 쪼개짐 반응

  • Published : 2007.03.31
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Abstract

The cleavage of fullerene oxides with several aromatic amines such as 4-nitroaniline, 3-nitroaniline, 4-isopropylaniline in the present of $FeCl_3$ occurred under ultrasonic irradiation in air at $25{\sim}43^{\circ}C$. The aminated fullerenes were confirmed by MALDI-TOF-MS and UV-vis spectra.

풀러렌 산화물 쪼개짐 반응은 $FeCl_3$를 첨가한 초음파 조건에서 4-nitroaniline, 3-nitroaniline, 4-isopropylaniline 등의 방향족 아민 화합물과 풀러렌 산화물을 반응시켜 일어났다. MALDI-TOF-MS와 UV-vis 스펙트라를 사용하여 풀러렌 산화물 쪼개짐 반응으로 생성된 화합물이 아민화 풀러렌 유도체임을 확인하였다.

Keywords

References

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