Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Influence of reinforcing systems and microstructures of SBR on water swelling behaviors of SBR composites

충전 시스템과 SBR의 미세 구조가 SBR 복합체의 수팽윤 거동에 미치는 영향

  • Published : 2007.06.30
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Abstract

Water swelling behaviors of SBR vulcanizates with different reinforcing systems of carbon black, silica without a coupling agent, and silica containing a coupling agent were studied. Distilled water and 3.5% NaCl solution were used as swelling media. The water swelling ratios in the distilled water were higher than those in the salt solution. The water swelling ratios of the carbon black-filled samples were lower than those of the silica-filled ones. For the silica-filled SBR vulcanizates, the specimens without the silane coupling agent had higher water swelling ratios than those containing it. Water swelling behaviors of SBR composites with different 1,2-unit contents were also compared. The water swelling ratios tended to decrease by increasing the 1,2-unit content.

카본블랙, 커플링제가 없는 실리카, 그리고 커플링제를 함유한 실리카 등 다른 충전 시스템을 갖는 SBR 가황물의 수팽윤 거동에 대해 연구하였다. 증류수와 3.5% NaCl 용액을 팽윤 매질로 사용하였다. 증류수에서의 수팽윤비가 소금물에서의 그것보다 높았다. 카본블랙으로 보강된 가황물의 수팽윤비가 실리카로 보강된 것보다 낮았다. 실리카로 보강된 SBR 가황물의 경우, 커플링제가 없는 것이 커플링제를 함유한 것보다 더 큰 수팽윤비를 나타내었다. 1,2-유니트 함량이 다른 SBR 가황물의 수팽윤 거동에 대해서도 비교하였다. 수팽윤비는 1,2-유니트 함량이 증가함에 따라 감소하는 경향을 보였다.

Keywords

References

  1. S.-S. Choi, J.-C. Kim, and C.-S. Woo, 'Accelerated thermal aging behaviors of EPDM and NBR vulcanizates', Bull. Kor. Chem. Soc., 27, 936 (2006) https://doi.org/10.5012/bkcs.2006.27.6.936
  2. S.-S. Choi, S.-H. Ha, and C.-S. Woo, 'Thermal aging behaviors of rubber vulcanizates cured with single and binary cure systems', Bull. Kor. Chem. Soc., 27, 429 (2006) https://doi.org/10.5012/bkcs.2006.27.3.429
  3. H. Acharya and S. K. Srivastava, 'Influence of nanodispersed organoclay on rheological and swelling properties of ethylene propylene diene terpolymer', Macromol. Res., 14, 132 (2006) https://doi.org/10.1007/BF03218500
  4. G. K. Jana and C. K. Das, 'Recycling natural rubber vulcanizates through mechanochemical devulcanization', Macromol. Res., 13, 30 (2005) https://doi.org/10.1007/BF03219012
  5. G. Wang, M. Li, and X. Chen, 'Preparation and water-absorbent properties of a water-swellable rubber', J. Appl. Polym. Sci., 68, 1219 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980523)68:8<1219::AID-APP3>3.0.CO;2-G
  6. Z. Zhang, G. Zhang, D. Li, Z. Liu, and X. Chen, 'Chlorohydrin water-swellable rubber compatibilized by an amphiphilic graft copolymer. II. Effects of PVA-g-PBA and CPA on waterswelling behaviors', J. Appl. Polym. Sci., 74, 3145 (1998) https://doi.org/10.1002/(SICI)1097-4628(19991220)74:13<3145::AID-APP17>3.0.CO;2-X
  7. Z. Zhang, G. Zhang, C. Wang, D. Liu, Z. Liu, and X. Chen, 'Chlorohydrin water-swellable rubber compatibilized by an amphiphilic graft copolymer. III. Effects of PEG and PSA on water-swelling behavior', J. Appl. Polym. Sci., 79, 2509 (2001) https://doi.org/10.1002/1097-4628(20010401)79:14<2509::AID-APP1059>3.0.CO;2-0
  8. J. H. Park and D. Kim, 'Preparation and characterization of water-swellable natural rubbers', J. Appl. Polym. Sci., 80, 115 (2001) https://doi.org/10.1002/1097-4628(20010404)80:1<115::AID-APP1079>3.0.CO;2-K
  9. G. R. Cotton, 'Mixing of carbon black with rubber. I. Measurement of dispersion rate by changes in mixing torque', Rubber Chem. Technol., 57, 118 (1984) https://doi.org/10.5254/1.3535988
  10. S. Wolff and U. Gorl, 'The influence of modified carbon blacks on viscoelastic compound properties', Kautsch. Gummi Kunstst., 44, 941 (1991)
  11. T. C. Gruber and C. R. Herd, 'Anisometry measurements in carbon black aggregate populations', Rubber Chem. Technol., 70, 727 (1997) https://doi.org/10.5254/1.3538456
  12. H. Raab, J. Frohlich, and D. Goritz, 'Surface topography and ist influence on the activity of carbon black', Kautsch. Gummi Kunstst., 53, 137 (2000)
  13. S. Wolff and M.-J. Wang, 'Filler-elastomer interactions. Part IV. The effect of the surface energies of fillers on elastomer reinforcement', Rubber Chem. Technol., 65, 329 (1992) https://doi.org/10.5254/1.3538615
  14. Y.-C. Ou, Z.-Z. Yu, A. Vida, and J. B. Donnet, 'Effects of alkylation of silica filler on rubber reinforcement', Rubber Chem. Technol., 67, 834 (1994) https://doi.org/10.5254/1.3538714
  15. Y. Li, M. J. Wang, T. Zhang, F. Zhang, and X. Fu., 'Study on dispersion morphology of silica in rubber', Rubber Chem. Technol., 67, 693 (1994) https://doi.org/10.5254/1.3538704
  16. S.-S. Choi, 'Influence of silane coupling agent on properties of filled styrene-butadiene rubber compounds', Kor. Polym. J., 8, 285 (2000)
  17. A. S. Hashim, B. Azahari, Y. Ikeda, and S. Kohjiya, 'The effect of TESPT on silica reinforcement of styrene-butadiene rubber' Rubber Chem. Technol., 71, 289 (1998) https://doi.org/10.5254/1.3538485
  18. S.-S. Choi, 'Characterization of bound rubber of filled styrene-butadiene rubber compounds using pyrolysis-gas chromatography', J. Anal. Appl. Pyrolysis, 55, 161 (2000) https://doi.org/10.1016/S0165-2370(99)00095-9
  19. S.-S. Choi and I.-S. Kim, 'Filler-polymer interactions in filled polybutadiene compounds', Eur. Polym. J., 38, 1265 (2002) https://doi.org/10.1016/S0014-3057(01)00300-7
  20. S.-S. Choi, I.-S. Kim, S. G. Lee, and C. W. Joo, 'Filler-polymer interactions of styrene and butadiene units in silica-filled styrene-butadiene rubber compounds', J. Polym. Sci. Part B: Polym. Phys., 42, 577 (2004) https://doi.org/10.1002/polb.10689
  21. D. C. Harris, Quantitative Chemical Analysis, 6th Ed., W. H. Freeman and Co., New York (2003)
  22. J. McMurry and R. C. Fay, Chemistry, 4th Ed., Pearson Education, Inc., New Jersey (2004)