Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
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Behavior of Oxygen Equilibrium Pressure in CRT Glass Melts doped with Sb and Ce ions from the Viewpoint of Fining

  • Kim, Ki-Dong (Department of Materials Science add Engineering, Kunsan National University) ;
  • Kim, Hyo-Kwang (Department of Materials Science add Engineering, Kunsan National University) ;
  • Kim, Jun-Hong (Department of Materials Science add Engineering, Kunsan National University)
  • Published : 2007.08.31
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Abstract

The behavior of oxygen gas participating in fining was observed in CRT (Cathode Ray Tube) glass melts doped with $Sb_2O_5\;or\;CeO_2$ by means of a yttria-stabilized zirconia (YSZ) electrode. The temperature dependence of the oxygen equilibrium pressure ($P_{o2}$) or the activity in both melts showed typical behavior corresponding to a theoretical redox reaction. In other words, the $P_{o2}$ value of melts with $CeO_2$ was lower than that of melts with $Sb_2O_5$ above $1250^{\circ}C$. The result implies that $Sb_2O_5$, is more efficient as a fining agent compared to $CeO_2$. On the other hand, melts from a batch containing $Sb_2O_5\;and\;KNO_3$ showed much higher $P_{o2}$ values compared to melts without $KNO_3$ above $1350^{\circ}C$. It is suggested that the addition of $KNO_3$ to CRT glass batch contributes partly to the first fining of the melts.

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