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Investigation of the Water Gas Shift from Reforming Gas for CO Removal

일산화탄소 저감을 위한 개질가스의 전이반응 연구

  • Published : 2007.10.01

Abstract

Hydrogen as an energy carrier in fuel cell offers perhaps the largest potential benefits of reduced emissions of pollutants and greenhouse gases. The generation of high-purity hydrogen from hydrocarbon fuels is essential for efficient operation of fuel cell. Reduction of carbon monoxide to an acceptable level of 10ppm involves high temperature and low temperature water gas shift (WGS), followed by selective oxidation of residual carbon monoxide. The WGS reactor was designed and tested in this study to produce hydrogen-rich gas with CO to less than 5000 ppm. In the water gas shift operation, gas emerges from the reformer is taken through a high temperature shift (HTS) catalyst to reduce the CO concentration to about $2{\sim}4%$ followed to about 5000 ppm via a low temperature shift (LTS) catalyst.

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References

  1. Son J. E., 2004, 'Hydrogen & Fuel Cell Technology,' Korean Chem. Eng. Res., Vol. 42 No. 1, pp.1-9
  2. Lim S. k., Bae J. M. and Nam S. W., 2006, 'Study on Basic Characteristics of Natural Gas Autothermal Reformer for Fuel Cell Applications,' Transactions of the KSME B., Vol. 30, No.9, pp.850-857 https://doi.org/10.3795/KSME-B.2006.30.9.850
  3. Yoon W. L., Park J. W., Rhee Y. W., Han M. W. and Jeong J. H., 2003, 'Operating Characteristics of Integrated NG Reformer System for 5 kW Class PEM Fuel Cell,' PWAHAK KONGHAK, 41, pp.389-396
  4. Oh Y. S. and Jung H., 2003, 'R&D Status of Reformer and Development of Small Scale Hydrogen Generator,' Prospective of Industrial Chemistry, Vol. 6, No. 3, pp.11-29
  5. Moon D. J. and Lee B. G., 2005, 'R&D Trends and Unit Processes of Hydrogen Station,' Korean Chem. Eng. Res., Vol. 43, No. 3, pp.331-343
  6. Trimm D. L., 2005, 'Minimization of Carbonmonoxide in a Hydrogen Stream for Fuel Cell Application,' Applied Catalysis A: General, 296, pp. 1-11 https://doi.org/10.1016/j.apcata.2005.07.011
  7. Zhang Z. G., Xu G. W., Chen X., Honda K. and Yoshida T., 2004, 'Process Development of Hydrogenous Gas Production for PEFC from Biogas,' Fuel Processing Technology, 85, pp.1213-1229 https://doi.org/10.1016/j.fuproc.2003.10.017
  8. Oh Y. S., Song T. Y., Baek Y. S. and Chol L. S., 2002, 'Efficiency Analysis of Compact Type Steam Reformer,' Tans. of the Korea Hydrogen and New Energy Society, Vol. 13, No. 4, pp. 313-321