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Feasibility of Recycling Residual Solid from Hydrothermal Treatment of Excess Sludge

  • Kim, Kyoung-Rean (Marine Environment Research Department, Korea Ocean Research and Development Institute) ;
  • Fujie, Koichi (Department of Ecological Engineering, Toyohashi University of Technology) ;
  • Fujisawa, Toshiharu (EcoTopia Science Institute, Nagoya University)
  • Published : 2008.09.28

Abstract

Residual solid in excess sludge treated by hydrothermal reaction was investigated as raw material for its recycling. Treated excess sludge and residual solid were also focused on their content change during hydrothermal reaction. Two kinds of excess sludge, obtained from a local food factory and a municipal wastewater treatment process, were tested under various conditions. Following hydrothermal reaction, depending on the reaction conditions, biodegradable substrates in treated excess sludge appeared to increase. The separated residual solid was a composite composed of organic and inorganic materials. The proportion of carbon varied from 34.0 to 41.6% depending on reaction conditions. Although 1.89% of hazardous materials were detected, SiO2 (Quartz) was a predominant constituent of the residual solid. X-ray diffraction (XRD) experiments revealed that the residual solid was of a partially amorphous state, suggesting that the residual solids could be easily converted to stable and non harmful substances through a stabilization process. Thus, this technology could be successfully used to control excess sludge and its reuse.

Keywords

References

  1. Neyens, E., and Baeyens, J., "A review of thermal sludge pre-treatment process to improve dewaterability," J. Hazard. Mater., B98, 51-67 (2003)
  2. Odegaard, H., "Sludge minimization technologies-an overview," Water Sci. Technol., 49(10), 31-40 (2004)
  3. Yasui, H., and Shibata, M., "An innovative approach to reduce excess sludge production in the activated sludge process," Water Sci. Technol., 30(9), 11-20 (1994)
  4. Sakai, Y., Fukase, T., Yasui, H., and Shibata, H., "An activated sludge process without excess sludge production," Water Sci. Technol., 36(11), 163-170 (1997) https://doi.org/10.1016/S0273-1223(97)00704-X
  5. Shanableh, A., "Production of useful organic mater from sludge using hydrothermal treatment," Water Res., 34(3), 945-951 (2000) https://doi.org/10.1016/S0043-1354(99)00222-5
  6. Saby, S., Djafer, M., and Chen, G.-H., "Feasibility of using a chlorination step to reduce excess sludge in activated sludge process," Water Res., 36(3), 656-666 (2002) https://doi.org/10.1016/S0043-1354(01)00259-7
  7. Insel, G., Karahan, Gul O., Orhon, D., Vanrolleghem, P. A., and Henze, M., "Important limitations in the modeling of activated sludge biased calibration of the hydrolysis process," Water Sci. Technol., 45(12), 23-36 (2002)
  8. Novak, J. T., and Park, C., "Chemical conditioning of sludge," Water Sci. Technol., 49(10), 73-80 (2004)
  9. Oh, S., "Improvement of anaerobic digestion rate of biosolids in waste activated sludge (WAS) by ultrasonic pretreatment," Environ. Eng. Res., 11(3), 143-148 (2006) https://doi.org/10.4491/eer.2006.11.3.143
  10. Savage, P. E., "Organic chemical reactions in supercritical water," Chem. Rev., 99, 603-621 (1999) https://doi.org/10.1021/cr9700989
  11. Aymonier, C. P., Beslin, P., Jolivalt, C., and Cansell, F., "Hydrothermal oxidation of nitrogen containing compounds: the fenuron," J. Supercrit. Fluid., 17, 45-54 (2000) https://doi.org/10.1016/S0896-8446(99)00040-6
  12. Staszak, C. N., Malinkowski, K. C., and Killilea, W. R., "The pilot-scale demonstration of MODAR oxidation process for the destruction of hazardous organic waste materials," Environ. Prog., 6, 39-43 (1987) https://doi.org/10.1002/ep.670060122
  13. Shin, K., Cho, H., Nam, Y., and Lee, D., "Hydrothermal decpmposition of formic acid in sub- and supercritical water," Environ. Eng. Res., 3(2), 61-66 (1998)
  14. Kang, K., Quitain, A. T., Daimon, H., Noda, R., Goto, N., Hu, H.-Y., and Fujie, K., "Optimization of amino acids production from waste fish entrails by hydrolysis in suband supercritical water," Can. J. Chem. Eng., 79, 65-70 (2001) https://doi.org/10.1002/cjce.5450790110
  15. Quitain, A. T., Sato, N., Daimon, H., and Fujie, K., "Production of valuable materials by hydrothermal treatment of shrimp shells," Ind. Eng. Chem. Res., 40, 5885-5888 (2001) https://doi.org/10.1021/ie010439f
  16. Kim, K., Fujita, M., Daimon, H., and Fujie, K., "Application of hydrothermal reaction to biodegradability improvement of refractory pollutants: structural conversion of di- and trichloroacetic acid to biodegradable products," Journal of Water and Environment Technology (on-line journal), 1(2), 217-224 (2003) https://doi.org/10.2965/jwet.2003.217
  17. Kim, K., Fujita, M., Daimon, H., and Fujie, K., "Biodegradability improvement and structural conversion of poly vinyl alcohol (PVA) by sub- and supercritical water reaction," J. Chem. Eng. Jpn., 37(6), 744-750 (2004) https://doi.org/10.1252/jcej.37.744
  18. Kim, K., Fujita, M., Daimon, H., and Fujie, K., "Application of hydrothermal reaction for excess sludge reuse as carbon sources in biological phosphorus removal," The 4th World Water Congress, IWA 2004 Marrakech, September 19-24, 2004, Marrakech, Morocco, Presentation Ref. 85748 in CD ROM (2004)
  19. American Public Health Association, American Water Works Association and Water Environment Federation, Standard Methods for the Examination of Water and Wastewater, 20th ed., United Book Press, Inc., Baltimore, Maryland, USA, pp. 2-57-59 (1998)
  20. Kappeler, J., and Gujer, W., "Estimation of kinetic parameters of heterotrophic biomass under Aerobic conditions and characterization of wastewater for activated sludge model," Water Sci. Technol., 25(6), 125-139 (1992)
  21. Henze, M., Gujer, W., Mino, T., Matsuo, T., Wentzel, M. C., and Marais, G. v. R., "Wastewater and biomass characterization for the activated sludge model No. 2: biological phosphorus removal," Water Sci. Technol., 31(2), 13-23 (1995.)
  22. Fujita, M., Kim, K., Daimon, H., and Fujie, K., "Evaluation of the usability of excess sludge treated by hydrothermal reaction as carbon sources for enhanced biological phosphorus removal," Environmental Engineering Research (Japanese), 40, 23-28 (2003)
  23. Francis, A. A., "Conversion of blast furnace slag into new glass-ceramic material," J. Eur. Ceram. Soc., 24, 2819-2824 (2004) https://doi.org/10.1016/j.jeurceramsoc.2003.08.019
  24. Kim, C., Lee, H., and Yoon, T., "Enhanced nitrification by immobilized clinoptilolite in an activated sludge," Environ. Eng. Res., 8(2), 49-58 (2003) https://doi.org/10.4491/eer.2003.8.2.049
  25. Jung, B., "Characteristics of high temperature viscosity in solid waste incineration ash," Environ. Eng. Res., 8(5), 236-242 (2003) https://doi.org/10.4491/eer.2003.8.5.236
  26. Jung, B., Koo, S., and Lee, H., " High temperature thermal characteristics of sewage sludge and its ash," Environ. Eng. Res., 5(2), 101-106 (2000)
  27. Jang, A., Jang, H., Kim, S., Lee, J., and Kim, I., "Decontamination of heavy metals from dewatered sludge by acidithiobacillus ferrooxidans," Environ. Eng. Res., 7(4), 199-206 (2002) https://doi.org/10.4491/eer.2002.7.4.199
  28. Taruya, T., Okuno, N., and Kanaya, K., "Reuse of sewage sludge as raw material of Portland cement in japan," Water Sci. Technol., 46(10), 255-258 (2002)
  29. Okuno, N., Ishikawa, Y., Shimizu, A., and Yoshida, M., "Utilization of sludge in building materials," Water Sci. Technol., 49(10), 225-232 (2004) https://doi.org/10.2166/wst.2004.0650
  30. Shimamura, K., Tanaka, T., Miura, Y., and Ishikawa, H., "Development of a high efficiency phosphorus recovery method using a fluidized-bed crystallized phosphorus removal system," Water Sci. Technol., 48(1), 163-170 (2003)
  31. Roeleveld, P., Loeffen, P., Temmink, H., and Klapwijk, B., "Dutch analysis for P-recovery from municipal wastewater," Water Sci. Technol., 49(10), 191-199 (2004)
  32. Balmer, P., "Phosphorus recovery-an overview of potentials and possibilities," Water Sci. Technol., 49(10), 185-190 (2004)

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