DOI QR코드

DOI QR Code

NO Gas Sensing Properties of ZnO-Carbon Nanotube Composites

산화아연-탄소나노튜브 복합체의 일산화질소 가스 감지 특성

  • Park, Seong-Yong (School of Nano Science and Technology, Chungnam National University) ;
  • Jung, Hoon-Chul (School of Nano Science and Technology, Chungnam National University) ;
  • Ahn, Eun-Seong (School of Nano Science and Technology, Chungnam National University) ;
  • Nguyen, Le Hung (School of Nano Science and Technology, Chungnam National University) ;
  • Kang, Youn-Jin (School of Nano Science and Technology, Chungnam National University) ;
  • Kim, Hyo-Jin (School of Nano Science and Technology, Chungnam National University) ;
  • Kim, Do-Jin (School of Nano Science and Technology, Chungnam National University)
  • 박성용 (충남대학교 공과대학 나노공학부) ;
  • 정훈철 (충남대학교 공과대학 나노공학부) ;
  • 안은성 (충남대학교 공과대학 나노공학부) ;
  • 웬래훙 (충남대학교 공과대학 나노공학부) ;
  • 강영진 (충남대학교 공과대학 나노공학부) ;
  • 김효진 (충남대학교 공과대학 나노공학부) ;
  • 김도진 (충남대학교 공과대학 나노공학부)
  • Published : 2008.12.27

Abstract

The NO gas sensing properties of ZnO-carbon nanotube (ZnO-CNT) composites fabricated by the coaxial coating of single-walled CNTs with ZnO were investigated using pulsed laser deposition. Upon examination, the morphology and crystallinity of the ZnO-CNT composites showed that CNTs were uniformly coated with polycrystalline ZnO with a grain size as small as 5-10 nm. Gas sensing measurements clearly indicated a remarkable enhancement of the sensitivity of ZnO-CNT composites for NO gas compared to that of ZnO films while maintaining the strong sensing stability of the composites, properties that CNT-based sensing materials do not have. The enhanced gas sensing properties of the ZnO-CNT composites are attributed to an increase in the surface adsorption area of the ZnO layer via the coating by CNTs of a high surface-to-volume ratio structure. These results suggest that the ZnO-CNT composite is a promising template for novel solid-state semiconducting gas sensors.

Keywords

References

  1. G. Eranna, B. C. Joshi, D. P. Runthala and R. P. Gupta, Crit. Rev. Sol. Sta. Mater. Sci., 29, 111 (2004) https://doi.org/10.1080/10408430490888977
  2. N. Barsan, D. Koziej and U. Weimar, Sensors and Actuators B, 121, 18 (2007) https://doi.org/10.1016/j.snb.2006.09.047
  3. J. Xu, Q. Pan, Y. Shun and Z. Tian, Sensors and Actuators B, 66, 277 (2000) https://doi.org/10.1016/S0925-4005(00)00381-6
  4. T. Gao and T. H. Wang, Appl. Phys. A, 80, 1451 (2005) https://doi.org/10.1007/s00339-004-3075-2
  5. Z. Fan and J. G. Lu, J. Nanosci. Nanotech., 5, 1561 (2005) https://doi.org/10.1166/jnn.2005.182
  6. A. O. Dikovska, Sensors and Actuators A, 140, 19 (2007) https://doi.org/10.1016/j.sna.2007.05.032
  7. J. Kong, N. R. Franklin, C. Zhou, M. C. Chapline, S. Peng, J. Cho and H. Dai, Science, 287, 622 (2000) https://doi.org/10.1126/science.287.5453.622
  8. P. G. Collins, K. Bradley, M. Ishigami and A. Zettl, Science, 287, 1801 (2000) https://doi.org/10.1126/science.287.5459.1801
  9. A. Wisitsoraat, A. Tuantranont, C. Thanachyanont and P. Singjai, in Proceedings of the 1st IEEE International Conference on Nano/Micro Engineered and Molecular Systems (Zhuhai, China, January 2006), p.1487
  10. K. H. An, S. Y. Jeong, H. R. Hwang and Y. H. Lee, Adv. Mater., 16, 1005 (2004) https://doi.org/10.1002/adma.200306176
  11. T. Ikuno, T. Yasuda, S. Honda, K. Oura, M. Katayama, J.- G. Lee and H. Mori, J. Appl. Phys., 98, 114305 (2005) https://doi.org/10.1063/1.2035891
  12. Y. Kang, D. Oh, H. Song, J. Jung, H. Jung, Y. Cho and D. Kim, Kor. J. Mater. Res., 18, 253 (2008) https://doi.org/10.3740/MRSK.2008.18.5.253
  13. S. Ito, Y. Suwa, S. Kondo, S. Kameoka, K. Tomishige and K. Kunimori, Catal. Commun., 4, 499 (2003) https://doi.org/10.1016/S1566-7367(03)00132-8
  14. R. Kelly and A. Miotello, Pulsed Laser Deposition of Thin Films, p.55, ed. D. B Chrisley and G. K. Hubler, John Wiley & Sons, New York, (1994)
  15. N. J. Ianno, L. McConville, N. Shaikh, S. Pittal and P. G. Snyder, Thin Solid Films, 220, 92 (1992) https://doi.org/10.1016/0040-6090(92)90554-O
  16. J. L. Solis and V. Lantto, Sensors and Actuators B, 48, 322 (1998) https://doi.org/10.1016/S0925-4005(98)00065-3
  17. N. Koshizaki and T. Oyama, Sensors and Actuators B, 66, 119 (2000) https://doi.org/10.1016/S0925-4005(00)00323-3

Cited by

  1. Synthesis and hydrogen gas sensing properties of ZnO wirelike thin films vol.27, pp.6, 2009, https://doi.org/10.1116/1.3244563
  2. Optimization of a zinc oxide urchin-like structure for high-performance gas sensing vol.22, pp.3, 2012, https://doi.org/10.1039/C1JM13696H