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Single Cell Test for Proton Conducting Oxide Electrolytes Based on the BaCe0.9M0.1O3−δ (M=La, Al) System

단위전지 제작을 통한 BaCe0.9M0.1O3−δ (M=La, Al)계 Proton 전도성 산화물 전해질의 특성평가

  • Published : 2008.11.30

Abstract

Proton conducting oxides based on the $BaCe_{0.9}M_{0.1}O_{3-{\delta}}$ (M = La, AL) were tested for the alternative electrolyte materials of fuel cell. The power density for single cell of Air |Pt| $BaCe_{0.9}M_{0.1}O_{3-{\delta}}$ |Pt| $H_2(3%H_2O)$ system was maximum $0.04W/cm^2$ at $1000^{\circ}C$. In this system, proton transport number was proved to depend on the lattice parameters and the distortion of $CeO_6$ octahedral as a function of the ionic radii of acceptor ions. This proton conducting oxide system requires developing the new electrode materials for application.

Keywords

References

  1. Truls Norby, Marius Wideroe, Ronny Glocker, and Yngve Larring, "Hydrogen in Oxides," Dalton transactions, 3012- 18, (2004)
  2. S. V. Bhide and A. V. Virkar, "Stability of $AB_/_{1/2}B_//{1/2}O_3$- Type Mixed Perovskite Proton Conductors," J. Electrochem. Soc., 146 [12] 4386-92 (1999) https://doi.org/10.1149/1.1392648
  3. S. M. Choi, W.-S. Seo, S. Kim, and H.-L. Lee, "Humidity Effect on the Characteristics of the Proton Conductor Based on $BaR_{0.5+x}Ta_{0.5-X}O_3-\delta$(R =Rare Earth) System," J. Kor. Ceram. Soc., 45 [5] 290-96 (2008) https://doi.org/10.4191/KCERS.2008.45.5.290
  4. M. K. Paria and H. S. Maiti, "Electrical Conduction in Barium Cerate Doped with $M_2O_3$ (M=La, Nd, Ho)," Solid State Ionics, 13 285-92 (1984) https://doi.org/10.1016/0167-2738(84)90070-5
  5. H. Iwahara, H Uchida, K. Ono, and K. Okaki, "Proton Conduction in Sintered Oxides Based on $BaCeO_3$," J. Electrochem. Soc., 135 [2] 529-33 (1988) https://doi.org/10.1149/1.2095649
  6. Hiroyasu Iwahara, Tamotsu Yajima, Takahasi Hibono, and Haruhisa Ushida, "Performance of Solid Oxide Fuel Cell Using Proton and Oxide Ion Mixed Conductors Based on $BaCe_{1-x}SmxO_{3-\alpha}$," J. Electrochem. Soc., 140 [6] 1687-91 (1988) https://doi.org/10.1149/1.2221624
  7. Robert C. T. Slade and Narendra Singh, "The Perovskitetype Proton-Conducting Solid Electrolyte $BaCe_{0.90}Y_{0.10}O_{3-a}$ in High Temperature Electrochemical Cells," Solid State Ionics, 46 111-14 (1993)
  8. D.A.Stevenson, N, Jiang, R.M. Buchanan, and F. E. G. Henn, "Characterization of Gd, Yb doped Barium Cerates as Proton Conductors," Solid State Ionics, 62 279-85 (1993) https://doi.org/10.1016/0167-2738(93)90383-E
  9. R. D. Shannon, "Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides," Acta Cryst., A32 751-67 (1976)
  10. N.Bonanos, B. Ellis, and M.N.Mahmood, "Construction and Operation of Fuel Cells Based on the Solid Electrolyte $BaCeO_3:Gd$," Solid State Ionics, 44 305-11 (1991) https://doi.org/10.1016/0167-2738(91)90023-5
  11. H.Iwahara, H.Uchida, and N.Maeda, "High Temperature Fuel and Steam Electrolysis Cells Using Proton Conductive Solid Electrolytes," J. Power Sources, 7 293-301 (1982) https://doi.org/10.1016/0378-7753(82)80018-9
  12. T. Scherban, R, Villeneuve, L. Abello, and G. Lucazeau, "Raman Scattering Study of Acceptor-doped $BaCeO_3$," Solid State Ionics, 61 93-8 (1993) https://doi.org/10.1016/0167-2738(93)90339-5
  13. C. N. Darlington, "Phenomenological Theory of the Deformation of Rotated Octahedra in Perovskite," phys. stst. sol. A, 155 [1] 31-42 (1996) https://doi.org/10.1002/pssa.2211550104
  14. B. T. Melekh, V. M. Egrove, Tu. M. Baikov, N. F. Kartenko, Yu, N. Filin, M. F. Kompan, I.I. Novak, G. B. Venus, and V. B. Kulik, "Structure Phase Transitions and Optical Properties of Pure and Rare Earth Doped $BaCeO_3$, $SrCeO_3$ Prepared by Inductive Melting," Solid State Ionics, 97 465-70 (1997) https://doi.org/10.1016/S0167-2738(97)00093-3
  15. J. F. Liu and A. S. Nowick, "The Incorporation and Migration of Protons in Nd-doped $BaCeO_3$," Solid State Ionics, 50 131-38 (1992) https://doi.org/10.1016/0167-2738(92)90045-Q
  16. N. Bonanos, "Transport Properties and Conduction Mechanism in High-Temperature Protonic Conductors," Solid State Ionics, 53-56 967-74 (1992) https://doi.org/10.1016/0167-2738(92)90278-W
  17. T. Yajima, H, Iwahara, and H. Uchida, "Protonic and Oxide Ionic Conduction in $BaCeO_3$-Based Ceramics - Effect of Partial Substitution for Ba in $BaCe_{0.9}Nd_{0.1}O_3-\alpha$ with Ca," Solid State Ionics, 47 117-24 (1991) https://doi.org/10.1016/0167-2738(91)90189-I
  18. Y. Larring and T. Norby, "Protons in $LaErO_3$," Solid State Ionics, 9 1-10 (1993)
  19. H. Iwahara, T. Yajima, and H. Ushia, "Effect of Ionic Radii of Dopants on Mixed Ionic Conduction ($H^++O^{2−}$) in $BaCeO_3$-based Electrolytes," Solid State Ionics, 70/71 267- 71 (1994) https://doi.org/10.1016/0167-2738(94)90321-2
  20. D. W. Strickler and W. G. Carlson, "Electrical Conductivity in the $ZrO_2$-Rich Region of Several $M_2O_3-ZrO_2$ Systems," J. Am. Ceram. Soc., 48 [6] 286-88 (1965) https://doi.org/10.1111/j.1151-2916.1965.tb14742.x
  21. A. Mitsui, M. Miyayama, and H. Yanagida, "Evaluation of the Activation Energy for Proton Conduction in Perovskitetype Oxides," Solid State Ionics, 22 213-17 (1987) https://doi.org/10.1016/0167-2738(87)90035-X
  22. W. Munch, G Seifert, K. D. Kruer, and J. Maier, "A Quantum Molecular Dynamics Study of Proton Conduction Phenomena in $BaCeO_3$," Solid State Ionics, 86-88, 647-52 (1996) https://doi.org/10.1016/0167-2738(96)00229-9
  23. M. Yoshino, K.Nakatsuka, H. Yukawa, and M. Morinaga, "Local Electronic Structures Around Hydrogen and Acceptor Ions in Perovskite-type Oxide, $SrZrO_3$," Solid State Ionics, 127 109-23 (2000) https://doi.org/10.1016/S0167-2738(99)00274-X
  24. J. A. Kilner and R. J. Brook, "A Study of Oxygen Ion Conductivity in Doped Non-Stoichiometric Oxides," Solid State Ionics, 6 237-52 (1982) https://doi.org/10.1016/0167-2738(82)90045-5
  25. S. M. Choi, K. T. Lee, S. Kim, M. C. Chun, and H. L. Lee, "Oxygen Ion Conductivity and Cell Performance of $La_{0.9}Ba_{0.1}Ga_{1-x}Mg_xO_3-\delta$ Electrolyte," Solid State Ionics, 131 221-28 (2000) https://doi.org/10.1016/S0167-2738(00)00673-1

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