Fire Science and Engineering (한국화재소방학회논문지)

Korean Institute of Fire Science and Engineering (한국화재소방학회)
권호 표지

Study of Thermal Diffusion in the Copper Wire Using SIMS Depth Profiling

이차이온질량분석기의 깊이 분포도를 이용한 동선의 열적 확산에 대한 연구

  • Published : 2008.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Recently SIMS has attracted interest as new technique to distinguish the primary and the secondary arc beads. A Cs+ primary ion beam was used to detect the $^{12}C^-$, $^{63}Cu^-$, $^{18}O^-$, $^{35}Cl^-$ secondary ions which are formed during depth profiles in the copper wires. In this work, we studied thermal diffusion in the copper wire which are occurred with supplying over-current. The results demonstrated that Carbon and Chloride are diffused in PVC-coated copper wire deeper than none PVC-coated. However Oxygen showed the reverse diffusion property.

최근에 이차이온질량분석기(Secondary Ion Mass Spectrometry)를 이용한 1 2차 용융흔 구별에 관한 연구가 많은 관심을 끌고 있다. 동선의 깊이 분포에 따른 $^{12}C^-$, $^{63}Cu^-$, $^{18}O^-$, $^{35}Cl^-$ 이차 이온을 검출하기 위해 Cs+ 일차 이온빔을 사용하였고, 본 논문에서는 과전류에 의한 동선의 열적 확산에 대해 분석하였다. 분석결과 PVC 절연피복이 덮인 동선이 보다 더 깊이 탄소와 염소가 확산함을 보였으나, 산소는 절연피복이 덮이지 않은 동선이 더 깊이 확산된 것을 보였다.

Keywords

References

  1. Bruce V. Ettling, "Electrical Wiring in Building Fires", Fire Technology", Vol.14, No.4, pp.317-325(1978) https://doi.org/10.1007/BF01998391
  2. D.W. Levinson, "Copper Metallurgy as a Diagnostic Tool for Analysis of the Origin of Building Fires", Fire Technology, Vol.19, No.1, pp.211-222(1983)
  3. 김향곤, 최충석, 김동욱, 정헌상, "과전류에 의해 열화된 비닐코드의 특성 분석", 한국전기전자재료학회 2003년도 하계학술대회 논문집, pp.489-492(2003)
  4. 최충석, 김향곤, 송길목, "외부화염에 의해 소손된 비닐 코드의 단락 특성에 관한 연구", 한국화재소방학회 논문지, Vol.18, No.4, pp.72-77(2004)
  5. Kazuhiro Satoh, Hajime Fukushima, Shigeru Sasao, and Masaya Iwaki, "Verification of SIMS Application to the Fire Investigation Concerning Arc Beads", Fire Engineers Journal, pp.30-32, March(1999)
  6. C.Y. Chen, Y.C. Ling, J.T. Wang, and H.Y. Chen, "SIMS Depth Profiling Analysis of Electrical Arc Residues", Applied Surface Science, Vol.203-204, pp.779-784(2003) https://doi.org/10.1016/S0169-4332(02)00817-6
  7. D. Briggs and M.P. Seah, "Practical Surface Analysis(Second Edition)", Vol.2, pp.10, 11(1992)
  8. A. Benninghoven, F.G. Rudenauer, and H.W. Werner, "Secondary Ion Mass Spectrometry", Chemical Analysis, Vol.86, Wiley & Son, New York(1987)
  9. E. Niehuis, T. Heller, H. Feld, and A. Benninghoven, "Design and Performance of a Reflectron Based Time-of-flight Secondary Ion Mass Spectrometer with Electrodynamic Primary Ion Mass Separation", J. Vac. Sci. Technol., A, Vol.5, No.4, pp.1243-1246(1987) https://doi.org/10.1116/1.574781
  10. H. Feld, R. Zurmullen, A. Leute, and A. Benninghoven, "Carbon Cluster Emission from Polymers Under keV and MeV-ion Bombardment", J. Phys. Chem., Vol.94, pp.4595-4599(1990) https://doi.org/10.1021/j100374a043
  11. Y.H. Lee and S.F. Han, "Surface Analysis by Time-Of-Flight Secondary Ion Mass Spectrometry(TOF SIMS)", Analytical Science & Technology, Vol.10, No.5, pp.87-104(1997)
  12. Y.H. Lee, "Time-of-Flight Secondary Ion Mass Spectrometry (TOF-SIMS) for Polymer Surface Analysis", Polymer Science and Technology, Vol.11, No.6, pp.798-805, December(2000) https://doi.org/10.1002/1099-1581(200008/12)11:8/12<798::AID-PAT56>3.0.CO;2-G
  13. H.Y. Won and I.W. Kim, "Manufacture and Processing of PVC Streight Resin", Polymer Science and Technology, Vol.4, No.4, pp.263-277, August (1993)
  14. C.-H. Lee, D.-S. Shim, and S.-W. Kim, "Effects of Pigment on Weatherability of PVC", J. of Korean Ind. & Eng. Chemistry, Vol.6, No.1, pp.22-28, February(1995)
  15. 최충석, 김형래, 송길목, 김향곤, 김동욱, 김동우, "과부하에 의해 변형된 비닐절연전선의 구조변화 분석", 한국전기전자재료학회 2002년도 하계학술대회 논문집, pp.398-401(2002)
  16. C.-S. Choi, K.-S. Lee, and D.-C. Lee, "Analysis of Properties Variation of Thermal Deteriorated 600V Grade Heat-Resistant Polyvinyl Chloride Insulated wires", Trans. KIEE. Vol.49C, No.1, pp.8-12, Jan. (2000)
  17. H.S. Jun, S.I. Woo, and Y.G. Kim, "Kinetic Study of Dehydrochlorination Reaction of Poly(vinyl chloride)", HWAHAK KONGHAK, Vol.25, No.6, pp.623-633, December(1987)
  18. S.-J. Hong, S.C. Oh, H.-P. Lee, H.T. Kim, and K.-O. Yoo, "A Study on the Pyrolysis Characteristics of Poly(vinyl chloride)", HWAHAK KONGHAK, Vol.37, No.4, pp.515-521, August(1999)
  19. S.D. Kim, I.-H. Hwang, and D.-H. Lee, "Dehydrochlorination Kinetic Models of PVC during the course of Pyrolysis", J. Korea Society of Waste Management Vol.19, No.5, pp.602-614(2002)