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Research on Performance of LSM Coating on Interconnect Materials for SOFCs

  • Zhai, Huijuan (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences) ;
  • Guan, Wanbing (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences) ;
  • Li, Zhi (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences) ;
  • Xu, Cheng (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences) ;
  • Wang, Wei Guo (Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences)
  • Published : 2008.12.31

Abstract

Experiments were conducted using SUS430 and Crofer 22 APU steels coated by LSM using plasma spray and slurry spray methods, respectively. High-temperature conductivity and oxidation resistance were investigated. For comparison, SUS430 and Crofer 22 APU without LSM coating were also investigated and coefficient of thermal expansion (CTE) was measured. The results show that the materials without LSM coating exhibit almost the same CTE as YSZ electrolyte in a range of temperatures of $550{\sim}850^{\circ}C$. When coated with LSM, the oxidation rate of the steels decreases by $30{\sim}40%$ using slurry spray and by $10{\sim}30%$ using plasma spray whereas the steels using plasma spray have a better high-temperature conductivity than the steels using slurry spray. It is thus concluded that the LSM coating has a limited effect on increasing high-temperature conductivity while it can effectively reduce the oxidation of the steels.

Keywords

References

  1. M. Mogensen and K. Kammer, Annu. Rev. Mater. Res., 33 321-31 (2003) https://doi.org/10.1146/annurev.matsci.33.022802.092713
  2. S.J. Geng, J.H. Zhu, and Z.G. Lu, Solid State Ionics, 177 559-68 (2006) https://doi.org/10.1016/j.ssi.2005.12.004
  3. X. Guo, W. Zheng, and G. Meng, J. Function Materials, 31 [1] 23-5 (2000)
  4. S.J. Geng and J.H. Zhu, J. Power Sources, 160 1009-16 (2006) https://doi.org/10.1016/j.jpowsour.2006.02.028
  5. C.-J. Fu, N.-Q. Zhang, K.-N. Sun, and D. Zhou, J. Materials Science & Technology, 13 [2] 123-6 (2005)
  6. Z. Wang, M. Han, and X. Chen, J. World SCI-THEH R&D, 29 30-7 (2007)
  7. S. Taniguchi, M. Kadowaki, H. Kawamura et al., J. Power Sources, 55 73-9 (1995) https://doi.org/10.1016/0378-7753(94)02172-Y
  8. S. P. S. Badwal, R. Deller, K. Foger et al., Solid State Ionics, 99 [3-4] 297-310 (1997) https://doi.org/10.1016/S0167-2738(97)00247-6
  9. Z.G. Yang, G.G. Xia, G. D. Maupin et al., Surface & Coatings Technology, 201 4476-83 (2006) https://doi.org/10.1016/j.surfcoat.2006.08.082
  10. C.J.Fu, K.N. Sun, N.Q. Zhang et al., Rare metal Materials and Engineering, 35 [7] 1117-20 (2006)
  11. S.J. Geng, J.H. Zhu, M.P. Brady et al., J. Power Sources, 172 [2] 775-81 (2007) https://doi.org/10.1016/j.jpowsour.2007.05.022
  12. X. Chen, M. Han, and Z. Wang, J. Rare Metal Materials and Engineering, 36 642-44 (2007)
  13. J.H. Kim, R.H. Song, and S.H. Hyun, Solid State Ionics, 174 185-91 (2004) https://doi.org/10.1016/j.ssi.2004.07.032
  14. B.C. Church, T.H. Sanders, R.F. Speyer et al., Mater. Sci. Eng. A, [452-453] 334-40 (2007) https://doi.org/10.1016/j.msea.2006.10.149
  15. H. Bin, P. Jian, G. Wei, and LI Jian, Battery Bimonthly, 36 [5] 387-89 (2006)
  16. P. Jian, H. Bin, Y. Jie, and L. Jian, J. Iron Steel Res., 49 [10] 34-9 (2007)

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