구연산을 이용한 스테인레스 스틸의 미세 전해가공

Micro Electrochemical Machining of Stainless Steel Using Citric Acid

  • 류시형 (전북대학교 기계공학과)
  • 발행 : 2008.03.01

초록

Micro electrochemical machining (ECM) is conducted on stainless steel 304 using non-toxic electrolyte of citric acid. Electrochemical dissolution region is minimized by applying a few hundred second duration pulses between the tungsten SPM tip and the work material. ECM characteristics according to citric acid concentration, feeding velocity and electric conditions such as pulse amplitude, pulse frequency, and offset voltage are investigated through a series of experiments. Micro holes of $60{\mu}m$ in diameter with the depth of $50{\mu}m$ and $90{\mu}m$ in diameter with the depth of $100{\mu}m$ are perforated. Square and circular micro cavities are also manufactured by electrochemical milling. This research can contribute to the development of safe and environmentally friendly micro ECM process.

키워드

참고문헌

  1. Schuster, R., Kirchiner, V., Allongue, P. and Etrl, G., "Electrochemical Micromachining," Science, Vol. 289, No. 5476, pp. 98-101, 2000 https://doi.org/10.1126/science.289.5476.98
  2. Ahn, S. H., Ryu, S. H., Choi, D. K. and Chu, C. N., "Localized Electro-chemical Micro Drilling Using Ultra Short Pulses," Journal of the Korean Society of Precision Engineering, Vol. 20, No. 8, pp. 213-220, 2003
  3. Kim, B. H., "Taper Reduction by Disk-type Electrode in Micro Electrochemical Machining," Ph. D. dissertation, Seoul National University, pp. 1-121, 2005
  4. Zerfaoui, M., Oudda, H., Hammouti, B., Kertit, S. and Bekaddour, M., "Inhibition of Corrosion of Iron in Citric Acid Media by Aminoacids," Progress in Organic Coatings, Vol. 51, Issue 2, pp. 134-148, 2004
  5. Trettenhahn, G. and Koberl, A., "Anodic Decomposition of Citric Acid on Gold and Stainless Steel Electrodes: an in situ-FTIR-spectroscopic Investigation," Electrochimica Acta, Vol. 52, Issue 7, pp. 2716-2722, 2007 https://doi.org/10.1016/j.electacta.2006.09.028
  6. , C. M. and Wan, C. C., "Effect of Citric Acid as a Chelating Agent on Anodic Behaviour of Pure Iron with Potentiostatic and Cyclic Voltammetry Methods," Materials Chemistry and Physics, Vol. 33, Issues 3-4, pp. 189-196, 1993 https://doi.org/10.1016/0254-0584(93)90061-P
  7. Park, B. J., "Effects of Tool Electrode Size on Micro Electrochemical Machining Using Ultra Short Pulses," Ph. D. dissertation, Seoul National University, pp. 18-112, 2006
  8. Bard, A. J. and Faulkner, L. R., "Electrochemical Methods: Fundamentals and Applications 2nd Edition," John Wiley & Sons, pp. 1-39, 2000
  9. Kirchiner, V., Cagnon, L., Schuster, R. and Etrl, G., "Electrochemical Machining of Stainless Steel Microelements with Ultrashort Voltage Pulses," Applied Physics Letters, Vol. 79, Issue 11, pp. 1721-1723, 2001 https://doi.org/10.1063/1.1401783
  10. Sedriks, A. J., "Corrosion of Stainless Steels 2nd Edition," John Wiley & Sons, pp. 75-160, 1996