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Colouring Effect of Malayaite Formation and Synthesis Sphene-Pink Pigment

Sphene-Pink 안료합성 및 Malayaite 결정이 발색에 미치는 영향

  • Lee, Hyun-Soo (Department of Materials Science & Engineering, Myongji University) ;
  • Lee, Byung-Ha (Department of Materials Science & Engineering, Myongji University)
  • 이현수 (명지대학교 신소재공학과) ;
  • 이병하 (명지대학교 신소재공학과)
  • Published : 2008.03.31

Abstract

This paper described the study of a sphene-pink pigment based on $Cr_2O_3-SnO_2-CaO-SiO_2$ system exhibits stable pink-red color at high temperature. This study is focused on the optimization of the synthesis parameter such as temperature and holding time for the formation the Malayaite crystal. Malayaite crystal is sensitively influenced by the synthesizing temperature, maintaining time and contents of substituting chromium. The crystal phases formed at different temperatures exhibits various color. The optimum temperature is suggested at $1300^{\circ}C$ for 2 h and substituting contents of Cr for Sn is 0.01 mole. The maximum substituting contents is 0.02 mole based on analysis results by XRD, FT-IR, SEM and UV-vis.

Keywords

References

  1. G. Costa, M. J. Ribeiro, J. A. Labrincha, M. Dondi, F. Matteucci, and G. Cruciani, "Malayaite Ceramic Pigments Prepared with Galvanic Sludge," Dyes and Pigments, 78 [2] 157-64 (2008). https://doi.org/10.1016/j.dyepig.2007.11.004
  2. Xavier Faure, Anne Vanderperre, and Philippe Colomban, "Pink Pigment Optimization by Resonance Raman Spectroscopy," J. Raman spectrosc., 34 [4] 290-94 (2003). https://doi.org/10.1002/jrs.996
  3. Beatriz Julin, Hctor Beltrn, Eloisa Cordoncillo, Purificacin Escribano, JosVicente Folgado, Maria Vallet-Reg, and Rafael P. del Real, "A Study of the Method of Synthesis and Chromatic Properties of the $Cr-SnO_2$ Pigment," Eur. J. Inorg. Chem., [10] 2694-700 (2002). https://doi.org/10.1002/1099-0682(200210)2002:10<2694::AID-EJIC2694>3.0.CO;2-N
  4. Cordoncillo E, del Rio F, Carda J, Llusar M, and Escribano P, "Influence of Some Mineralizers in the Synthesis of Sphene-Pink Pigments," J. Eur. Ceram. Soc., 18 [8] 1115-20 (1998). https://doi.org/10.1016/S0955-2219(98)00010-7
  5. Frank J. Berry, Nicola Costanatini, and Lesley E. Smart, "Synthesis of Chromium-containing from Pigment Chromium Recovered from Leather Waste," J. Waste Management, 22 [7] 761-72 (2002). https://doi.org/10.1016/S0956-053X(01)00046-0
  6. Neil T. McDevitt and William L. Baun, "Infrared Absorption Study of Metal Oxides in the Low Frequency Region (700 - 240 $cm^{-1}$ )," J. Spectrochimica Acta., 20 [5] 799-808 (1964). https://doi.org/10.1016/0371-1951(64)80079-5
  7. G. Monros*, H. Pinto, J. Badenes, M. Llusar, and M. A. Tena, "Chromium(IV) Stabilisation in New Ceramic Matrices by Coprecipitation Method: Application as Ceramic Pigments," Z. Anorg. Allg. Chem., 631 [11] 2131-35 (2005). https://doi.org/10.1002/zaac.200570029
  8. A. Domnech, F. J. Torres, E. R de Sola, and J Alarcn, "Electrochemical Detection of High Oxidation States of Chromium( IV and V) in Chromium-Doped Cassiterite and Tin- Sphene Ceramic Pigmenting Systems," Eur. J. Inorg. Chem., [3] 638-48 (2006). https://doi.org/10.1002/ejic.200500775
  9. F. M. Filho, A. Z. Simes, A. Ries, L. Perazolli, E. Longo, and J. A. Varela, "Dependence of the nonlinear electrical behavior of $SnO_2$-based varistors on $Cr_2O_3$ addition," Ceram. Int., 33 [2] 187-92 (2007). https://doi.org/10.1016/j.ceramint.2005.07.025
  10. E. Lopez-Navarretea, A. Caballeroa, V. M. Orerab, F. J. Lzarob, and M. Ocaa, "Oxidation State and Localization of Chromium Ions in Cr-doped Cassiterite and Cr-doped Malayaite," J. Acta Mat., 51 [8] 2371-81(2003). https://doi.org/10.1016/S1359-6454(03)00044-2
  11. Escribano Lopez P, Guillem Monzonis C, and Alarcon Navarro J, "$Cr-SnO_2-CaO-SiO_2-Based$ Ceramic Pigments," Am. Ceram. Soc. Bull., 63 pp. 12, 1492-94 (1984).
  12. E. Lpez-Navarrete and M. Ocaa, "A Simple Procedure for the Preparation of Cr-doped Tin Sphene Pigments in the Absence of Fluxes," J. Eur. Ceram. Soc., 22 [3] 353-59 (2002). https://doi.org/10.1016/S0955-2219(01)00282-5
  13. E. Lpez-Navarrete, A. R. Gonzlez-Elipe, and M. Ocaa, "Non-conventional Synthesis of Cr-doped $SnO_2$ Pigments," Ceram. Int., 29 [4] 385-92 (2003). https://doi.org/10.1016/S0272-8842(02)00149-9
  14. Ibrar Ayub, Frank J. Berry, Clive Johnson, David A. Johnson, Elaine A. Moore, Xiaolin Ren, and Hisham M. Widatallah, "Tin-, Titanium-, and Magnesium-doped a- $Cr_2O_3$: Characterisation and Rationalisation of the Structures," Solid State Comm., 123 [3-4] 141-45 (2002). https://doi.org/10.1016/S0038-1098(02)00213-2
  15. M. A. Tena, S. Meseguer, C. Gargori, A. Fors, J. A. Badenes, and G. Monors, "Study of Cr-$SnO_2$ Cereamic Pigment and of Ti/Sn Ratio on Formation and Coloration of These Materials," J. Eur. Ceram. Soc., 27 [1] 215-21 (2007). https://doi.org/10.1016/j.jeurceramsoc.2006.04.183