Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Tetrapyrazinoindoloporphyrazine Langmuir-Blodgett Films

  • Kim, Jong-Min (Department of Fiber and Polymer Engineering, Hanyang University) ;
  • Jaung, Jae-Yun (Department of Fiber and Polymer Engineering, Hanyang University) ;
  • Ahn, Hee-Joon (Department of Fiber and Polymer Engineering, Hanyang University)
  • Published : 2008.06.30
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Abstract

We fabricated tetra(5-n-nonyl-8-tert-butyl-2,3-pyrazino[2,3-b]indolo)porphyrazinato copper(II) (Cu-Pc-$C_8$) Langmuir-Blodgett (LB) films. We further investigated the influence of arachidic acid (AA) as a transfer promoter, as well as the effect of dipping speed, on the deposition of the films on hydrophilic and hydrophobic substrates. In the case of pure Cu-Pc-$C_8$ LB deposition on a hydrophilic substrate, the transfer ratio was close to one for up-stroke depositions, but the previously deposited film was peeled off and re-spread onto water at down-stroke depositions. Whereas the stability of the Cu-Pc-$C_8$ LB films was not improved by AA addition on hydrophilic substrates, the deposition of Cu-Pc-$C_8$ was significantly improved by the presence of AA on a hydrophobic substrate. The AA-assisted deposition had transfer ratio of close to 1 and was essentially stable up to 10-layer depositions. Comparison of the UV-visible spectrum of a Cu-Pc-$C_8$/AA LB film with that of Cu-Pc-$C_8$/AA solution in dichloroethane revealed that the Soret and Q bands for the Cu-Pc-$C_8$/AA LB film were broadened and red-shifted due to the aggregation of phthalocyanines upon assembly in the LB film.

Keywords

References

  1. Y. Choe, S. Y. Park, D. W. Park, and W. Kim, Macromol. Res., 14, 38 (2006) https://doi.org/10.1007/BF03219066
  2. A. L. Thomas, Phthalocyanine Research and Applications, CRC Press, Boston, 1990
  3. S. R. Forrest, Chem. Rev., 97, 1793 (1996) https://doi.org/10.1021/cr941014o
  4. N. Kobayashi, Curr. Opin. Solid State Mat. Sci., 4, 345 (1999) https://doi.org/10.1016/S1359-0286(99)00030-3
  5. J. -Y. Jaung, M. Matsuoka, and K. Fukunishi, Dyes and Pigments, 40, 73 (1999) https://doi.org/10.1016/S0143-7208(98)00031-X
  6. K. Jsrg, L. R. Subramanian, and H. Michael, J. Porphyrins Phthalocyanines, 4, 498 (2000) https://doi.org/10.1002/1099-1409(200008)4:5<498::AID-JPP277>3.0.CO;2-F
  7. B. H. Lee, J.-Y. Jaung, S. C. Jang, and S. C. Yi, Dyes and Pigments, 65, 159 (2005) https://doi.org/10.1016/j.dyepig.2004.06.022
  8. . M. O. Flaherty, S.V. Hold, M. J. Cook, T. Torres, Y. Chen, M. Hanac, and W. J. Blau, Adv. Mater., 15, 19 (2003) https://doi.org/10.1002/adma.200390002
  9. J. -Y. Jaung, M. Matsuoka, and K. Fukunishi, Synthesis, 1998, 1347 (1998) https://doi.org/10.1055/s-1998-6092
  10. O. Berger, W. -J. Fischer, B. Adolphi, S. Tierbach, V. Melev, and J. Schreiber, J. Mater. Sci. Mater. Electron, 11, 331 (2000) https://doi.org/10.1023/A:1008933516940
  11. J. Han, J. -Y. Jaung, and H. Ahn, Colloids and Surfaces A: Physicochem. Eng. Aspects, 313, 545 (2008) https://doi.org/10.1016/j.colsurfa.2007.04.099
  12. C. -S. Cho, I. -K. Park, J. -W. Nah, and T. Akaike, Macromol. Res., 11, 2 (2003) https://doi.org/10.1007/BF03218270
  13. J. -K. Lee, J. -H. Ryou, W. -K. Lee, C. -Y. Park, S. -B. Park, and S. -K Min, Macromol. Res., 11, 476 (2003) https://doi.org/10.1007/BF03218979
  14. K. R. Yoon, H. Lee, B. K. Rhee, and C. Jung, Macromol. Res., 12, 581 (2004) https://doi.org/10.1007/BF03218447
  15. M. Choi, B. Chung, B. Chun, and T. Chang, Macromol. Res., 12, 127 (2004) https://doi.org/10.1007/BF03219005
  16. W. R. Barger, A. W. Snow, H. Wohltjen, and N. L. Jarvis, Thin Solid Films, 133, 197 (1985) https://doi.org/10.1016/0040-6090(85)90441-9
  17. S. M. Baker, J. Danzer, H. Desaire, G. Credo, and R. Flitton, Langmuir, 14, 5267 (1998) https://doi.org/10.1021/la971217i
  18. C. -W. Chen and T. -J. Liu, J. Colloid Interface Sci., 298, 298 (2006) https://doi.org/10.1016/j.jcis.2005.12.024
  19. S. Kawata and T. Nagamura, Colloids and Surfaces A: Physicochem. Eng. Aspects, 103, 257 (1995) https://doi.org/10.1016/0927-7757(95)03294-N
  20. S. Palacin, Adv. Colloid Interface Sci., 87, 165 (2000) https://doi.org/10.1016/S0001-8686(99)00043-3
  21. R. L. Cerro, J. Colloid Interface Sci., 257, 276 (2003) https://doi.org/10.1016/S0021-9797(02)00009-7
  22. M. J. Savelski, S. A. Shetty, W. B. Kolb, and R. L. Cerro, J. Colloid Interface Sci., 176, 117 (1995) https://doi.org/10.1006/jcis.1995.0015
  23. J. G. Petrov and P. G. Petrov, Langmuir, 14, 2490 (1998) https://doi.org/10.1021/la971011h
  24. A. Suzuki, H. Awano, M. Hikosaka, and H. Ohigashi, Thin Solid Films, 216, 283 (1992) https://doi.org/10.1016/0040-6090(92)90851-2
  25. J. G. Petrov, I. Kuleff, and D. Platikanov, J. Colloid Interface Sci., 88, 29 (1982) https://doi.org/10.1016/0021-9797(82)90152-7
  26. S. Ye, H. Noda, T. Nishida, S. Morita, and M. Osawa, Langmuir, 20, 357 (2004) https://doi.org/10.1021/la036008e
  27. O. Ichiro, Photosensitization of porphyrins and phthalocyanines, Kodansha Ltd., Japan, 2001
  28. T. Del Ca-o, R. Aroca, J. A. De Saja, and M. L. Rodriguez-Mendez, Langmuir, 19, 3747 (2003) https://doi.org/10.1021/la020825h
  29. M. M. El-Nahass, K. F. Abd-El-Rahman, and A. A. A. Darwish, Mater. Chem. Phys., 92, 185, (2005) https://doi.org/10.1016/j.matchemphys.2005.01.008
  30. S. Ambily and C. S. Menon, Thin Solid Films, 347, 284 (1999) https://doi.org/10.1016/S0040-6090(98)01744-1
  31. J. Puigdollers, C. Voz, M. Fonrodona, S. Cheylan, M. Stella, J. Andreu, M. Vetter, and R. Alcubilla, J. Non-Cryst. Soli., 352, 1778 (2006) https://doi.org/10.1016/j.jnoncrysol.2005.10.063
  32. M. I. Viseu, A. M. Gonalves da Silva, P. Antunes, and S. M. B. Costa, Langmuir, 18, 5772 (2002) https://doi.org/10.1021/la0117909