DOI QR코드

DOI QR Code

Effect of Si:C Ratio on Porosity and Flexural Strength of Porous Self-Bonded Silicon Carbide Ceramics

Si:C Ratio가 다공질 Self-Bonded SiC 세라믹스의 기공율과 곡강도에 미치는 영향

  • Lim, Kwang-Young (Department of Materials Science and Engineering, the University of Seoul) ;
  • Kim, Young-Wook (Department of Materials Science and Engineering, the University of Seoul) ;
  • Woo, Sang-Kuk (Energy Materials Research Center, Korea Institute of Energy Research) ;
  • Han, In-Sub (Energy Materials Research Center, Korea Institute of Energy Research)
  • 임광영 (서울시립대학교 신소재공학과) ;
  • 김영욱 (서울시립대학교 신소재공학과) ;
  • 우상국 (한국에너지기술연구원 에너지재료연구센터) ;
  • 한인섭 (한국에너지기술연구원 에너지재료연구센터)
  • Published : 2008.05.31

Abstract

Porous self-bonded silicon carbide (SiC) ceramics were fabricated at temperatures ranging from 1750 to $1850^{\circ}C$ using SiC, silicon (Si), and carbon (C) powders as starting materials. The effect of the Si:C ratio on porosity and strength was investigated as a function of sintering temperature. It was possible to produce self-bonded SiC ceramics with porosities ranging from 36% to 43%. The porous ceramics showed a maximal porosity when the Si:C ratio was 2:1 regardless of the sintering temperature. In contrast, the maximum strength was obtained when the ratio was 5:1.

Keywords

References

  1. N. Keller, C. Pham-Huu, S. Roy, M. J. Ledoux, C. Estournes, and J. Guille, 'Influence of the Preparation Conditions on the Synthesis of High Surface Area SiC for Use as a Heterogeneous Catalyst Support,' J. Mater. Sci., 34 3189-202 (1999) https://doi.org/10.1023/A:1004681806843
  2. S.-S. Hwang and T.-W. Kim, 'Fabrication and Properties of Reaction Bonded SiC Hot Gas Filter Using Si Melt Infiltration Method,' J. Kor. Ceram. Soc., 40 9 891-96 (2003) https://doi.org/10.4191/KCERS.2003.40.9.891
  3. J. Adler, 'Ceramic Diesel Particular Filters,' Int. J. Appl. Ceram. Technol., 2 6 429-39 (2005) https://doi.org/10.1111/j.1744-7402.2005.02044.x
  4. J. H. Eom, D. H. Jang, Y.-W. Kim, I. H. Song, and H. D. Kim, 'Low Temperature Processing of Porous Silicon Carbide Ceramics by Carbothermal Reduction(in Korean),' J. Kor. Ceram. Soc., 43 9 552-57 (2006) https://doi.org/10.4191/KCERS.2006.43.9.552
  5. Y.-W. Kim, Y. S. Chun, T. Nishimura, M. Mitomo, and Y. H. Lee, 'High-Temperature Strength of Silicon Carbide Ceramics Sintered with Rare-Earth Oxide and Aluminum Nitride,' Acta Mater., 55 2 727-36 (2007) https://doi.org/10.1016/j.actamat.2006.08.059
  6. S. H. Kim, Y.-W. Kim, J. Y. Yun, and H. D. Kim, 'Fabrication of Porous SiC Ceramics by Partial Sintering and their Properties(in Korean),' J. Kor. Ceram. Soc., 41 7 541-47 (2004) https://doi.org/10.4191/KCERS.2004.41.7.541
  7. V. Z. Stavric and M. Hue, 'Rekristallisiertes Siliziumkarbid,'Keram. Zeit., 27 3 125-28 (1975)
  8. S. H. Kim and Y.-W. Kim, 'Processing of Cellular SiC Ceramics Using Polymer Microbeads,' J. Kor. Ceram. Soc., 43 8 458-62 (2006) https://doi.org/10.4191/KCERS.2006.43.8.458
  9. F. F. Lange and K. T. Miller, 'Open Cell, Low-Density Ceramics Fabricated from Reticulated Polymer Substrates,'Adv. Ceram. Mater., 2 4 827-31 (1987)
  10. K. S. Seo, S. W. Park, and H. B. Kwon, 'Fabrication of Porous RBSC by Si Melt Infiltration,' J. Kor. Ceram. Soc., 37 11 1119-25 (2000)
  11. Y.-W. Kim, S. H. Kim, I. H. Song, H. D. Kim, and C. B. Park, 'Fabrication of Open-Cell, Microcellular Silicon Carbide Ceramics by Carbothermal Reduction,' J. Am. Ceram. Soc., 88 10 2949-51 (2005) https://doi.org/10.1111/j.1551-2916.2005.00509.x
  12. Y.-W. Kim, J. H. Eom, C. Wang, and C. B. Park, 'Processing of Porous Silicon Carbide Ceramics from Carbon-Filled Polysiloxane by Extrusion and Carbothermal Reduction,' J. Am. Ceram. Soc., 91 4 1361-64 (2008) https://doi.org/10.1111/j.1551-2916.2008.02280.x
  13. J. H. Eom, Y.-W. Kim, and M. Narisawa, 'Microstructural Development of Macroporous Silicon Carbide ceramics During Annealing,' J. Ceram. Proc. Res., 9 2 176-79 (2008)
  14. S. H. Yun, P. N. Tan, Y. D. Kim, and S. W. Park, 'Effects of Amounts of Carbon Source and Infiltrated Si on the Porosity and Fracture Strength of porous Reaction Bonded SiC,' J. Kor. Ceram. Soc., 44 7 381-86 (2007) https://doi.org/10.4191/KCERS.2007.44.7.381
  15. J. H. Eom, Y.-W. Kim, I. H. Song, and H. D. Kim, 'Microstructure and Properties of Porous Silicon Carbide Ceramics Fabricated by Carbothermal Reduction and Subsequent Sintering Process,' Mater. Sci. Eng. A, 464 129-34 (2007) https://doi.org/10.1016/j.msea.2007.03.076
  16. J. H. Eom, Y.-W. Kim, I. H. Song, and H. D. Kim, 'Processing and Properties of Polysiloxane-Derived Porous Silicon Carbide Ceramics Using Hollow Microspheres as Templates,' J. Europ. Ceram. Soc., 28 1029-35 (2008) https://doi.org/10.1016/j.jeurceramsoc.2007.09.009

Cited by

  1. Flexural Strength of Macroporous Silicon Carbide Ceramics vol.48, pp.5, 2011, https://doi.org/10.4191/kcers.2011.48.5.360
  2. Processing of alumina-coated glass-bonded silicon carbide membranes for oily wastewater treatment vol.14, pp.4, 2017, https://doi.org/10.1111/ijac.12693