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Synthesis and Characterization of ZnxMN1−xFe2O4 Nanoparticles by a Reverse Micelle Process

  • Kim, Sun-Woog (School of Nano & Advanced Materials Science Engineering, Changwon National University) ;
  • Kim, Hyeon-Cheol (School of Nano & Advanced Materials Science Engineering, Changwon National University) ;
  • Kim, Jun-Seop (School of Nano & Advanced Materials Science Engineering, Changwon National University) ;
  • Kim, Hyun-Ju (School of Nano & Advanced Materials Science Engineering, Changwon National University) ;
  • Bae, Dong-Sik (School of Nano & Advanced Materials Science Engineering, Changwon National University)
  • Published : 2008.06.30

Abstract

The preparation of $Zn_xMn_{1-x}Fe_2O_4$ nanoparticles in an Igepal CO-520-cyclohexane water reverse micelle solution has been studied. The transmission electron microscopy and X-ray diffraction pattern analyses revealed the resulting particles to be $Zn_xMn_{1-x}Fe_2O_4$. The average size and distribution of the synthesized particles calcined at $500^{\circ}C$ for 5 h were in the range of 10 to 20 nm and broad, respectively. The phase of the synthesized particles was crystalline, the magnetic behavior of the synthesized particles was ferromagnetic. The effect of the synthesis parameters, such as the molar ratio of water to surfactant and calcination temperature, is discussed.

Keywords

References

  1. D. S. Bae, S. W. Kim, H. W. Lee, and K. S. Han, "Synthesis and Characterization of Nanosize $Co_xNi_{1-x}Fe_2O_4$ Powders by Glycothermal Process," Mater. Lett., 57 1997-2000 (2003) https://doi.org/10.1016/S0167-577X(02)01119-9
  2. M. Shinkai, "Functional Magnetic Particles for Medical Application," J. Biosci. Bioeng., 94 606-13 (2002) https://doi.org/10.1016/S1389-1723(02)80202-X
  3. A. S. Lubbe, C. Alexiou, and C. Bergemann, "Clinical Applications of Magnetic Drug Targeting," J. Surgical Res., 95 200-06 (2001) https://doi.org/10.1006/jsre.2000.6030
  4. L. X. Tiefenauer, A. Tschirky, G. Kuhne, and R. Y. Andres, "In Vivo Evaluation of Magnetite Nanoparticles for use as a Tumor Contrast Agent in MRI," Magn. Res. Imaging., 14 391-402 (1996) https://doi.org/10.1016/0730-725X(95)02106-4
  5. R. Skmoski, "Nanomagnetics," J. Phys.: Condens. Matter., 15 R841-96 (2003) https://doi.org/10.1088/0953-8984/15/20/202
  6. M. R. J. Gibbs, "Nanomagnetism-nascent or Fully Formed," Curr. Opin. Solid State Mater. Sci., 7 83-6 (2003) https://doi.org/10.1016/S1359-0286(03)00053-6
  7. H. Su, H. Zhang, X. Tang, and X. Wei. "Effects of Calcining and Sintering Parameters on the Magnetic Properties of High-Permeability MnZn Ferrites," IEEE Trans. Magn., 41 4225-28 (2005) https://doi.org/10.1109/TMAG.2005.855327
  8. P. S. Anil Kumar, J. J. Shrotri, C. E. Despande, and S. K. Date, "Low Temperature Synthesis of $Ni_{0.8}Zn_{0.2}Fe_2O_4$ Powder and Its Characterization," Mater. Lett., 27 293-96 (1996) https://doi.org/10.1016/0167-577X(96)00010-9
  9. D. Stoppels, "Developments in Soft Magnrtic Powder Ferrites," Magn. Mater., 160 323-28 (1996) https://doi.org/10.1016/0304-8853(96)00216-8
  10. S. E. Jacobo, S. Duhalde, and H. R. Bertorello, "Rare Earth Influence on the Structural and Magnetic Properites of NiZn Ferrites," J. Magn. Magn. Mater., 272-76 2253-54 (2004)
  11. M. Seki, J. Sato, and S. Usui, "Observations of Ultrafine $ZnFe_2O_4$ Particles with Transmission Electron Microscopy," J. Appl. Phys., 63 [5] 1424-27 (1988) https://doi.org/10.1063/1.339974
  12. S. Komarneni, E. Freagan, E. Bravel, and R. Roy, "Hydrothermal Preparation of Ultrafine Ferrites and Their Sintering," J. Am. Ceram. Sci., 71 [1] C26-C8 (1988)
  13. J. R. Ahn, D. S. Bae, and J. S. Kim, "$CO_2$ Decomposition properties of Ternary Ferrites Synthesized by the Wet Processing," J. Kor. Ceram. Soc., 37 [10] 962-67 (2000)
  14. P. Sainamthip and V. R. W. Amarakoon, "Preparation of Manganese Zinc Ferrite Powders by Alcoholic Dehydration of Citrate/Formate Solutions," J. Am. Ceram. Soc., 71 [2] C-92-C-5 (1988)
  15. D. S. Bae, K. S. Han, and S. H. Choi, "Fabrication and Characterization of Ru-doped $TiO_2$ Composite Membranes by the Sol-gel Process," Mate. Lett., 33 101-05 (1997) https://doi.org/10.1016/S0167-577X(97)00082-7
  16. B. K. Paul and S. P. Moulik, "Structure, Dynamic and Transport Properties of Microemulsions," Ady. Coll. Inter. Sci., 78 99-195 (1998) https://doi.org/10.1016/S0001-8686(98)00063-3
  17. K. Ossed-Asare and F. J. Arriagada, "Preparation of $SiO_2$ Nanoparticles in Non-Ionic Reverse Miceller System," Colloids and Surfaces, 50 321-39 (1990) https://doi.org/10.1016/0166-6622(90)80273-7
  18. V. pillai, P. Kumar, M. J. Hou, P. Ayyub, and D. D. Shah, "Preparation of Nanoparticles of Silver Halides, Superconductors and Magnetic Materials using Water-in-Oil Microemulsions as Nano-Reactors," Ady. Coll. Inter. Sci., 55 241-69 (1995) https://doi.org/10.1016/0001-8686(94)00227-4
  19. P. Monnoyer, A. Fonseca, and J. B. Nagy, "Preparation of Colloidal AgBr Particles form Microemulsions," Coll. Surf. A: Physicochemical Eng. Aspects., 100 233-43 (1995) https://doi.org/10.1016/0927-7757(95)03187-I
  20. Y. Yafet and C. Kittel, "Antiferromagnetic Arrangements in Ferrites," Phys. Rev., 87 290-94 (1952) https://doi.org/10.1103/PhysRev.87.290