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Ferroelectric and Magnetic Properties of BiFeO3 Thin Films Deposited on SrTiO3 Substrate

SrTiO3기판 위에 증착한 BiFeO3박막의 강유전 및 자기적 특성

  • Lee, Eun-Gu (Department of Advanced Materials Engineering, Chosun University) ;
  • Kim, Sun-Jae (Department of Advanced Institute of Nano Technologies, Sejong University) ;
  • Lee, Jae-Gab (School of Advanced Materials Engineering, Kookmin University)
  • Published : 2008.06.30

Abstract

$BiFeO_3$ films were hetero-epitaxially grown on $SrTiO_3$ substrate with a various orientation by pulse laser deposition. $BiFeO_3$ films grown on (111) $SrTiO_3$ substrate have a rhombohedral structure, identical to that of single crystals. On the other hand, films grown on (110) or (001) $SrTiO_3$ substrate are monoclinically distorted from the rhombohedral structure due to the epitaxial constraint. The easy axis of spontaneous polarization is close to [111] for the variously oriented films. Dramatically enhanced polarization and magnetization have been found for $BiFeO_3$ thin films grown on $SrTiO_3$ substrate comparing to that of $BiFeO_3$ crystals. The results are explained in terms of an epitaxially-induced transition between cycloidal and homogeneous spin states, via magneto-electric interactions.

Keywords

References

  1. H. Schmid, "Multi-ferroic Magnetoelectrics," Ferroelectrics 162 317-38 (1994) https://doi.org/10.1080/00150199408245120
  2. N. A. Hill, "Why are there so Few Magnetic Ferroelectries?," J. Phys. Chem. B 104 6694-709 (2000) https://doi.org/10.1021/jp000114x
  3. V. A. Isupov, "Nonlinearity of the Concentration Dependence of the Curie Temperature in Ferroelectric Perovskite Solid Solutions," Phys. Status Solidi A 181 211-18 (2000) https://doi.org/10.1002/1521-396X(200009)181:1<211::AID-PSSA211>3.0.CO;2-J
  4. M. M. Kumar, S. Srinath, G S. Kumar, and S. V. Suryanarayana, "Spontaneous Magnetic Moment in $BiFeO_3-BaTiO_3$ Solid Solutions at Low Temperatures," J. Magn. Magn. Mater., 188 203-12 (1998) https://doi.org/10.1016/S0304-8853(98)00167-X
  5. S. A. Fedulov, P. B. Ladyzhinskii, I. L. Pyatigorskaya, and Y. N. Venevtsev, "Complete Phase Diagram of the $PbTiO_3-BiFeO_3$ System," Sov. Phys.-Solid State, 6 375-78 (1964)
  6. G. A. Smolenskii and V. M. Yudin, "Weak Ferromagnetism of some $BiFeO_3-Pb(Fe_{0.5}Nb_{0.5}O_3$ Perovskites," Sov. Phys. Solid State, 6 2936-42 (1965)
  7. T. Fujii, S. Jinzenji, Y. Asahara, A. Kajima, and T. Shinjo, "Magnetic Properties of $BiFeO_3-BaTiO_3$ and $BiFeO_3-PbTi(Zr)O_3$ Glassy Sputtered Films," J. Appl. Phys., 64 5434-36 (1988) https://doi.org/10.1063/1.342338
  8. T. Kanai, S. Ohkoshi, and K. Hashimoto, "Magnetic, Electric and Optical Functionalities of $(PLZT)_x(BiFeO_3)_{1-x}$ Ferroelectric-ferromagnetic thin Films," J. Phys and Chem. Solids, 64 391-97 (2003) https://doi.org/10.1016/S0022-3697(02)00284-6
  9. K. Ueda, H. tabata, and T. Kawai, "Coexistence of Ferroelectricity and Ferromagnetism in $BiFeO_3-BaTiO_3$ thin Films at Room Temperature," Appl. Phys. Lett., 75 555-57 (1999) https://doi.org/10.1063/1.124420
  10. D. N. Astrov, "The Magnetoelectric Effect in Antiferro-magnetics," Sov. Phys. JETP, 11 708-09 (1960)
  11. P. Fischer, M. Polomska, I. Sosnowsa, and M. Szymanski, "Temperature Dependence of the Crystal and Magnetic Structure of $BiFeO_3$" J. Phys. C, 13 1931-40 (1980) https://doi.org/10.1088/0022-3719/13/10/012
  12. I. Sosnowska, T. Peterlin-Neumaier, and E. Steichele, "Spiral Magnetic Ordering in Bismuth Ferrite," J. Phys. C, 15 4835-46 (1982) https://doi.org/10.1088/0022-3719/15/23/020
  13. B. Ruette, S. Zvyagin, A. P. Pyatakov, A. Bush, J. F. Li, V. I. Belotelov, A. K. Zvezdin, and D. Viehland, "Magnetic-field-induced Phase Transition in $BiFeO_3$ Observed by High-field Electron Spin Resonance: Cycloidal to Homogeneous Spin Order," Phys. Rev. B, 69 064114 (2004) https://doi.org/10.1103/PhysRevB.69.064114
  14. J. Wang, J. B. Neaton, H. Zheng, V. Nagarajan, S. B. Ogale, B. Liu, D. Viehland, V. Vaithyanathan, D. G. Schlom, U. V. Waghmare, N. A. Spaldin, K. M. Rabe, M. Wuttig, and R. Ramesh, "Epitaxial $BiFeO_3$ Multiferroic thin Film Hetero-structures," Science, 299 1719-22 (2003) https://doi.org/10.1126/science.1080615
  15. C. Michel, J-M. Moreau, G. D. Achenbach, R. Gerson, and W. J. James, "The Atomic Structure of $BiFeO_3$," Solid State Commun., 7 701-04 (1969) https://doi.org/10.1016/0038-1098(69)90597-3
  16. J. D. Bucci, B. K. Robertson, and W. J. James, "The Precision Determination of the Lattice Parameters and the Coefficients of Thermal Expansion of $BiFeO_3$," J. Appl. Cryst., 5 187-91 (1972) https://doi.org/10.1107/S0021889872009173
  17. J. R. Teague, R. Gerson, and W. J. James, "Dielectric Hysteresis in Single Crystal $BiFeO_3$," Solid State Commun., 8 1073-74 (1970) https://doi.org/10.1016/0038-1098(70)90262-0
  18. Yu. E. Roginskaya, Yu. Ya. Tomashpol'skii, Yu. N. Venevtsev, V. M. Petrov, and G. S. Zhdanov, "The Nature of the Dielectric and Magnetic Properties of $BiFeO_3$," Sov. Phys. JETP, 23 47-51 (1966)
  19. I. Sosnowska, M. Loewenhaupt, W. I. F. David, and R. Ibberson, "Investigation of the Unusual Magnetic Spiral Arrangement in $BiFeO_3$," Physica B 180 117-18 (1992) https://doi.org/10.1016/0921-4526(92)90678-L