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Formation of Sn-dispersed Si Nanoparticles by Co-grinding

  • Kim, Bong-Chull (Sasmung SDI Co. Ltd.) ;
  • Uono, Hiroyuki (Mitsubishi Chemical Corporation MCC-Group Science &Technology Research Center) ;
  • Ue, Makoto (Mitsubishi Chemical Corporation MCC-Group Science &Technology Research Center) ;
  • Senna, Mamoru (Department of Applied Chemistry, Faculty of Science and Technology, Keio University)
  • Published : 2009.11.30

Abstract

An immiscible Si/Sn (=7/3 by volume) powder mixture was subjected to simple grinding and subsequent leaching process to give Sn nanopowder reinforced or dispersed in Si powder. Crystallite and their agglomerates of Si were ca. 15 nm and 100 nm, respectively. Sn remained at 4.5 vol% in Si powder after aqueous HCl leaching, dispersively occluded in Si matrix as confirmed by ICP analysis and cross sectional TEM observation.

Keywords

References

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