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Preparation of Spherical Activated Carbon and Their Physicochemical Properties

  • Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University) ;
  • Kim, Jong-Gyu (Hanil Green Tech Co. Ltd.) ;
  • Kim, Hyuk (Hanil Green Tech Co. Ltd.) ;
  • Chen, Ming-Liang (Department of Advanced Materials & Science Engineering, Hanseo University) ;
  • Zhang, Feng-Jun (Department of Advanced Materials & Science Engineering, Hanseo University,Anhui Key Laboratory of Advanced Building Materials, Anhui University of Architecture) ;
  • Zhang, Kan (Department of Advanced Materials & Science Engineering, Hanseo University) ;
  • Meng, Ze-Da (Department of Advanced Materials & Science Engineering, Hanseo University)
  • Published : 2009.11.30

Abstract

In this study, we used coal based activated carbons as starting material and phenolic resin (PR) as a bonding agent to prepare spherical shaped activated carbons. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity and pressure drop. According to the results, the spherical activated carbon prepared with activated carbon and PR at a ratio of 60:40 was found to have the best formation of spherical shape, which was found in sample SAC40. After activation, SAC40 has high BET surface area, iodine adsorption capability and strength value, and lowest pressure drop.

Keywords

References

  1. S. H. Joo, S. J. Choi, I. Oh, J. Wak, Z. Liu, O. Terasaki, and R. Ryoo, “Ordered Nanoporous Arrays of Carbon Supporting High Dispersions of Platinum Nanoparticles,” Nature, 412 169-72 (2001) https://doi.org/10.1038/35084046
  2. E. Frackowiak, “Carbon Materials for Supercapacitor Application,” Phys. Chem. Chem. Phys., 9 1774-85 (2007) https://doi.org/10.1039/b618139m
  3. M. A. de la Casa-Lillo, F. Lamari-Darkrim, D. Cazorla-Amoros, and A. Linares-Solano, “Hydrogen Storage in Activated Carbons and Activated Carbon Fibers,” J. Phys. Chem. B, 106 10930-34 (2002) https://doi.org/10.1021/jp014543m
  4. Y. R. Lin and H. Teng, “A Novel Method for Carbon Modification with Minute Polyaniline Deposition to Enhance the Capacitance of Porous Carbon Electrodes,” Carbon, 41 2865-71 (2003) https://doi.org/10.1016/S0008-6223(03)00424-X
  5. J. Lee, S. Yoon, T. Hyeon, S. M. Oh, and K. B. Kim, “Synthesis of a New Mesoporous Carbon and Its Application to Electrochemical Double-layer Capacitors,” Chem. Commun., 21 2177-78 (1999)
  6. A. Vinu, C. Streb, V. Murugesan, and M. Hartmann, “Adsorption of Cytochrome C on New Mesoporous Carbon Molecular Sieves,” J. Phys. Chem. B, 107 8297-99 (2003) https://doi.org/10.1021/jp035246f
  7. C. T. Hsieh and H. Teng, “Influence of Mesopore Volume and Adsorbate Size on Adsorption Capacities of Activated Carbons in Aqueous Solutions,” Carbon, 38 863-69 (2000) https://doi.org/10.1016/S0008-6223(99)00180-3
  8. I. Martin-Gullon and R. Font, “Dynamic Pesticide Removal with Activated Carbon Fibers,” Water Res., 35 516-20 (2001) https://doi.org/10.1016/S0043-1354(00)00262-1
  9. Q. Li, V. L. Snoeyink, B. J. Marinas, and C. Campos, “Elucidating Competitive Adsorption Mechanisms of Atrazine and NOM Using Model Compounds,” Water Res., 37 773-84 (2003) https://doi.org/10.1016/S0043-1354(02)00390-1
  10. K. Nakagawa, A. Namba, S. R. Mukai, H. Tamon, P. Ariyadejwanich, and W. Tanthapanichakoon, “Adsorption of Phenol and Reactive Dye from Aqueous Solution on activated carbons derived from Solid Wastes,” Water Res., 38 1791-98 (2004) https://doi.org/10.1016/j.watres.2004.01.002
  11. Z. Yue, J. Economy, K. Rajagopalan, G. Bordson, M. Piwoni, L. Ding, V. L. Snoeyink, and B. J. Marinas, “Chemically Activated Carbon on a Fiberglass Substrate for Removal of Trace Atrazine From Water,” J. Mater. Chem., 16 3375-80 (2006) https://doi.org/10.1039/b606679h
  12. S. Han, K. Sohn, and T. Hyeon, “Fabrication of New Nanoporous Carbons through Silica Templates and Their Application to the Adsorption of Bulky Dyes,” Chem. Mater., 12 3337-41 (2000) https://doi.org/10.1021/cm000106t
  13. H. Tamai, T. Kakii, Y. Hirota, T. Kumamoto, and H. Yasuda, “Synthesis of Extremely Large Mesoporous Activated Carbon and Its Unique Adsorption for Giant Molecules,” Chem. Mater., 8 454-62 (1996) https://doi.org/10.1021/cm950381t
  14. C. H. Chang and A. Stella, “Control Performance of Liquid Column Vibration Absorbers,” Prep. Symp.: Am. Chem. Soc. Div. Fuel Chem., 43 580-86 (1998) https://doi.org/10.1016/S0141-0296(97)00062-X
  15. F. Haghseresht, S. Nouri, J. J. Finnerty, and G. Q. Lu, “Effects of Surface Chemistry on Aromatic Compound Adsorption from Dilute Aqueous Solutions by Activated Carbon,” J. Phys. Chem. B, 106 10935-43 (2002) https://doi.org/10.1021/jp025522a
  16. A. Arenillas, F. Rubiera, J. B. Parra, C. O. Ania, and J. J. Pis, “Surface Modification of Low Cost Carbons for Their Application in the Environmental Protection,” Appl. Surf. Sci., 252 619-24 (2005) https://doi.org/10.1016/j.apsusc.2005.02.076
  17. A. Derylo-Marczewska and A. W. Marczewski, “Effect of Adsorbate Structure on Adsorption from Solutions,” Appl. Surf. Sci., 196 264-72 (2002) https://doi.org/10.1016/S0169-4332(02)00064-8
  18. A. M. Puziy, O. I. Poddubnaya, V. N. Zaitsev, and O. P. Konoplitska, “Modeling of Heavy Metal Ion Binding by Phosphoric Acid Activated Carbon,” Appl. Surf. Sci., 221 421-29 (2004) https://doi.org/10.1016/S0169-4332(03)00956-5
  19. J. B. Yang, L. C. Ling, L. Liu, F. Y. Kang, Z. H. Huang, and H. Wu, “Preparation and Properties of Phenolic Resinbased Activated Carbon Spheres with Controlled Pore Size Distribution,” Carbon, 40 911-16 (2002) https://doi.org/10.1016/S0008-6223(01)00222-6
  20. Z. Liu, L. Ling, W. Qiao, and L. Liu, “Effect of Hydrogen on the Mesopore Development of Pitch-based Spherical Activated Carbon Containing Iron During Activation by Steam,” Carbon, 37 2063-66 (1999) https://doi.org/10.1016/S0008-6223(99)00058-5
  21. G. Gryglewicz, K. Grabas, and E. Lorenc-Grabowska, “Preparation and Characterization of Spherical Activated Carbons from Oil Agglomerated Bituminous Coal for Removing Organic Impurities from Water,” Carbon, 40 2403-11 (2002) https://doi.org/10.1016/S0008-6223(02)00119-7
  22. H. Nakagawa, K. Watanabe, Y. Harada, and K. Miura, “Control of Micropore Formation in the Carbonized Ion Exchange Resin by Utilizing Pillar Effect,” Carbon, 37 1455-61 (1999) https://doi.org/10.1016/S0008-6223(99)00008-1
  23. V. M. Gunko, R. Leboda, J. Skubiszewska-Zieba, B. Charmas, and P. Oleszczuk, “Adsorbents from Waste Ion Exchange Resins,” Carbon, 43 1143-50 (2005) https://doi.org/10.1016/j.carbon.2004.09.032
  24. E. M. Zippi and G. W. Kabalka, “Characterization and Pyrolysis of Poly(Styrene) Derivatives,” Carbon, 34 1539-42 (1996) https://doi.org/10.1016/S0008-6223(96)00101-7
  25. M. Kocirik, J. Brych, and J. Hradil, “Carbonization of Bead-shaped Polymers for Application in Adsorption and in Composite Membranes,” Carbon, 39 1919-28 (2001) https://doi.org/10.1016/S0008-6223(00)00326-2
  26. American Society for Testing and Materials, “Standard Test Method for Determination of Iodine Number of Activated Carbon,” Philadelphia, PA: ASTM Committee on Standards (1986)
  27. Japanese Industrial Standard Specifies the Testing Methods, “Testing Methods for Carbon Blocks,” Japan Carbon Association (1995)
  28. N. S. Roh, K. H. Kim, and D. C. Kim, “Rheological Characteristics of Coal-water Mixture Fuel and Pressure Losses in Pipe Flow,” J. Kor. Ins. Chem. Eng., 33 282-91 (1995)
  29. W. Lu and D. D. L. Chung, “Mesoporous Activated Carbon Filaments,” Carbon, 35 427-30 (1997) https://doi.org/10.1016/S0008-6223(97)89614-5
  30. J. W. Kim, M. H. Sohn, D. S. Kim, S. M. Sohn, and Y. S. Kwon, “Production of Granular Activated Carbon from Waste Walnut Shell and Its Adsorption Characteristics for $Cu^{2+}$ Ion,” J. Hazardous Materials, 85 301-15 (2001) https://doi.org/10.1016/S0304-3894(01)00239-4
  31. S. C. Kim, I. K. Hong, and K. A. Park, “Preparation and Performance of the Briquette Type Activated Carbon Based on Bituminous Coal,” J. Industrial Eng. Chem., 3 218-22 (1997)

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