Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Silver Coating on the Porous Pellets from Porphyry Rock and Application to an Antibacterial Media

반암(맥반석)으로 제조한 다공성 펠렛의 Ag 담지 및 항균 메디아로서의 적용

  • Han, Yo-Sep (Department of Geoenvironmental System Engineering, Hanyang University) ;
  • Kim, Hyun-Jung (Department of Chemical and Environmental Engineering, University of California) ;
  • Shin, Young-Seop (Department of Geoenvironmental System Engineering, Hanyang University) ;
  • Park, Jai-Koo (Department of Geoenvironmental System Engineering, Hanyang University) ;
  • Ko, Jae-Churl (Graduate School of Knowledge Based Technology and Energy, Korea Polytechnic University)
  • 한요셉 (한양대학교 지구환경시스템공학과) ;
  • 김현중 ;
  • 신영섭 (한양대학교 지구환경시스템공학과) ;
  • 박재구 (한양대학교 지구환경시스템공학과) ;
  • 고재철 (한국산업기술대 에너지대학원)
  • Published : 2009.01.31
Download PDF
⟨ Previous Next ⟩

Abstract

The porous pellets were prepared from porphyry by slurry foaming method. The effect of sintering temperatures on pore structure of porous porphyry pellets with different extension ratio ($E_R$) was investigated by specific surface area, water absorption and porosity, which changed with sintering temperatures. When the sintering temperatures increased from $975^{\circ}C$ to $1075^{\circ}C$, specific surface area and water absorption of the all samples decreased. In case of the sample with an equal sintering temperature, $E_R=3.0$ pellets had little influence on pore structure compared to the $E_R=2.0$ pellets. As a results, it was shown by SEM that facilitated formation of micro pores at $E_R=2.0$ pellets shrunk increasingly after sintering process. At $E_R=3.0$ and sintering temperature at $1025^{\circ}C$, optimum conditions of the porous porphyry porous pellets was found. Also, Escherichia coli removal efficiency of the silver-containing porphoyry porous pellets was measured for the feasibility as a antibacterial media. The antibacterial activity of prepared silver-containing sample was maintained above 90% for 40 days.

Keywords

References

  1. K. Ishizaki, S. Komarneni, and M. Nanko, “Kluwer Academic Publishers, Porous Materials : Process Technology and Applications,” 1-11, London, 1998.
  2. J. B. Hwang, M. O. Yang, and M. S. Koo, “Extraction of Minerals and Elimination Effect of Heavy Metals in Water by Nohwado Quartz Porphyry,” Analytical Sci. & Tech., 9 210-19 (1996).
  3. H. H. Kim, S. K. Park, K. B. Chung, and S. H. Chang, “Preparation of Adsorbent from Quartz Porphyry : NaOH Activation,” J. Korean Ind. Eng. Chem., 11 183-89 (2000).
  4. J. B. Hwang, M. O. Yang, M. A. Kim, and S. H. Park, “Extraction of Minerals and Elimination Effect of Heavy Metals in Water by Korean Quartz Porphyry,” Analytical Sci. & Tech., 9 310-19 (1996).
  5. Z. X. Quen, C. R. Yin, Y. S. Jin, M. S. Seok, and S. T. Lee, “Removal of Heavy Metal and Hydrogen Sulfide / Nitrophenol Using Mackban-Stone,” J. of KOWREC, 9 45-51 (2001).
  6. J. K. Park and J. S. Lee, “Preparation of Porous Cordierite Using Gelcasting Method and its Feasibility as a Filter,” J. Porous Mater., 9 203-10 (2003). https://doi.org/10.1023/A:1020939018359
  7. T. N. Kim, Q. L. Feng, J. O. Kim, J. Cui, H. H. Wang, G. C. Chen, and F. Z. Cui, “Antimicrobial Effects of Metal Inos($Ag^+,\;Cu^{2+},\;Zn^{2+}$) in Hydroxyapatite,” J. Mater. Sci : Mater. Med., 9 129-34 (1998). https://doi.org/10.1023/A:1008811501734
  8. Ar. Hendry and IO. Strwart, “Silver-Resistant Enterobacteriaceae from Hospital Patients,” Can. J. Microbial., 25 915-21 (1979). https://doi.org/10.1139/m79-136
  9. S. J. Kramer, J. A. Spadaro, and D. A. Webster, “Antibacterial and Osteoinductive Properties of Demineralized Bone Matrix Treated with Silver,” J. Clin Ortho., 161 154-62 (1979).
  10. S. Biloe and S. Mauran, “Gas Flow through Highly Porous Graphite Matrices,” Carbon, 41 525-37 (2003). https://doi.org/10.1016/S0008-6223(02)00363-9
  11. J. K. Park and S. H. Lee, “Observation and Segmentation of Gray Images of Surface Cells in Open Cellular Foams,” J. Ceram. Soc. Jpn., 109 7-12 (2001). https://doi.org/10.2109/jcersj.109.S7
  12. K. S., Handbook of Bactericide and Fungicide, Tokyo, 1986.
  13. W. H. Seo, Y. S. Han, Y. Jeong, and J. K. Park, “Preparation of Ag-Impregnated Porous Ceramic Beads and Antibacterial Properties,” J. KSEE, 5 549-54 (2005).
  14. K. H. Lee, H. J. Kim, and J. K. Park, “Preparation of Porous Lime Filters and SOx Removal Characteristics,” J. KOSAE, 20 153-59 (2004).
  15. J. K. Park, H. Y. Kim, and J. S. Lee, “Preparation of Macroporous Pellet from Industrial Waste Flyash by Foaming Method,” Geosystem Eng., 4 112-16 (2001). https://doi.org/10.1080/12269328.2001.10541177
  16. J. S. Lee and J. K. Park, “Processing of Porous Ceramic Spheres by Pseudo-Double-Emulsion Method,” Ceram. Int., 29 271-78 (2003). https://doi.org/10.1016/S0272-8842(02)00115-3
  17. Y. S. Han, J. B. Li, Q. M. Wei, and Ke Tang, “The Effect of Sintering Temperatures on Alumina Foam Strength,” Ceram. Int., 28 755-59 (2002). https://doi.org/10.1016/S0272-8842(02)00039-1
  18. H. Y. Kang, M J. Jung, and Y. K. Jeong, “Antibacterial Activity and the Stability of an $Ag^+$ Solution made Using Metallic Silver,” Korean J. Biotechnol. Bioeng., 5 521-24 (2000).
  19. Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, and J. O. Kim, “A Mechanistic Study of the Antibacterial Effect of Silver Ions on Escherichia coli and Staphylococcus aureus,” J. of Biomed. Mater. Res., 52 662-68 (2000). https://doi.org/10.1002/1097-4636(20001215)52:4<662::AID-JBM10>3.0.CO;2-3
  20. EPA., Drinking Water Standards and Health Advisories, Washington DC : EPA 822-R-04-005 (2004).

Cited by

  1. Changes in the porosity of bulk graphite according to the viscosity of resin for impregnation vol.16, pp.2, 2015, https://doi.org/10.5714/CL.2015.16.2.132
  2. EVOH nanocomposite films with enhanced barrier properties under high humidity conditions vol.35, pp.4, 2013, https://doi.org/10.1002/pc.22707