DOI QR코드

DOI QR Code

Effect of MgB6 Addition on Synthesis of Hexagonal Boron Nitride

Hexagonal Boron Nitride의 합성에 있어서 MgB6 첨가의 효과

  • Lee, Dae-Jin (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering & Technology) ;
  • Jee, Mi-Jung (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering & Technology) ;
  • Choi, Byung-Hyun (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering & Technology) ;
  • Lee, Mi-Jai (Electronic Materials Laboratory, Korea Institute of Ceramic Engineering & Technology) ;
  • Cho, Nam-Hee (School of Materials Science and Engineering, Inha University) ;
  • Cha, Mi-Sun (Large Industry)
  • Published : 2009.01.31

Abstract

The h-BN powder was synthesized by amorphous $B_2O_3$ and activated carbon at $1550^{\circ}C$ in nitrogen atmosphere, whose properties were examined according to $MgB_6$ addition. Amount of $MgB_6$ addition was varied in the range of $0{\sim}$10\;wt% of the initial mixture. It was observed that $MgB_6$ addition led to an increase in the amount and the grain size of h-BN and decrease in the amount of $B_4C$ forming. When $MgB_6$ added 5 wt%, the amount and crystallinity of h-BN increased as the holding time at the synthesis temperature was prolonged. It was also confirmed that the regularity of three-dimensional ordering of h-BN increases.

Keywords

References

  1. Kempfer, L., “The Many Faces of Boron Nitride,” Mater. Eng., 107, 41-4 (1990).
  2. Hasan Erdem Çamurlu, Naci Sevinç, and Yavuz Topkaya, “Effect of Calcium Carbonate Addition on Carbothermic Formation of Hexagonal Boron Nitride,” J. Eur. Ceram. Soc., 28 [3] 679-89 (2008). https://doi.org/10.1016/j.jeurceramsoc.2007.07.002
  3. Aydo˘gdu, A. and Sevinc¸, N., “Carbothermic Formation of Boron Nitride,” J. Eur. Ceram. Soc., 23 3153-61 (2003). https://doi.org/10.1016/S0955-2219(03)00092-X
  4. Joon, S. J. and Jha, A. A., “Vapour-Phase Reduction and the Synthesis of Boron-Based Ceramic Phases,” J. Mat. Sci., 30 607-14 (1995). https://doi.org/10.1007/BF00356318
  5. T.S. Bartniskaya, A.V. Kurdyumov, V.I. Lyashenko, N.F. Ostrovskaya, and I.G. Rogovaya, “Catalytic Synthesis of Graphite-like Boron Nitride,” Powder Metallurgy and Metal Ceramics, 35 [5-6] 296-300 (1996). https://doi.org/10.1007/BF01328837
  6. Hwang, Chyi-Ching and Chung, Shyan-Lung, “Combustion Synthesis of Boron Nitride Powder,” J. Mater. Res., 13 [3] 680-86 (1998). https://doi.org/10.1557/JMR.1998.0085
  7. H. Lorenz and I. Orgzall, “Influence of the Initial Crystallinity on the High Pressure-High Temperature Phase Transition in Boron Nitride,” Acta Mater., 52 1909-16 (2004). https://doi.org/10.1016/j.actamat.2003.12.030