DOI QR코드

DOI QR Code

Preparation and Photonic Properties of CNT/TiO2 Composites Derived from MWCNT and Organic Titanium Compounds

  • Oh, Won-Chun (Department of Advanced Materials & Science Engineering, Hanseo University)
  • Published : 2009.05.31

Abstract

In this study, CNT/$TiO_2$ composites derived from various titanium alkoxides and multiwalled carbon nanotubes (MWCNTs) were synthesized and characterized. Surface areas and pore volumes of the CNT/$TiO_2$ samples showed catastrophic decrease due to deposition of titanium compounds. Scanning electron microscopy (SEM) results indicated that the MWCNTs were homogenously decorated and well-dispersed onto/into the composites without apparent agglomeration of $TiO_2$ particles. In the X-ray diffraction (XRD) patterns, peaks of anatase and rutile phase were observed. The energy dispersive X-ray spectroscopy (EDX) spectra revealed the presence of major elements such as C and O with strong Ti peaks. According to the photocatalytic results, MB removal by a treatment with CNT/$TiO_2$ composites seems to have an excellent removal effect as order of CTIP, CTNB and CTPP composites due to a photolysis of the supported $TiO_2$, the radical reaction and the adsorptivity and absorptivity of the MWCNTs.

Keywords

References

  1. Y. Yu, J.C. Yu, C.Y. Chan, Y.K. Che, J.C. Zhao, and L. Ding, 'Enhancement of Adsorption and Photocatalytic Activity of $TiO_2$ by using Carbon Nanotubes for the Treatment of Azo Dye,' Appl. Cat. B: Environ., 61 1-11 (2005) https://doi.org/10.1016/j.apcatb.2005.03.008
  2. S.M. Yuen, C.C. Ma, C.Y. Chung, Y.H. Hsiao, C.L. Ching, and A.D. Yu, 'Preparation, Morphology and Electrical Properties of $TiO_2$ Coated Multiwalled Carbon Nanotube/epoxy Composites,' Composites: Part A, 39 119-23 (2008) https://doi.org/10.1016/j.compositesa.2007.08.021
  3. R. Ulbricht, S.B. Lee, X. Jiang, K. Inoue, M. Zhang, S. Fang, R.H. Baughman, and A.A. Zakhidov, 'Transparent Carbon Nanotube Sheets as 3-D Charge Collectors in Organic Solar Cells,' Solar Energy Materials and Solar Cells, 91 [5] 416-19 (2007) https://doi.org/10.1016/j.solmat.2006.10.002
  4. N.B. Jackson, S.G. Thoma, S. Kohler, and T. M. Nenoff, 'Zirconium-titanium Phosphate Acid Catalysts Synthesized by Sol Gel Techniques,' Studies in Surface Science and Catalysis, 118 643-49 (1998) https://doi.org/10.1016/S0167-2991(98)80231-0
  5. G. Zhang, L. Wang, K. Shen, D. Zhao, and H. S. Freeman, 'Hydrogenation of o-chloronitrobenzene on a Pd/C Catalyst Doped with Metal Oxide Nanoparticles,' Chemical Engineering J., 141 [1-3] 368-74 (2008) https://doi.org/10.1016/j.cej.2008.04.006
  6. S. Yang, W. Zhu, J. Wang, and Z. Chen, 'Catalytic Wet Air Oxidation of Phenol Over $CeO_2-TiO_2$ Catalyst in the Batch Reactor and the Packed-bed Reactor,' J. Hazardous Materials, 153 [3] 1248-53 (2008) https://doi.org/10.1016/j.jhazmat.2007.09.084
  7. P.M. Ajayan, 'Nanotubes from Carbon,' Chem. Rev., 99 [7] 1787-92 (1999) https://doi.org/10.1021/cr970102g
  8. R.H. Baughman, A.A. Zakhidov, and W.A. de Heer, 'Carbon Nanotubes-the Route Toward Applications,' Science, 297 [5582] 787-92 (2002) https://doi.org/10.1126/science.1060928
  9. P. Vincent, A. Brioude, C. Journet, S. Rabaste, S.T. Purcell, J. Le Brusq, and J.C. Plenet, 'Inclusion of Carbon Nanotubes in a $TiO_2$ Sol-gel Matrix,' J. Non-Crystalline Solids, 311 130-37 (2002) https://doi.org/10.1016/S0022-3093(02)01371-6
  10. W.C. Oh, A.R. Jung, and W.B. Ko, 'Preparation of Fullerene/TiO2 Composite and its Photocatalytic Effect, ' J. Industrial and Engineering Chemistry, 13 [7] 1208-14 (2007)
  11. W.C. Oh and M.L. Chen, 'Synthesis and Characterization of $CNT/TiO_2$ Composites Thermally Derived from MWCNT and Titanium (IV) n-butoxide,' Bull. Kor. Chem. Soc., 29 [1] 159-64 (2008) https://doi.org/10.5012/bkcs.2008.29.1.159
  12. W.C. Oh, and M.L. Chen, 'Electro-chemical Preparation of $TiO_2/$ACF Composites with TNB Electroyte and Their Photocatalytic Effect,' J. Ceramic Processing Research, 9 [2] 100-06 (2008)
  13. S.H. Chien, Y. C. Liou, and M.C. Kuo, 'Preparation and Characterization of Nonosized Pt/Au Particles on $TiO_2$-nanotubes,' Synthetic Metals, 152 333-36 (2005) https://doi.org/10.1016/j.synthmet.2005.07.254
  14. D. He, L. Yang, S. Kuang, and Q Cai, 'Fabrication and Catalytic of Pt and Ru Decorated $TiO_2$/CNTs Catalyst for Methanol Electrooxidation,' Elctrochemistry Communications, 9 2467-2472 (2007) https://doi.org/10.1016/j.elecom.2007.07.025
  15. W. Wang, P. Serp, P. Kalck, and J.L. Faria, 'Visible Light Photodegradation of Phenol on MWCNT-$TiO_2$ Composite Catalysts Prepared by a Modified Sol-gel Method,' J. Molecular Catalysis A: Chemical, 235 194-99 (2005) https://doi.org/10.1016/j.molcata.2005.02.027
  16. J.W. Patrick, 'Porocity in Carbon Characterization and Applications,' pp. 28-30, Edward Arnold, London, 1995
  17. M.L. Chen, Y.S. Ko, and W.C. Oh, '$Carbon/TiO_2$ Prepared from to Pitch and their Photocatalytic Activity', Carbon Science, 8 [1] 6-11 (2007)
  18. W.C. Oh, Synthesis and Characterization of Fe-containing $AC/TiO_2$ Composites and their Photodegradation Effect for the Piggery Waste, Environ. Eng. Res., 13 [2] 85-92 (2008) https://doi.org/10.4491/eer.2008.13.2.085
  19. X.H. Xia, Z.J. Jia, Y. Yu, Y. Liang, Z. Wang, and L.L. Ma, 'Preparation of Multi-walled Carbon Nanotube Supported $TiO_2 and its Photocatalytic Activity in the Reduction of CO_2 with H_2O$,' Carbon, 45 717-21 (2007) https://doi.org/10.1016/j.carbon.2006.11.028
  20. A. Jitianu, T. Cacciaguerra, R. Benoit, S. Delpeux, F. Beguin, and S. Bonnamy, 'Synthesis and Characterization of Carbon Nanotubes-$TiO_2$ Nanocomposites,' Carbon, 42 1147-51 (2004) https://doi.org/10.1016/j.carbon.2003.12.041
  21. M.L. Chen, J.S. Bae and W.C. Oh, 'Photocatalytic Effect for the Carbon-coated TiO2 Prepared from Different Heat Treatment Temperature,' Analytical Science & Technology, 19 [6] 460-67 (2006)
  22. W.C. Oh, J.S. Bae, and M.L. Chen, 'Preparation of Carboncoated $TiO_2$ at Different Heat Treatment Temperatures and their Photoactivity,' Carbon Science, 7 [4] 259-65 (2006)
  23. H. Kominami, J. Kato, Y. Takada, Y. Doushi, B. Ohtani, S. Nishimoto, M. Inoue, T. Inui, and Y. Kera, 'Novel Synthesis of Microcrystalline Titanium(IV) Oxide Having High Thermal Stability and Ultra-high Photocatalytic Activity: Thermal Decomposition of Titanium(IV) Alkoxide in Organic Solvents,' Catalysis Latters, 46 235-40 (1997) https://doi.org/10.1023/A:1019022719479
  24. W.C. Oh, and A.R. Jung, 'Properties and Photocatalytic Activity of Pitch-binded ACF/$TiO_2$ Composites,' J. Kor. Ceram. Soc., 45 [3] 150-56 (2008) https://doi.org/10.4191/KCERS.2008.45.3.150
  25. W.C. Oh, and Y.R. Na, 'Photocatalytic Oxidation for Organic Dye using Phenol Resin-based Carbon-titania Composites,' J. Kor. Ceram. Soc., 45 [1] 36-42 (2008) https://doi.org/10.4191/KCERS.2008.45.1.036
  26. W.C. Oh, and T.S. Park, 'Comparative Analysis of the Physical Properties and Photocatalytic Effects for $C/TiO_2$ Complexes Derived from Titanium n-butoxide,' Environ. Eng. Res., 12 [5] 218-23 (2007) https://doi.org/10.4491/eer.2007.12.5.218
  27. W.C. Oh, S.B. Han, and J.S. Bae, 'The Analysis for the HCl Modification Effect and Formation of $TiO_2$ on Activated Carbon Fiber Surface,' Analytical Science & Technology, 20 [4] 279-88 (2007)
  28. Z.S. Guan, X.T. Zhang, Y. Ma, Y.A. Cao, and J. N. Yao, 'Photocatalytic Activity of TiO2 Prepared at Low Temperature by a Photo-assisted Sol-gel Method,' J. Mater. Res., 16 [4] 907-09 (2001) https://doi.org/10.1557/JMR.2001.0128
  29. M. Inagaki, Y. Hirose, T. Matsunage, T. Tsumura, and M. Toyoda, 'Carbon Coating of Anatase-type $TiO_2$ Through their Precipitation in PVA Aqueous Solution,' Carbon, 41 2619-24 (2003) https://doi.org/10.1016/S0008-6223(03)00340-3
  30. Y. Yu, J.C. Yu, J.G. Yu, Y.C. Kwok, Y.K. Che, J.C. Zhao, L. Ding, W.K. Ge, and P.K. Wang 'Enhancement of Photocatalytic Activity of Mesoporous $Tio_2$ by using Carbon Nanotubes,' Appl. Cat. B: Environ, 289 186-96 (2005) https://doi.org/10.1016/j.apcata.2005.04.057
  31. W.Wang, P. Serp, P. Kalck, C.G. Silvia, and J.L. Faria, 'Preparation and Characterization of Nonostructured MWCNT-$TiO_2$ Composite Materials for Photocatalytic Water Treatment Applications,' Materials Research Bulletin, 43 958-67 (2008) https://doi.org/10.1016/j.materresbull.2007.04.032
  32. W.C. Oh, and M.L. Chen, 'Synthesis and Characterization of CNT/$TiO_2$ Composites Thermally Derived from MWCNT and Titanium (IV) N-butoxide,' Bull. Korean Chem. Soc., 29 [1] 159-64 (2008) https://doi.org/10.5012/bkcs.2008.29.1.159
  33. T. Matsunaga, and M. Inagaki, Proceeding of the 32nd annual meeting in Carbon Society of Japan, pp. 270-71, 2004
  34. M.L. Chen, F.J. Zhang, and W.C. Oh, 'Photocatalytic degradation of Methylene Blue by CNT/$TiO_2$ Composites Prepared from MWCNT and Titanium N-butoxide with Benzene,' J. Kor. Ceram. Soc., 45 [11] 651-57 (2008) https://doi.org/10.4191/KCERS.2008.45.1.651
  35. G. Cao, 'Nanostructures & Nanomaterials,' pp. 344-5, Imperial College Press, 2004

Cited by

  1. Effect of rapid cooling time on optical absorption and band gap energy of TiO2 nanoparticles vol.25, pp.6, 2014, https://doi.org/10.1007/s10854-014-1894-2
  2. Study of morphology and band gap energy of TiO2-carbon nanotube nanocomposite vol.26, pp.5, 2015, https://doi.org/10.1007/s10854-015-2825-6
  3. Gold loaded titanium dioxide–carbon nanotube composites as active photocatalysts for cyclohexane oxidation at ambient conditions vol.5, pp.57, 2015, https://doi.org/10.1039/C5RA05253J
  4. The Effect of Carbon Nanotube on Band Gap Energy of TiO2 Nanoparticles vol.82, pp.2, 2015, https://doi.org/10.1007/s10812-015-0102-3