Physical Detection Properties of Irradiated Wheat and Corn Treated with Different Radiation Sources

방사선 조사선원에 따른 밀과 옥수수의 물리적 검지 특성

  • Kim, Gui-Ran (Department of Food Science and Technology, Kyungpook National University) ;
  • Lee, Ju-Woon (Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute) ;
  • Kim, Jeong-Sook (Department of food Nutrition & Culinary, Keimyung Collage) ;
  • Kwon, Joong-Ho (Department of Food Science and Technology, Kyungpook National University)
  • 김귀란 (경북대학교 식품공학과) ;
  • 이주운 (한국원자력연구원 정읍방사선과학연구소) ;
  • 김정숙 (계명문화대학 식품영양조리과) ;
  • 권중호 (경북대학교 식품공학과)
  • Published : 2009.04.30

Abstract

This study determined the photostimulated luminescence(PSL), thermoluminescence(TL), and electron spin resonance(ESR) properties of wheat and corn irradiated with 0-10 kGy of gamma-ray or electron-beam. PSL values of both irradiated grains, regardless of radiation source, were 241-429 photons/sec in nonirradiated samples(negative values, defined as ${\leq}700$ photons/60 sec) and 5,528-40,870 photons/60 sec in irradiated ones(positive values, defined as ${\geq}5,000$ photons/sec), thereby distinguishing irradiated from nonirradiated samples. The TL glow curves($TL_1$) peaked at around $300^{\circ}C$ in nonirradiated samples, but at about $180^{\circ}C$ in irradiated samples, at high intensities, regardless of radiation source. The TL ratios($TL_1/TL_2$) calculated to strengthen $TL_1$ data reliability were less than 0.03 for nonirradiated samples and over 0.20 for irradiated materials, in good agreement with threshold values for nonirradiated(${\leq}0.1$) and irradiated(${\geq}0.1$) samples. ESR analysis was not applicable in identification of irradiated wheat and corn. Electron-beam irradiation resulted in higher PSL and TL signals than did gamma-rays, at the same applied doses.

곡류 중 수입이 활발한 밀과 옥수수에 대하여 국제적으로 이용이 허가된 감마선과 전자선 에너지를 총 흡수선량 $0{\sim}10\;kGy$를 조사한 다음 photostimulated luminescence(PSL), thermoluminescence(TL) 및 electron spin resonance(ESR)를 분석하여 조사여부 검지 특성을 확인하였다. PSL 분석 결과, 두 시료 모두 조사선원에 관계없이 비조사구에서는 $241{\sim}249$ photon count/sec 값으로 700(negative) 이하의 값을, 1 kGy 이상 조사구에서는 $5528{\sim}40870$ photon count/sec 값으로 5000(positive) 이상의 값을 나타내어 비조사구와 조사구의 스크리닝이 가능하였다. TL 분석에서는 두 시료 모두 조사선원에 무관하게 비조사구는 $300^{\circ}C$ 부근에서 매우 낮은 강도의 glow curve($TL_1$)를 나타낸 반면, 조사구에서는 $180^{\circ}C$ 부근에서 방사선 조사 유래의 glow curve($TL_1$)가 관찰되었다. 한편 $TL_1$ 결과의 검증을 위하여 재조사에 의한 TL ratio($TL_1/TL_2$)를 산출한 결과, 비조사구에서는 0.03 이하를, 1 kGy 이상 조사구에서는 0.2 이상의 값을 나타내어 비조사구와 조사구의 threshold value 차이로써 곡류 시료의 방사선 조사여부 판별이 가능하였다. 밀과 옥수수 시료에 대한 ESR 분석 결과, 방사선 조사 유래의 특이한 signal은 확인되지 않았다. 밀과 옥수수의 조사여부 판별에서 동일 선량에서의 PSL 및 TL signal은 감마선에 비해 전자선에서 높은 강도를 나타내었다.

Keywords

References

  1. KFDA. (2008) Korea Food Standard Code. Korea Food and Drug Administration, 2-1-9∼2-1-10
  2. IAEA. (2006) Database on approvals for irradiation food (supplement). Food Envir. Prot. Newsletters, 9, 22-59
  3. Korea Agricultural Trade Information. (2008). Trade Statistical Database (http://www.kati.net)
  4. ACSH. (2003) Irradiated Foods. American Council on Science and Health, p.5-50
  5. Kwon, J.H. (2007) Current status of food irradiation in Korea. Food Irradiation (Japan), 42, 35-42
  6. IAEA (1991) Analytical detection methods for irradiated food. A review of current literature, IAEA-TECDOC 587-172
  7. FAO/WHO CODEX (2003) General Codex Methods for the Detection of Irradiated Food. CODEX STAN 231-2001, Rev. 1
  8. Alberti, A., Corda. U., Fuochi. P., Bortolin, E., Calicchia, A. and Onori, S. (2007) Light-induced fading of the PSL signal from irradiated herbs and spices. Radiat. Phys. Chem., 76, 1455-1458 https://doi.org/10.1016/j.radphyschem.2007.02.050
  9. Khan, H.M. and Delince$\acute{e}$, H. (1995) Detection of radiation treatment of spices and herbs of Asian origin using thermoluminescence of mineral contaminants. Appl. Radiat. Isot., 46, 1071-1075 https://doi.org/10.1016/0969-8043(95)00193-H
  10. Desrosiers, M.F. and Mclaughlin, W.L. (1989) Examination of gamma-irradiated fruits and vegetables by electron spin resonance spectroscopy. Radiat. Phys. Chem., 34, 895-898
  11. EN 13751 (2002) Foodstuffs - Detection of irradiated food using photostimulated luminescence, European Committee for Standardization. Brussels, Belgium
  12. Schreiber, G.A., Ziegelmann, B., Quitzsch, G., Helle, N. and Bőgl, K.W. (1993) Luminescence techniques to identify the treatment of foods by ionizing irradiation. Food Structure, 12, 385
  13. Schreiber, G,A., Hoffmann, A., Helle, N. and Bőgl, K.W. (1995) An interlaboratory trial on the identification of irradiated spices, herbs, and spice-herb mixtures by thermo-luminescence analysis. J. AOAC International, 78, 88
  14. Schreiber, G.A., Hoffmann, A., Helle, N. and Bőgl, K.W. (1994) Methods for routine control of irradiate food determination of the irradiation status of shellfish by thermoluminescence analysis. Raiat. Phys. Chem., 43, 533 https://doi.org/10.1016/0969-806X(94)90164-3
  15. EN 1788 (2001) Foodstuffs - detection of irradiated food from which silicate minerals can be isolated, method by thermoluminescence; European Committee for standardization. Brussels, Belgium
  16. Origin (1999) Origin tutorial manual, version 6.0, Microcal Software, Inc., Northampton, MA, p.20-45
  17. SAS (1998) SAS User's Guide Statistics, 3rd ed., Statistical Analysis System Institute Inc., Cary, NC, U.S.A.
  18. Bayram, G. and Delince$\acute{e}$, H. (2004) Identification of irradiated Turkish foodstuffs combining various physical detection methods. Food Control, 15, 81-91 https://doi.org/10.1016/S0956-7135(03)00018-5
  19. Kwon, J.H., Kim, M.Y., Kim, B.K., Chung, H.W., Kim, T.C. and Kim, S.J. (2006) The detection of irradiation composite seasoning foods by analyzing photostimulated luminescence (PSL), electron spin resonance (ESR) and thermoluminescence (TL). Korean J. Food Preserv., 13, 55-60
  20. Bhatti, I.A., Kim, B.K., Kim, M.Y., Lee, J.E., Kim, H.K. and Kwon, J.H. (2008) The screening and/or identification of different types of irradiated eggs by analyzing photostimulated luminescence and thermoluminescence. Food Control, 19, 87-591
  21. Chung, H.W. and Kwon, J.H. (1998) Detection of irradiated potato and garlic by thermoluminescence measurement. Korean J. Food Sci. Technol., 30, 283-287